===================== Product Identification =====================
MSDS NAME:10 DUST, 2903-R; ORTHO SEVIN BRAND (SUPDAT)
NIIN:00N088678
Status Code:A
MSDS Number: CHSQQ
=== Responsible Party ===
Company:SOLARIS GROUP DIV MONSANTO CO
Box:5008
City:SAN RAMON
State:CA
ZIP:94583-0808
Country:US
Info Phone Num:800-225-2883
Emergency Phone Num:800-454-2333
CAGE:SOLAR
=== Contractor Identification ===
Company:SOLARIS GROUP DIV MONSANTO CO
Box:UNKNOW
CAGE:5XLAR
Company:SOLARIS GROUP DIV OF AGRICULTURAL GRP OF
Box:5008
City:SAN RAMON
State:CA
ZIP:94583-0808
Phone:800-225-2883/800-454-2333
CAGE:SOLAR
============= Composition/Information on Ingredients =============
Name:CARBAMIC ACID, METHYL-, 1-NAPHTHYL ESTER; (CARBARYL,
1-NAPHTHYL-N-METHYLCARBAMATE) (SARA 313) (CERCLA)
CAS:63-25-2
RTECS #:FC5950000
Fraction by Wt: 10%
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3; 9495
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:INERT INGREDIENTS
Fraction by Wt: 90%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:SUPDAT: DECONTAMINATE PERSONAL PROTECTIVE EQUIPMENT AND
FIRE FIGHTING EQUIPMENT BEFORE REUSE. READ THE ENTIRE DOCUMENT.
RTECS #:9999999ZZ
Name:EFTS OF OVEREXP: TO INTERNAL ORGANS IF INHALED. TARGET
ORGANS: CARBARYL IS AN INHIBITOR OF THE CHOLINESTERASE (ING 5)
RTECS #:9999999ZZ
Name:ING 4: ENZYME, FOUND IN NERVOUS TISSUE, RED BLOOD CELLS, &
PLASMA. TOX INFO: FOR COMPLETE TOX INFO, CNTCT NEHC .
RTECS #:9999999ZZ
Name:FIRST AID PROC: PERS VOMIT UNLESS DIRECTED TO DO SO BY MED
PERS. IF MED ADVICE CANNOT BE OBTAINED, THEN IMMED (ING 7)
RTECS #:9999999ZZ
Name:ING 6: TAKE PERS & PROD CNTNR, W/LABEL, TO AN EMER
TREATMENT CENTER. INHAL: IF RESP DISCOMFORT/IRRIT OCCURS, (ING 8)
RTECS #:9999999ZZ
Name:ING 7: MOVE PERS TO FRESH AIR. SEE A DOCTOR IF
DISCOMFORT/IRRITATION CONTINUES. NOTES TO MD: IN SEV POISONING,
(ING 9)
RTECS #:9999999ZZ
Name:ING 8: MEASUREMENT OF BLOOD CHOLINESTERASE ACTIVITY MAY BE
USED IN MONITORING EXPOS, BUT MAY NOT BE RELIABLE (ING 10)
RTECS #:9999999ZZ
Name:ING 9: DETECTORS OF CARBAMATE POISONING BECAUSE ENZYME
ACTIVITIES MAY REVERT TO NORMAL WITHIN MINS/HRS OF (ING 11)
RTECS #:9999999ZZ
Name:ING 10: EXPOSURE. IF SIGNS OF CHOLINESTERASE INHIBITION
APPEAR, ATROPINE SULFATE IS ANTIDOTAL.
RTECS #:9999999ZZ
Name:SPILL PROC: IN DISPOSABLE CNTNR. SCRUB CONTAMD AREA
W/DETERGENT & H*2O USING A STIFF BROOM. PICK UP LIQ W/OIL (ING 13)
RTECS #:9999999ZZ
Name:ING 12: DRY, CAT LITTER, CLAY, RAGS/OTHER ABSORBENT & PLACE
IN A DISPOSABLE CNTNR. DISPOSE OF I/A/W/INSTRUCTIONS(ING 14)
RTECS #:9999999ZZ
Name:ING 13: IN SECTION 7 "WASTE DISPOSAL METHOD". GEN PROCS:
OBSERVE ALL PROT & SAFETY PRECS WHEN CLEANING UP SPILLS(ING 15)
RTECS #:9999999ZZ
Name:ING 14: SEE SECTION 8 "CONTROL MEASURES". FOR HELP WITH ANY
SPILL, LEAK, FIRE OR EXPOSURE INVOLVING THIS (ING 16)
RTECS #:9999999ZZ
Name:ING 15: MATERIAL, CALL DAY OR NIGHT (800) 454-2333.
RTECS #:9999999ZZ
Name:WASTE DISP METH: RECS THAT ALL OF PROD BE USED UP,
CAREFULLY FOLLOWING ALL LABEL DIRECTIONS & PRECS. IF NEC (ING 18)
RTECS #:9999999ZZ
Name:ING 17: TO DISPOSE OF PARTIALLY FILLED PROD CNTNR, THEN
SECURELY WRAP IT IN SEVERAL LAYERS OF NEWSPAPER & (ING 19)
RTECS #:9999999ZZ
Name:ING 18: DISCARD IN TRASH. EMPTY CONTAINER: DO NOT REUSE
EMPTY CONTAINER. DISCARD CONTAINER IN TRASH.
