===================== Product Identification =====================
MSDS NAME:LITHIUM MANGANESE DIOXIDE BATTERY,DL 223,02202
NIIN:01-214-6441
MSDS Number: CHHRX
=== Responsible Party ===
Company:DURACELL INC
Address:BERKSHIRE CORPORATE PARK
City:BETHEL
State:CT
ZIP:06801
Country:US
Info Phone Num:203-796-4000
Emergency Phone Num:203-796-4682/203-796-4575
CAGE:GO384
=== Contractor Identification ===
Company:DURACELL INC
Address:BERKSHIRE INDUSTRIAL PK BLDG 9
City:BETHEL
State:CT
ZIP:06801-5000
Country:US
Phone:203-796-4292/617-449-7600
CAGE:GO384
Company:DURACELL INC TECHNICAL SALES AND MARKETING GROUP
Address:BERKSHIRE CORPORATE PARK
Box:City:BETHEL
State:CT
ZIP:06801
Country:US
Phone:203-796-4000
CAGE:90303
Company:DURACELL USA (ALIAS BATTERY TECHNOLOGY COMPANY)
Address:305 NEW HIGHWAY 64 EAST
Box:City:LEXINGTON
State:NC
ZIP:27292-2037
Country:US
Phone:617-449-7600
CAGE:2A917
Company:EAGLE-PICHER ENERGY PRODUCTS CORP
Address:13136 82A AVENUE
Box:City:SURREY, V3W 9Y6
State:BC
Country:US
Phone:604-543-4350
CAGE:0E1R2
============= Composition/Information on Ingredients =============
Name:LITHIUM METAL (LI), (0.5 G/CELL)
CAS:7439-93-2
RTECS #:OJ5540000
Other REC Limits:NONE RECOMMENDED
Name:MANGANESE DIOXIDE (MNO2), (5.6 G/CELL)
CAS:1313-13-9
RTECS #:OP0350000
Other REC Limits:PEL=0.2MG/M3,DURACEL
OSHA PEL:5 MG MN/M3 CEILING
ACGIH TLV:5 MG MN/M3
Name:CARBON BLACK (0.4 G/CELL)
CAS:1333-86-4
RTECS #:FF5800000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3; 9495
Name:TEFLON (0.2 G/CELL)
Other REC Limits:NONE RECOMMENDED
Name:PROPYLENE CARBONATE (PC), (0.25 G/CELL)
CAS:108-32-7
RTECS #:FF9650000
Other REC Limits:NONE RECOMMENDED
Name:ETHYLENE CARBONATE (EC), (0.25 G/CELL)
Other REC Limits:NONE RECOMMENDED
Name:DIMETHOXY ETHER (DME), (1.2 G/CELL)
Other REC Limits:3 PPM INDUSTRY STD
Name:LITHIUM TRIFLUOROMETHANE SULFONATE (LITFS), (0.05 G/CELL)
CAS:33454-82-9
Other REC Limits:0.1 MG/M3 3M CO
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHEMICALS/METALS ARE CONTAINED IN
SEALED CAN. RISK OF EXPOSURE OCCURS ONLY IF CELL LEAKS, EXPOSED TO
HIGH TEMP, ACCIDENTALLY SWALLOWED, OR MECHANICALLY, PHYSICALLY,
ELECTRICALLY ABUSED. CONTACT WITH E LECTROLYTE MAY CAUSE EYE AND
SKIN IRRITATION. LITHIUM CAN CAUSE THERMAL/CHEMICAL BURNS. DME MAY
BE REPRODUCTIVE HAZARD.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:RISK OF EXPOSURE OCCURS ONLY IF CELL IS
MECHANICALLY, PHYSICALLY OR ELECTRICALLY ABUSED. IF CELL IS
LEAKING, CONTACT WITH ELECTROLYTE MAY CAUSE EYE AND SKIN
IRRITATION. LITHIUM CAN CAUSE THERMAL AND C HEMICAL BURNS ON
CONTACT WITH SKIN. DMAMAY BE REPRODUCTIVE HAZARD.
