===================== Product Identification =====================
MSDS NAME:A399-500 1-BUTANOL
NIIN:00-939-5390
MSDS Number: CHHPS
=== Responsible Party ===
Company:FISHER SCIENTIFIC, CHEMICAL DIV.
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100 OR 201-796-7523
Emergency Phone Num:201-796-7100/800-424-9300(CHEMTREC)
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:N-BUTYL ALCOHOL (SARA 313) (CERCLA)
CAS:71-36-3
RTECS #:EO1400000
Fraction by Wt: >99%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:S, C 50 PPM; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL,RAT:LD50=790MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:MAY CAUSE MODERATE IRRIT.MAY
RESULT IN CORNEAL INJURY VAP MAY CAUSE IRRIT.SKIN:CAUSES IRRIT.MAY
BE ABSORBED THRU SKIN IN HARMFUL AMTS.PROL &/OR RESP CONTACT MAY
CAUSE DEFATTING OF SKIN,DERM.INGEST :MAY CAUSE SYST TOXICITY
W/ACIDOSIS.MAYCAUSE LIV/KID DMG.MAY CAUSE CNS
DEPRESS(HEAD,DIZZ,DROWS,NAU.ADV STAGE-(SIGN/SYM)
Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY:NOT LISTED BY
ACGIH,IARC,NIOSH,NTP,OSHA.
Effects of Overexposure:HEALTH:COLLAPSE,UNCONSC,COMA,DEATH-RESP
FAILURE).MAY BE HARMFUL.INHAL:HI CONC MAY CAUSE CNS
EFFECTS(HEAD,DIZZ,UNCONSC,COMA).CAUSE RESP TRACT IRRIT,LIVER/KID
DMG.CHRONIC:REP EYE EXPO CAUSE VISUAL ABNOR MALITIES INCLUDE BLUR
VISION,PHOTOSENSITIVITY.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
TARGET ORGANS:KIDNEYS,CENTRAL NERVOUS SYSTEM,LIVER.
======================= First Aid Measures =======================
First Aid:EYE:IMMED FLUSH W/LOTS OF H2O @LEAST 15MIS,LIFT LIDS.GET MED
AID.DONT ALLOW TO RUB OR KEEP EYES CLSD.SKIN:FLUSH W/LOTS OF
SOAP/H2O @LEAST 15MINS.REMOVE CONTAM CLOTH/SHOE.IRRIT DVLPS/PERSIST
GET EMD AI D.INGEST:CONSC/ALERT GIVE 2-4CUP OF MILK/H2O.NEVER GIVE
ANYTHING BY MOUTH IF UNCONSC.GETE MED AID IMMED.INHAL:MOVE TO FRESH
AIR.NOT BREATH GIVE ART RESP;BREATH DIFFI GIVE OXY.GET MED
AID.(SUPPLE)
================================ 98 ================================
Autoignition Temp:=365.C, 689.F
Autoignition Temp Text:689F
Lower Limits:1.4
Upper Limits:11.2
Extinguishing Media:SM:DRY CHEM,CO2.H2OSPRAY,ALCO-RESIST
FOAM.LG:H2OSPRAY,FOG,ALCO-RESIST FOAM.USE H2OSPRAY TO COOL
FIRE-EXPO CNTNR.(SUPPLE)
Fire Fighting Procedures:WEAR SCBA IN PRESSURE-DEMAND
MSHA/NIOSH(APPROV/EQUIV),FULL PROT GEAR.COOL FIRE-EXPO CNTNR
W/H2OSPARY.H2O MAY BE INEFFECTIVE;MATL LIGHTER THAN H2O FIRE
MAY(SUPP)
Unusual Fire/Explosion Hazard:WARNING!FLAMM LIQ.CAN RELEASE VAP FORM
EXPLO MIX @TEMP >FLASHPT.VAP MAY FORM EXPLO MIX W/AIR.VAP TRAVEL TO
IGN SOURCE-FLASHBK.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PPE AS INDICATED IN MSDS.AVOID
RUNOFF INTO STORM SEWERS/DITCHES WHICH LEAD TO WATERWAYS.REMOVE ALL
SOURCES OF IGNITION.ABOSRB SPILL USING ABSORBENT,NON-COMBUSTIBLE
MATL SUCH AS EARATH,SAND, VERMICULITE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:USE ONLY IN WELL VENTI
AREA.GROUND/BOND CNTNR WHEN TRANSF MATL.USE SPARK-PROOF TOOLS/EXPLO
PROOF EQMPT.EMPTY CNTNR RETAIN RESIDUE-CAN BE DANGEROUS.
