===================== Product Identification =====================
MSDS NAME:MANGANESE DIOXIDE LITHIUM PRIMARY BATTERIES,HP 1420-0854
NIIN:01-155-2359
MSDS Number: CHHRQ
=== Responsible Party ===
Company:SANYO ENERGY USA CORP
Address:2001 SANYO AVE
City:SAN DIEGO
State:CA
ZIP:92173
Country:US
Info Phone Num:619-661-6620
Emergency Phone Num:619-661-6620
CAGE:00JU0
=== Contractor Identification ===
Company:KOEBERT TOOL SALES INC
Address:121 HOLLY DR
Box:339
City:HATBORO
State:PA
ZIP:19040
Country:US
Phone:215-674-9622
CAGE:0RB59
Company:SANYO ENERGY(U.S.A.) CORP.
Address:2001 SANYO AVE
Box:City:SAN DIEGO
State:CA
ZIP:92173
Country:US
Phone:619-661-6620
CAGE:00JU0
============= Composition/Information on Ingredients =============
Name:MANGANESE DIOXIDE
CAS:1313-13-9
RTECS #:OP0350000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG MN/M3 CEILING
ACGIH TLV:5 MG MN/M3
Name:LITHIUM METAL
CAS:7439-93-2
RTECS #:OJ5540000
Other REC Limits:NONE RECOMMENDED
Name:PROPYLENE CARBONATE (PC)
CAS:108-32-7
RTECS #:FF9650000
Other REC Limits:NONE RECOMMENDED
Name:DIMETHOXYETHANE (DME)
CAS:110-71-4
RTECS #:KI1451000
Other REC Limits:NONE RECOMMENDED
Name:LITHIUM PERCHLORATE
CAS:7791-03-9
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) IS UNKNOWN.
Routes of Entry: Inhalation:NO Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:THESE CHEMICALS ARE CONTAINED IN A
SEALED CAN. RISK OF EXPOSURE OCCURS ONLY IF BATTERY IS
MECHANICALLY/ELECTRICALLY ABUSED. ACUTE & CHRONIC- ELECTROLYTE
(DME) IS SLIGHTLY TO MODERATELY TOXIC. MAY CAUS E EYE, SKIN &
MUCOUS MEMBRANES IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:NONE. IF BROKEN OR IN FIRE: IRRITATION
Medical Cond Aggravated by Exposure:NONE
======================= First Aid Measures =======================
First Aid:IF BROKEN/FIRE: GET MEDICAL HELP IF SYMPTOMS PERSIST.
INHALED:MOVE TO FRESH AIR. EYES:IMMEDIATELY FLUSH WITH WATER FOR 15
MINUTES. HOLD EYELIDS OPEN. SKIN:WASH WITH WATER. ORAL:IF
BATTERY/OPEN BATTERY IS INGESTED, DO NOT INDUCE VOMITING ORGIVE
FOOD/DRINK. SEEK IMMEDIATE MEDICAL ATTENTION. CALL NATIONAL BATTERY
INGESTION HOTLINE FOR ADVICE & FOLLOWUP (202-625-3333).
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:FOR BURNING BATTERIES IN BULK QUANTITIES OF
UNPACKED CELLS, USE CLASS D EXTINGUISHERS; LITH-X, POWDERED
GRAPHITE
Fire Fighting Procedures:NO WATER, SAND, CARBON DIOXIDE, SODA-ACID OR
HALOGENATED EXTINGUISHERS. WEAR NIOSH-APPROVED SELF CONTAINED
BREATHING APPARATUS & FULL PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:HAZARDOUS DECOMPOSITION PRODUCTS MAY BE
FORMED.
================== Accidental Release Measures ==================
Spill Release Procedures:IF BROKEN, ALLOW BATTERIES TO COOL AND VAPORS
TO DISSIPATE. AVOID EYES AND SKIN CONTACT. REMOVE SPILLED LIQUID
WITH INERT ABSORBENT AND INCINERATE.
Neutralizing Agent:NOT RELEVANT
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY PLACE. BATTERIES
MAY EXPLODE OR CAUSE BURNS, IF DISASSEMBLED, CRUSHED, RECHARGED,
EXPOSED TO FIRE OR HIGH TEMPERATURE.
Other Precautions:DO NOT INCINERATE. DO NOT TOUCH BROKEN OR LEAKING
BATTERIES. AVOID MECHANICAL OR ELECTRICAL ABUSE. DO NOT ATTEMPT TO
RECHARGE. AVOID SHORT CIRCUITS. DO NOT CARRY BATTERIES LOOSE IN
POCKET OR BAG. KEEP BATTERIES AWAY FROM SMALL CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NECESSARY UNDER NORMAL CONDITIONS OF USE.
WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WHEN LARGE
NUMBERS OF CELLS ARE INVOLVED IN A FIRE.
Ventilation:ADEQUATE
Protective Gloves:RUBBER FOR LEAKERS
Eye Protection:GOGGLES FOR LEAKERS
Other Protective Equipment:EYE BATH, WASHING FACILITIES
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING,
DRINKING/SMOKING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Spec Gravity:NOT RELEVANT
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:NOT RELEVANT
Appearance and Odor:BATTERY - ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER WITH INTERNAL CONTNETS
Stability Condition to Avoid:FIRE, HEAT, MOISTURE, RECHARGE,
DISASSEMBLE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. OPEN CELLS SHOULD BE TREATED AS HAZARDOUS
WASTE.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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