===================== Product Identification =====================
MSDS NAME:SODIUM NITRATE TABLETS, S2901
NIIN:00N085051
MSDS Number: CGZWR
=== Responsible Party ===
Company:SIGMA CHEMICAL CO
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:314-771-5765
Emergency Phone Num:314-771-5765
CAGE:21076
=== Contractor Identification ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:SODIUM NITRITE (CERCLA)
CAS:7632-00-0
RTECS #:RA1225000
Fraction by Wt: 100%
OSHA PEL:N/K
ACGIH TLV:N/K
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:SUPP DATA:SALTS, CYANOGEN COMPOUNDS, THIOCYANATES,
THIOSULFATES, CYANIDES, SODIUM AMIDE.
RTECS #:9999999ZZ
Name:EFTS OF OVEREXP:W/OUT ANESTH); BEHAVIORAL (CONVLS/EFT ON
SEIZURE THRESHOLD; EXCITEMENT; CHANGE IN MOTOR ACTIVITY;(ING 4)
RTECS #:9999999ZZ
Name:ING 3:COMA); CARD (PULSE RATE INCR W/OUT FALL IN BP);
VASCULAR (BP LOWERING NOT CHARACT IN AUTONOMIC SECTION; (ING 5)
RTECS #:9999999ZZ
Name:ING 4:REGIONAL/GEN ARTERIOLAR/VENOUS DILATION; OTHER
CHANGES); LUNGS, THORAX/RESPIRATION (DYSPNAE; CYANOSIS; RESP(ING 6)
RTECS #:9999999ZZ
Name:ING 5:STIMULATION); GI (CHANGES IN STRUCTURE/FUNCTION OF
SALIVARY GLANDS; NAUS/VOMIT); KIDNEY, URETER, BLADDER (ING 7)
RTECS #:9999999ZZ
Name:ING 6:(URINE VOL INCREASED); BLOOD
(METHEMOGLOBINEMIA-CARBOXHEMOGLOBINEMIA); PATERNAL EFTS
(SPERMATOGENESIS); (ING 8)
RTECS #:9999999ZZ
Name:ING 7:EFTS ON FERTILITY (MALE FERTILITY INDEX;
PRE-IMPLANTATION MORTALITY); EFTS ON EMBRYO/FETUS (FETAL DEATH;
(ING 9)
RTECS #:9999999ZZ
Name:ING 8:OTHER EFTS TO EMBRYO/FETUS); SPECIFIC DEVELOPMENTAL
ABNORMS (CNS; BLOOD & LYMPHATIC SYSTEMS); EFTS ON (ING 10)
RTECS #:9999999ZZ
Name:ING 9:NEWBORN (GROWTH STATISTICS; BEHAVIORAL).
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) 180 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:HARMFUL IF SWALLOWED,
INHALED/ABSORBED THRU SKIN. CAUSES EYE & SKIN IRRIT. MATL IS IRRIT
TO MUC MEMBS & UPPER RESP TRACT. ABSORPTION INTO BODY LEADS TO FORM
OF METHEMOGLOBIN WHICH IN SUFFICIENT CONC CAUSES CYANOSIS. ONSET
MAY BE DELAYED 2-4 HRS/LONGER. CHRONIC:LAB EXPTS HAVE SHOWN
MUTAGENIC EFTS.(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:TARGET ORGS:BLOOD, CVS. PRDCES
METHEMOGLOBIN. INGEST OF 1 GM HAS PRDCD DEATH IN HUMANS. TO THE
BEST OF MFR'S KNOWLEDGE, THE CHEM, PHYSICAL & TOXICOLOGICAL
PROPERTIES HAVE NOT BEEN THORO INVES TIGATED. TARGET ORG
DATA:PERIPHERAL NERVE & SENSATION (SPASTIC PARAL WITH/WITHOUT
SENSORY CHANGE; FLACCID PARAL (ING 3)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT LST 15 MINS.
ASSURE ADEQ FLUSHING BY SEPARATING EYELIDS W/FINGERS. SKIN:IMMED
FLUSH W/COPIOUS AMTS OF WATER FOR AT LST 15 MINS WHILE REMOVING
CONTAM CLT HG & SHOES. WASH CONTAM CLTHG BEFORE REUSE. DISCARD
CONTAM SHOES. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG GIVE ARTF
RESP. IF BRTHG IS DFCLT, GIVE OXYG. INGEST:WASH OUT MOUTH W/WATER
PROVIDED (SUPDAT)
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . STRONG OXIDIZER.
Unusual Fire/Explosion Hazard:CONTACT W/OTHER MATERIAL MAY CAUSE FIRE.
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL SOURCES OF IGNIT.
WEAR NIOSH APPRVD SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. COVER
W/DRY-LIME, SAND/SODA ASH. PLACE IN COVERED CNTNRS USING
NON-SPARKING TOOLS & TRANSPORT OUTDOORS. VENTILATE AREA & WASH
SPILL SITE(SUPDAT)
Neutralizing Agent:DRY LIME, SAND OR SODA ASH.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID BRTHG DUST. DO NOT GET IN EYES,
ON SKIN, ON CLTHG. AVOID PRLNG/RPTD EXPOS. IRRIT. POSS MUTAGEN.
KEEP TIGHTLY CLSD. STORE IN A COOL, DRY PLACE.
Other Precautions:KEEP AWAY FROM COMBUST MATLS, HEAT, SPARKS & OPEN
FLAME. AVOID CONT W/ACID. OXIDIZING. CONT W/COMBUST MATL MAY CAUSE
FIRE. TOX BY INHAL, IN CONT W/SKIN & IF SWALLOWED. IRRIT TO EYES,
RESP SYS & SKIN. CONT W/ACIDS LIBERATES TOXIC GAS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . WEAR OTHER SUITABLE PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
FIRST AID PROC:PERS IS CONSCIOUS. CALL MD. SPILL PROC:AFTER MATL PICKUP
IS COMPLETE. MATLS TO AVOID:HYPOPHOSPHATES, IODIDES, MERCURY SALTS,
PERMANGANATE, SULFITES, TANNIC ACID, VEGETABLE ASTRINGENT DE
COCTIONS, INFUSIONS/TINCTURES, PRIMARY AMINES & AMIDES, SECONDARY
AMINES & AMIDES, ACTIVATED CARBON, AMMONIUM (ING 2)
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:520F,271C
Spec Gravity:2.168
Appearance and Odor:SOLID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG REDUCING AGENTS, FINELY POWDERED METALS, STRONG ACIDS. INCOMPAT
W/ACETANILIDE, ANTIPYRINE, CHLORATES, (SUPP DATA)
Stability Condition to Avoid:PROTECT FROM MOISTURE.
Hazardous Decomposition Products:NITROGEN OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL
SERVICE TO DISPOSE OF THIS MATERIAL. OBSERVE ALL FEDERAL, STATE &
LOCAL ENVIRONMENTAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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