Other Precautions:AVOID CONTACT W/HEAT/SPARKS/FLAME.AVOID
INGEST/INHAL.DONT PRESSURIZE,CUT,WELD,BRAZE,SOLDER,DRILL,GRIND,EXPO
EMPTY CNTNR TO HEAT/SPARK/OPN FLAME.STORE IN TIGHTLY CLSD CNTNR,IN
COOL DRY WELL-VENTI AREA AWAY FROM INCOMPAT SUBSTANCES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW OSHA RESPRIATOR REGUALTINS FOUND IN
29CFR1910.134.ALWAYS USE NIOSH-APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUATE GENERAL/LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW PERMISSIBLE EXPO LIMITS.
Protective Gloves:PROTECTIVE GLOVES
Eye Protection:PROT EYEGLASS,CHEM SAF GOGG,FACE PROTECT
Other Protective Equipment:WEAR APPROP PROT CLOTH TO PREVENT SKIN
EXPO.EYES-29CFR1910.133.
Work Hygienic Practices:WASH WELL AFT HNDLG.REMOVE CONTGAM CLOTH;WASH
BEF REUSE.
Supplemental Safety and Health
1STAID:DR NOTE:TREAT SYMPT/SUPPORT. FIREFIGHT:BE SPEAD BY USE OF
H2O.VAP HEAV THAN AIR;CAN SPREAD ALONG GROUND/COLLECT IN LOW/CONF
AREAS. EXT MEDIA:COOL CNTNR W/FLOOD QUANT OF H2O TIL WELL AFT FIRE
OU T. DISPO:CONSISTENT W/FED/STATE/LOC REGS.RCRA WASTE#U031(IGN
WASTE).BAN FRM LAND DISPO PER RCRA.SARA 313,RQ=5000LBS.
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:=117.2C, 243.F
Melt/Freeze Pt:=-90.C, -130.F
Decomp Temp:Decomp Text:N/AVAI
Vapor Pres:6.5
Vapor Density:2.6
Spec Gravity:0.8
pH:N/AVAI
Viscosity:2.94 CP @20C
Evaporation Rate & Reference:0.46, BUTYL ACETATE=1
Solubility in Water:9.1ML/10ML H20,APPRE
Appearance and Odor:COLOURLESS LIQUID, SWEETISH ODOR,PUTRID
ODOR,BANANA-LIKE
Percent Volatiles by Volume:NP
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALUMINUM,CHROMIUM TRIOXIDE,ORGANIC PEROXIDES,STRONG OXIDIZERS.
Stability Condition to Avoid:HIGH TEMPERATURES, INCOMPATIBLE
MATLS,IGNITION SOURCES.
Hazardous Decomposition Products:CAROBN MONOXIDE,CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHEN RELEASE TO SOIL EXPECTED TO
BIODEGRADE,LEACH TO GROUND H2O OR VOLATILIZE;IN H2O-BIODEGRADE OR
VOLATILIZE.BIOCONC POT PREDICTED TO BE LOW.SUBST MODERATELY-HI
MOBILE.SUBST RXS W/AIR W/HYDROXYL RADI
CALS(1/2LIFE-2.3DAYS).DISPOSE OF IN MANNER(SUPPE)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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