===================== Product Identification =====================
MSDS NAME:SKYDROL LD-4 FIRE RESISTANT HYDRAULIC FLUID
NIIN:01-096-6497
MSDS Number: CHHRF
=== Responsible Party ===
Company:MONSANTO CO
Address:800 N LINDBERGH BLVD
City:SAINT LOUIS
State:MO
ZIP:63167
Country:US
Info Phone Num:800-332-3111/314-694-6661
Emergency Phone Num:314-694-4000/800-424-9300(CHEMTREC)
CAGE:76541
=== Contractor Identification ===
Company:MONSANTO COMPANY
Address:800 N LINDBERGH BLVD
Box:City:SAINT LOUIS
State:MO
ZIP:63167
Country:US
Phone:314-694-6661 OR 800-332-3111
CAGE:76541
Company:SOLUTIA INC.
Address:10300 OLIVE BLVD
Box:City:ST LOUIS
State:MO
ZIP:63166-6760
Country:US
Phone:334-473-8472
CAGE:1CHP6
============= Composition/Information on Ingredients =============
Name:TRIBUTYL PHOSPHATE
CAS:126-73-8
RTECS #:TC7700000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3
ACGIH TLV:0.2 PPM; 9596
Name:DIBUTYL PHENYL PHOSPHATE
CAS:2528-36-1
RTECS #:TB9626600
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:S,3.5 MG/M3 (0.3PPM)
Name:2,6-DI-TERT-BUTYL-P-CRESOL
CAS:128-37-0
RTECS #:GO7875000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3
ACGIH TLV:10 MG/M3; 9596
Name:BUTYL DIPHENYL PHOSPHATE
CAS:2752-95-6
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) 2,100 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY &
GASTROINTESTINAL TRACTS. ACUTE- EYE:MAY CAUSE SEVERE PAIN.
SKIN:PROLONGED/REPEATED CONTACT MAY CAUSE DRYING & CRACKING.
INHALE:VAPORS OR MISTS MAY CAUSE RESPIRAT ORY IRRITATION. ORAL:MAY
BE HARMFUL IF INGESTED. CHRONIC- MAY CAUSE URINARY BLADDER DAMAGE
BASED ON ANIMAL STUDIES.
Explanation of Carcinogenicity:NONE.
Effects of Overexposure:IRRITATION, REDNESS, NAUSEA, VOMITING, BLURRED
VISION, TEARING, DEFATTING OF SKIN, HEADACHE, CRACKING
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE
MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:MOVE TO FRESH
AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15
MINUTES. HOLD EYELIDS OPEN. SKIN:WIPE OFF EXCESS & WASH SKIN WITH
MILD SOAP & WATER OR WATERLESS CLEANER. ORAL:GET MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:320F,160C
Autoignition Temp:Autoignition Temp Text:750F
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, SAND, FOAM/DRY
CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS
COOL.
Fire Fighting Procedures:DO NOT ENTER ANY ENCLOSED OR CONFINED AREA
WITHOUT PROPER PROTECTIVE EQUIPMENT AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:TOXIC GASES
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. PROVIDE ADEQUATE
VENTILATION. REMOVE SPILL WITH INERT ABORBENT SUCH AS SAND, CLAY,
EARTH. TRANSFER TO PROPER CONTAINERS FOR DISPOSAL. PREVENT RUN-OFF
TO ENTER SEWERS OR WATE RWAYS. REPORT SPILLS AS REQUIRED TO
AUTHORITIES.
Neutralizing Agent:NOT RELEVANT
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE AT AMBIENT TEMPERATURES. KEEP
AWAY FROM STRONG OXIDIZERS. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT
IN USE. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:DO NOT GET IN EYES. MINIMIZE SKIN CONTACT. WASH
THOROUGHLY AFTER HANDLING. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. EMPTY CONTAINER RETAINS RESIDUE. FOLLOW LABEL INSTRUCTIONS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY NEEDED. IF EXCESSIVE MISTING IS
EXPECTED, WEAR NIOSH-APPROVED ORGANIC VAPOR AND MIST RESPIRATOR
(REFER TO 29 CFR 1910.134)
Ventilation:ADEQUATE
Protective Gloves:NEOPRENE TO MINIMIZE SKIN CONTACT
Eye Protection:CHEMICAL GOGGLES/SAFETY GLASSES
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
FORMULA CHANGED. FOR PREVIOUS FORMULATION, SEE PNI A, SAME NSN.
================== Physical/Chemical Properties ==================
HCC:V6
NRC/State Lic Num:NOT RELEVANT
Melt/Freeze Pt:M.P/F.P Text:<-80F,<-62C
Spec Gravity:1.004 - 1.014
Viscosity:10.8-11.6 CS
Appearance and Odor:CLEAR, PURPLE OILY LIQUID - ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:EXCESSIVE HEAT (250F - 275F)
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
OXIDES OF PHOSPHORUS, SMOKE MAY BE FORMED.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. RECYCLING OR INCINERATION IS RECOMMENDED.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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