===================== Product Identification =====================
MSDS NAME:INDUSTRIAL ENAMELS, B54Y37 SAFETY YELLOW
NIIN:00N088642
MSDS Number: CHSQL
=== Responsible Party ===
Company:SHERWIN-WILLIAMS CO
Address:101 PROSPECT AVE NW
City:CLEVELAND
State:OH
ZIP:44115
Country:US
Info Phone Num:216-566-2902
Emergency Phone Num:216-566-2917
CAGE:54636
=== Contractor Identification ===
Company:SHERWIN-WILLIAMS CO THE
Address:101 PROSPECT AVE NW
Box:City:CLEVELAND
State:OH
ZIP:44115-1042
Country:US
Phone:800-251-2486/216-566-2242
CAGE:54636
============= Composition/Information on Ingredients =============
Name:SOLVENT NAPHTHA, PETROLEUM, MEDIUM ALIPHATIC; (MINERAL
SPIRITS). VP:2.
CAS:64742-88-7
RTECS #:WF3450000
Fraction by Wt: 42%
OSHA PEL:100 PPM (MFR)
ACGIH TLV:100 PPM (MFR)
Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 13%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Name:EFTS OF OVEREXP:WORKPLACE. RPTS HAVE ASSOC RPTD & PRLNG
OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. INTENTIONAL(ING 5)
RTECS #:9999999ZZ
Name:ING 4:MISUSE BY DELIB CONCENTRATING & INHALING CONTENTS CAN
BE HARMFUL/FATAL. CAL PROP 65:WARNING:THESE PRODS (ING 6)
RTECS #:9999999ZZ
Name:ING 5:CONTAIN CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER.
RTECS #:9999999ZZ
Name:OTHER PREC:CNTNRS W/COMPLETE & APPROP LABELING. KEEP OUT OF
REACH OF CHILDREN. USE ONLY W/ADEQ VENT. AVOID BRTHG (ING 8)
RTECS #:9999999ZZ
Name:ING 7:VAP & SPRAY MIST. AVOID CONT W/SKIN & EYES. THESE
COATINGS MAY CONTAIN MATLS CLASSIFIED AS NUISANCE (ING 9)
RTECS #:9999999ZZ
Name:ING 8:PARTICULATES WHICH MAY BE PRESENT AT HAZ LEVELS ONLY
DURING SANDING/ABRADING OF DRIED FILM. IF NO SPEC (ING 10)
RTECS #:9999999ZZ
Name:ING 9:DUSTS ARE LISTED, APPLIC LIMS FOR NUISANCE DUSTS ARE
ACGIH TLV: 10 MG/M3 (TDUST), OSHA PEL: 15 MG/M3 (ING 11)
RTECS #:9999999ZZ
Name:ING 10:(TDUST), 5 MG/M3 (RESPIRABLE FRACTION). ADDN OF
REDUCERS/OTHER ADDITIVES TO THESE PRODS MAY SUBSTANTIALLY(ING 12)
RTECS #:9999999ZZ
Name:ING 11:ALTER COMPOSITION & HAZARDS OF PRODUCT.
RTECS #:9999999ZZ
Name:RESP PROT:MAY BE GENERATED FROM THIS PRODUCT, UNDERLYING
PAINT OR THE ABRASIVE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE
CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR
PROPER USE, VENT & PPE. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY
CAUSE NERV SYS DEPRESS. EXTREME OV EREXP MAY RSLT IN UNCON & POSS
DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF
EXCESSIVE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:EXPOS TO VAPS/SPRAY MISTS. REDNESS &
ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS.
CHRONIC:PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE EFTS TO LIVER,
URINARY & REPRO SYS. RAT S EXPOS TO TITANIUM DIOXIDE DUST AT
250MG/M3 DEVEL LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS ARE NOT
ATTAINABLE IN(ING 4)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGEST:GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:101F,38C
Lower Limits:0.2%
Upper Limits:19%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF.
WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT)
Unusual Fire/Explosion Hazard:COMBUST. KEEP CNTNRS TIGHTLY CLSD.
ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY
EXPLODE WHEN EXPOS TO EXTREME HEAT. APPLICATION TO (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE &
REMOVE W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DOL STOR CATEGORY:III 2. KEEP AWAY
FROM HEAT, SPKS & OPEN FLAME. CONSULT NFPA CODE. USE APPRVD BONDING
& GROUNDING PROCS. DO NOT TAKE INTERNALLY.
Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA
VENTED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT LIGHTS & HEATERS;
TURN OFF ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. KEEP
CNTNR CLSD WHEN NOT IN USE. TRANSFER ONLY TO APPRVD (ING 7)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR PROPERLY FITTED NIOSH APPRVD ORG
VAP/PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING
DRIED FILM, WEAR NIOSH APPRVD DUST/MIST RESP FOR DUST WHICH (ING
13)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO INGS IS
MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS (SUPDAT)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS
TO EXTREME HEAT. EXPLO HAZ:HOT SURFS REQS SPECIAL PRECS. DURING
EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY
NOT BE IMMED APPARENT. OBTAIN MED ATTN. WASTE DISP METH:REGARDING
POLLUTION. VENT:1910.94, 1910.107, 1910.108.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>174F,>79C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.96-1.25
VOC Grams/Liter:3.71
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:39.59
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THESE PRODS MAY BE HAZ AS DEFINED
UNDER RCRA (40 CFR 261). WASTE MUST BE TESTED FOR IGNITABILITY TO
DETERM APPLIC EPA HAZ WASTE NUMBERS. INCIN IN APPRVD FACILITY. DO
NOT INCIN CLSD CNTNR. D ISP OF I/A/W FED, STATE & LOC REGS (SUPDAT)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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