===================== Product Identification =====================
MSDS NAME:CUPRIC SULFATE,5-HYDRATE,37-1441
NIIN:00-975-0696
MSDS Number: CHHQB
=== Responsible Party ===
Company:WARDS NATURAL SCIENCE ESTABLISHMENT INC
Address:5100 W HENRIETTA RD
Box:92912
City:ROCHESTER
State:NY
ZIP:14692
Country:US
Info Phone Num:716-359-2502/334-4222 (NIGHTS)
Emergency Phone Num:716-226-6177/800-424-9300(CHEMTREC)
Preparer's Name:MICHAEL RASZEJA
CAGE:63759
=== Contractor Identification ===
Company:WARDS NATURAL SCIENCE ESTABLISHMENT INC
Address:5100 W HENRIETTA RD
Box:92912
City:ROCHESTER
State:NY
ZIP:14692-9012
Country:US
Phone:(716) 359-2502
Contract Num:MDA414-99-A-0024-0030
CAGE:63759
============= Composition/Information on Ingredients =============
Name:CUPRIC SULFATE PENTAHYDRATE
CAS:7758-99-8
RTECS #:GL8900000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.2 MG/M3 AS CU FUME
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY
& GI TRACTS. ACUTE- INHALE:IRRITATING TO UPPER RESPIRATORY TRACT.
MAY CAUSE NASAL CONGESTION. EYES:CORROSIVE, CAUSES CONJUCTIVITIS.
SKIN:MAY CAUSE IRRITATION & AL LERGIC SKIN REACTION. ORAL:TOXIC.
MAY CAUSE COPPER POISONING AND/OR DEATH. CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, CHILLS, PAIN, NAUSEA, VOMITING,
METALLIC TASTE, DIARRHEA, REDNESS, ALLERGIC SKIN REACTION, BURNS
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS, IMPAIRED RESPIRATORY FUNCTION OR PERSONS
WITH WILSON'S DISEASE MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF
THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:MOVE TO FRESH
AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15
MINUTES. HOLD EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:IF
CONSCIOUS, DRINK 1-2 GLASSES OF WATER & INDUCE VOMITING. SEEK
IMMEDIATE MEDICAL ATTENTION. DO NOT GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NOT RELEVANT
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION
PRODUCTS MAY BE FORMED.
Unusual Fire/Explosion Hazard:MAY EMIT HAZARDOUS MATERIALS.
================== Accidental Release Measures ==================
Spill Release Procedures:SPRINKLE LIME OR SODA ASH ON SPILL TO FORM
INSOLUBLE COPPER SALT. SWEEP, SCOOP OR PICK UP. DO NOT RAISE DUST.
PLACE IN A SUITABLE CONTAINER FOR DISPOSAL.
Neutralizing Agent:SODA ASH, LIME
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE MATERIAL IN A DRY, VENTILATED
AREA AWAY FROM INCOMPATIBLES. KEEP CONTAINER TIGHTLY CLOSED.
PROTECT AGAINST PHYSICAL DAMAGE.
Other Precautions:DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. AVOID
INHALATION OF DUSTS. KEEP OUT OF REACH OF CHILDREN. OBEY HAZARD
WARNING LABEL. FOR LABORATORY USE ONLY. NOT FOR DRUG,
FOOD/HOUSEHOLD USE. USE WITH ADE QUATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NEEDED IN NORMAL LABORATORY HANDLING. IF
DUSTY SITUATIONS PREVAIL, WORK IN VENTILATION HOOD OR WEAR
NIOSH-APPROVED DUST RESPIRATOR OR MASK.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP FUME OR
DUST LEVELS AS LOW AS POSSIBLE.
Protective Gloves:RUBBER
Eye Protection:DUST-RESISTANT SAFETY GOGGLES
Other Protective Equipment:EYE WASH STATION, EMERGENCY SHOWER,
APPROPRIATE LABORATORY COAT TO COVER EXPOSED SKIN
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH AFTER HANDLING AND BEFORE EATING OR
DRINKING.
Supplemental Safety and Health
NSN CANCELLED. EFFECTIVE DATE: 91305. REPLACEMENT NSN: NONE.
================== Physical/Chemical Properties ==================
HCC:T6
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:302F(-5H2O)
Decomp Temp:Decomp Text:>1112F,>600
Spec Gravity:2.284
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:24.3% @ 30C/86F
Appearance and Odor:BLUE CRYSTALS OR LINE BLUE POWDER - ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
UNKNOWN WHEN PRODUCT REMAINS DRY.
Stability Condition to Avoid:EXCESSIVE HEAT, MOISTURE
Hazardous Decomposition Products:SULFUR DIOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. CONTACT AN APPROVED/LICENSED DISPOSAL AGENCY.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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