INHALATION/INGESTION OF LITFS MAY BE HARMFUL.
Medical Cond Aggravated by Exposure:AN ACUTE EXPOSURE WILL NOT
GENERALLY AGGRAVATE ANY MEDICAL CONDITION.
======================= First Aid Measures =======================
First Aid:IF LEAKAGE FROM A CELL CONTACTS THE SKIN, FLUSH IMMEDIATELY
WITH WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. FOR EYE
CONTACT, FLUSH WITH COPIOUS AMOUNTS OF WATER AND GET MEDICAL
ATTENTION AT ONCE. DO NOT INHALE VENTED MATERIAL. EMPLOYEE
BREATHING VAPORS FROM VENTING CELL SHOULD BE REMOVED TO FRESH AIR.
IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. IF INGESTED, GET
MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NOT RELEVANT
Extinguishing Media:DRY CHEMICAL, DRY SAND. COOL BATTERIES AND ADJACENT
STRUCTURES WITH WATER.
Fire Fighting Procedures:CELLS CAN VENT WHEN SUBJECTED TO EXCESSIVE
HEAT. WHEN LARGE NUMBERS OF CELLS ARE INVOLVED IN A FIRE, FIRE
FIGHTERS SHOULD USE SCBA.
Unusual Fire/Explosion Hazard:TOXIC FUMES MAY BE FORMED.
================== Accidental Release Measures ==================
Spill Release Procedures:LEAVE AREA AND ALLOW BATTERIES TO COOL AND
VAPORS TO DISSIPATE. AVOID SKIN AND EYE CONTACT. DO NOT INHALE
VAPORS. REMOVE SPILLED LIQUID WITH ABSORBENT AND INCINERATE.CLEANUP
CREW SHOULD WEAR FULL-FACE RESPIRATOR (PARTICULATE/ORGANIC VAPOR
CARTRIDGE).
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY PLACE. AVOID
MECHANICAL, PHYSICAL, ELECTRICAL ABUSE. DO NOT SHORT CIRCUIT OR
INSTALL WITH INCORRECT POLARITY.
Other Precautions:BATTERIES MAY EXPLODE, PYROLIZE, OR VENT IF
DISASSEMBLED, CRUSHED, RECHARGED, OR EXPOSED TO FIRE OR HIGH
TEMPERATURES. DO NOT TOUCH BROKEN OR LEAKING BATTERIES. DO NOT
ATTEMPT TO RECHARGE. DO NOT CARR Y BATTERIES LOOSE IN POCKET OR
BAG.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS WHEN CELLS ARE INVOLVED IN A FIRE OR LEAKING IN CONFINED
SPACES. FOR SPILL, USE FULL-FACE RESPIRATOR WITH
PARTICULATE/ORGANIC CARTRIDGE.
Ventilation:PROVIDE ADEQUATE VENTILATION. IN CASE OF VENTING, PROVIDE
AS MUCH VENTILATION AS POSSIBLE.
Protective Gloves:BUTYL IF HANDLING LEAKERS.
Eye Protection:SAFETY GLASSES WHEN HANDLING LEAKERS.
Other Protective Equipment:NONE.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
BATTERY CONTAINS 0.5 GRAM OF LITHIUM. SOLID CATHODE.
================== Physical/Chemical Properties ==================
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:356F,180CLI
Spec Gravity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:NOT RELEVANT
Appearance and Odor:BATTERY - ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:DO NOT HEAT, DISASSEMBLE, RECHARGE, OR
SHORT CIRCUIT.
Hazardous Decomposition Products:TOXIC FUMES MAY BE FORMED.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH
LOCAL,STATE,FEDERAL REGULATIONS.TREAT OPEN CELLS AS HAZARDOUS
WASTE.DISCHARGED CELLS ARE NON-HAZARDOUS AND CAN BE DISPOSED OF,IN
SMALL AMOUNTS,WITH HOUSEHOLD TRASH.THESE BATTERIES ARE CONSIDERED
TO BE NON-HAZARDOUS WASTE
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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