===================== Product Identification =====================
MSDS NAME:ULTRA ETCH 50, REPLENISHER
NIIN:00N088677
Status Code:A
MSDS Number: CHSQP
=== Responsible Party ===
Company:CP CHEMICALS INC
Address:ONE PARKER PLAZA
City:FORT LEE
State:NJ
ZIP:07024
Country:US
Info Phone Num:201-944-8528
Emergency Phone Num:800-424-9300 (CHEMTREC)
CAGE:HO912
=== Contractor Identification ===
Company:CP CHEMICALS INC
Address:1 PARKER PLAZA, SUITE 1400
City:FORT LEE
State:NJ
ZIP:07024
Country:US
Phone:803-481-8528
CAGE:HO912
Company:CP CHEMICALS, INC
Address:1 PARKER PLZ
Box:City:FT LEE
State:NJ
ZIP:07024
Country:US
Phone:800-424-9300(CHEMTREC)
CAGE:8C813
============= Composition/Information on Ingredients =============
Name:AMMONIUM CHLORIDE (CERCLA). LD50 (ORAL, RAT): 1650 MG/KG
CAS:12125-02-9
RTECS #:BP4550000
Fraction by Wt: 23-25%
OSHA PEL:10 MG/M3
ACGIH TLV:10 MG/M3 FUME; 9495
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:AMMONIUM HYDROXIDE (CERCLA). LD50 (ORAL, RAT): 350 MG/KG
CAS:1336-21-6
RTECS #:BQ9625000
Fraction by Wt: 21-23%
OSHA PEL:35 MG/M3 (MFR)
ACGIH TLV:17 MG/M3 (MFR)
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:AMMONIUM CARBONATE
CAS:10361-29-2
RTECS #:9999999ZZ
Fraction by Wt: 2-4%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:SUPDAT: HYDROXIDE, AMMONIUM CHLORIDE). NEW JERSEY LIST:
EMPLOYERS WHO PRODUCE, USE/STORE THIS PROD ARE REQD TO (ING 5)
RTECS #:9999999ZZ
Name:ING 4: FILL AN ANNUAL SURVEY DUE ON MARCH 1 OF EACH YEAR.
(AMMONIUM CHLORIDE, AMMONIUM HYDROXIDE).
RTECS #:9999999ZZ
Name:RESP PROT: OR AIRLINED HOOD MAY BE WORN.
RTECS #:9999999ZZ
Name:VENT: CONTROLS THE EMISSION AT ITS SOURCE, PREVENTING
DISPERSION OF IT INTO THE GENERAL WORK AREA. REFER TO THE (ING 8)
RTECS #:9999999ZZ
Name:ING 7: ACGIH DOCUMENT "INDUSTRIAL VENTILATION, A MANUAL OF
RECOMMENDED PRACTICES" FOR DETAILS.
RTECS #:9999999ZZ
Name:OTHER PREC: DEFECTS, AND/OR OTHER REPRODUCTIVE HARM". IT IS
REASONABLE TO ASSUME THAT ALL AMMONIA ETCHANT (ING 10)
RTECS #:9999999ZZ
Name:ING 9: COMPOUNDS CONTAIN ARSENIC, CADMIUM, CHROMIUM, AND
LEAD IN CONCONCENTRATIONS RANGING FROM A FEW PARTS PER (ING 11)
RTECS #:9999999ZZ
Name:ING 10: BILLION TO SEVERAL HUNDRED PARTS PER MILLION.
RTECS #:9999999ZZ
Name:EYE PROT: AND FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SYMPS OF INGEST: HUMAN POISON BY
INGEST. MAY CAUSE IRRIT/BURNING OF DIGESTIVE TRACT. SYMPS MAY INCL
NAUS, VOMIT, ABDOM PAIN, & DIARR. SYMPS OF INHAL: LIQ & VAP IRRIT
TO MUC MEMB & UPPER RESP TRACT. SY MPS MAY INCL COUGHING, SORE
THROAT, SHORTNESS OF BREATH. SYMPS OF SKIN CNTCT: IRRIT TO SKIN.
SYMPS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: MAY INCLUDE IRRITATION, REDNESS, &
PAIN. SYMPS OF EYE CONTACT: MAY CAUSE SEVERE IRRITATION, REDNESS,
PAIN, BLURRED OR IMPAIRED VISION, DISCOLORATION, AND DAMAGE.
CHRONIC: MAY AGGRAVATE OTHER PRE-EXISTING DISEASES TO INCLUDE
DISEASES OF THE EYES, SKIN, LUNGS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE: IMMED, FLUSH W/LRG AMTS OF H*2O FOR AT LEAST 15 MIN
WHILE HOLDING EYELIDS APART. WASHING W/IN ONE MIN IS ESSNTL TO
ACHIEVE MAX EFTIVNESS. GET IMMED MED ATTN AFTER FLUSHING. SKIN:
WASH AFFECTED AR EA THOROUGHLY W/SOAP & H*2O. REMOVE CONTAMD CLTHG
& LAUNDER BEFORE REUSE. IF IRRIT SHOULD DEVELOP, GET MED ATTN.
INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG
IS DFCULT (SUDAT)
===================== Fire Fighting Measures =====================
Lower Limits:15.5%-16.0%
Upper Limits:25.0%-27.0%
Extinguishing Media:USE ANY SUITABLE MEANS TO EXTINGUISH SURROUNDING
FIRE. COOL DRUMS WITH WATER SPRAY.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION RELEASES OXIDES OF
CARBON, TOXIC AMMONIA FUMES, AND OXIDES OF NITROGEN.
================== Accidental Release Measures ==================
Spill Release Procedures:NEVER ALLOW SPILLS TO ENTER SEWERS/WATERWAYS.
VENT SPILL AREA. REMOVE ALL SOURCES OF HEAT/IGNIT. VACUUM/SOAK UP
SPILLED MATL. PACKAGE FOR RECLAMATION/RECOVERY. WHATEVER CANNOT BE
SAVED MAY BE NEUT W/D ILUTE ACID & SENT TO APPRVD CHEM WASTE
LANDFILL.
Neutralizing Agent:DILUTE ACID.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP IN A TIGHTLY CLSD CNTNR. STORE IN
A COOL, DRY, WELL-VENT AREA, & AWAY FROM DIRECT SUNLIGHT. PROTECT
FROM FREEZING. KEEP AWAY FROM INCOMPAT MATLS.
Other Precautions:PROT FROM PHYSICAL DMG. AVOID CNTCT W/SKIN, EYES, &
CLTHG. WEAR PROT CLTHG, GLOVES, & SPLASH GOGGLES/SHIELD. AVOID
DUST/MIST. USE W/ADEQ VENT. "WARNING: THIS PROD MAY CONTAIN A CHEM
KNOWN TO THE STATE OF CA TO CAUSE CANCER/BIRTH (ING 9)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPRVD RESP IF EXPOS MAY/DOES EXCEED OCCUP
EXPOS LIMS. GENERALLY, A NIOSH APPRVD DUST/MIST RESP MAY BE WORN IN
AREAS WHERE TLV IS EXCEEDED UP TO TEN TIMES. ALTERNATIVELY, A NIOSH
APPRVD SUPPLIED AIR FULL FACEPIECE RESP (ING 6)
Ventilation:A SYS OF LOC EXHST IS REC TO KEEP EMPLOYEE EXPOS BELOW
AIRBORNE EXPOS LIMS. LOC EXHST IS USUALLY PREF BECAUSE IT (ING 7)
Protective Gloves:RUBBER/PLASTIC/IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(ING 12)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHY AFTER HANDLING.
Supplemental Safety and Health
FIRST AID PROC: GIVE OXYGEN. CALL MD. INGEST: NEVER GIVE ANYTHING BY
MOUTH TO UNCON PERS. DO NOT INDUCE VOMIT. GIVE PLENTY OF H*2O. CALL
MD IMMED. NOTES TO MD: NONE. WASTE DISP METH: (UNLISTED HAZ WAS TES
CHARACT/CORROSIVITY) RQ = 100 LBS. CANADIAN (HMIS) LIST): THIS PROD
IS SUBJECT TO REPORTING. (AMMONIUM (ING 4)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>212F,>100C
Melt/Freeze Pt:M.P/F.P Text:<50F,<10C
Vapor Pres:20 AQUEOUS
Vapor Density:<1
Spec Gravity:1.021 (H*2O =1)
pH:9-10
Evaporation Rate & Reference:NOT FOUND
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS TO PALE-BLUE LIQ: STRONG AMMONIA
ODOR. DO NOT SMELL-CORROSIVE.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS AND OXIDIZING MATERIALS; CORROSIVE TO SOME METALS. REACTS WITH
HALOGENS AND CERTAIN ORGANICS.
Stability Condition to Avoid:DO NOT STORE IN DIRECT SUNLIGHT OR EXPOSE
TO HEAT. PROTECT FROM FREEZING. AVOID CONTACT WITH INCOMPATIBLE
MATERIALS.
Hazardous Decomposition Products:THERMAL DECOMPOSITION RELEASES OXIDES
OF CARBON, TOXIC AMMONIA FUMES, AND OXIDES OF NITROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN AN APPRVD CHEM WASTE LANDFILL
I/A/W/APPLICABLE FED, STATE, & LOCAL REGS. IF APPRVD, MAY BE SENT
TO WASTEWATER TREATMENT FACILITY. SUPERFUND REPORTABLE QTY (RQ):
5000 LBS (12125-02-9), 10 00 LBS (1336-21-6). HAZ WASTE NO: D002
(SUPDAT)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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