RTECS #:9999999ZZ
Name:RESP PROT: GIVEN APPLICATION. OBSERVE RESP USE LIMITATIONS
SPECIFIED BY NIOSH/MFR. RESP PROT PROGRAMS MUST (ING 21)
RTECS #:9999999ZZ
Name:ING 20: COMPLY WITH 29 C.F.R. 1910.134. FOR APPLICATION OF
PROD I/A/W/LABEL INSTRUCTIONS, NO SPECIAL RESP PROT REQUIRED.
RTECS #:9999999ZZ
Name:VENT: MECHANICAL EXHAUST VENTILATION AT SOURCES OF AIR
CONTAMINATION SUCH AS OPEN PROCESS EQUIPMENT.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT): 2.9 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: EYE CNTCT MAY INCL DISCOMFORT,
TEARING, SWELL, REDNE, & BLURRED VISION. SEE TOX INFO. SKIN: THIS
SUBSTANCE IS NOT EXPECTED TO CAUSE PRLNG/SIGNIFICANT SKIN IRRIT. IF
ABSORBED THRU SKIN, THIS SUBS TANCE IS CONSIDERED PRACTICALLY
NON-TOXTO INTERNAL ORGS. READ TOX INFO SECTION OF (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: FOR MORE INFO. INGEST: INGEST MAY
CAUSE IRRIT OF DIGESTIVE TRACT WHICH MAY INCL NAUS, VOMIT, & DIARR.
IF SWALLOWED, THIS SUBSTANCE IS CONSIDERED SLIGHTLY TOX TO INTERNAL
ORGANS. SEE TOX INFO . INHAL: SYSTEMIC TOX OF THIS SUBSTANCEHAS NOT
BEEN DETERM. HOWEVER, IT SHOULD BE PRACTICALLY NON-TOXIC (ING 4)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes: FLUSH IMMED W/FRESH H*2O FOR AT LEAST 15 MIN WHILE
HOLDING EYELIDS OPEN. REMOVE CNTCT LENSES IF WORN. NO ADDITIONAL
FIRST AID SHOULD BE NEC. HOWEVER, IF IRRIT PERSISTS, SEE A DOCTOR.
SKIN: NO FI RST AID PROCS ARE REQD. AS A PREC, WASHSKIN THOROUGHLY
W/SOAP & H*2O. REMOVE & WASH CONTAMD CLTHG. INGEST: IMMED TELEPHONE
A POIS CTL CTR, EMER TREATMENT CENTER/MD FOR ADVICE. DO NOT MAKE
(ING 6)
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Extinguishing Media:USE APPROPRIATE AGENT FOR SURROUNDING FIRE -
PRODUCT IS NOT COMBUSTIBLE.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
PRODS OF COMBUST FROM FIRES INVOLVING THIS MATL MAY BE TOX. AVOID
BRTHG SMOKE & MISTS. AVOID PERS & (SUPDAT)
Unusual Fire/Explosion Hazard:NORMAL COMBUSTION FORMS CARBON DIOXIDE,
WATER VAPOR AND MAY PRODUCE OXIDES OF NITROGEN. INCOMPLETE
COMBUSTION CAN PRODUCE CARBON MONOXIDE.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL SPILL: SWEEP UP MATL & USE ACCDG TO
LABEL INSTRUCTIONS/DISPOSE OF IN TRASH. LRG SPILL: CLEAN UP SPILLS
IMMED, OBSERVE PRECS IN EXPOS CONTROLS/PERS PROT SECTION. VACUUM
W/MACHINES EQUIPPED W/HIGH EFFICIENCY FILTERS/SWEEP UP MATL &
PLACE (ING 12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:GENERAL PROCEDURES: KEEP PESTICIDE IN
ORIGINAL CONTAINER. DO NOT PUT INTO FOOD OR DRINK CONTAINERS. AVOID
CONTAMINATION OF FEED AND FOODSTUFFS.
Other Precautions:STORE IN A COOL, DRY PLACE, PREFERABLY LOCKED STORAGE
AREA. WASH CONTAMINATED SKIN PROMPTLY. LAUNDER CONTAMINATED
CLOTHING AND CLEAN PROTECTIVE EQUIPMENT BEFORE REUSE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AVOID BRTHG DUST. USE NIOSH APPRVD RESP PROT
EQUIP (FULL FACEPIECE REC) WHEN AIRBORNE EXPOS LIMS ARE EXCEEDED
(SEE INGS). IF USED, FULL FACEPIECE REPLACES NEED FOR CHEM GOGGLES.
CONSULT RESP MFR TO DE TERM APPROP TYPE EQUIP FOR (ING 20)
Ventilation:PROVIDE NATURAL/MECH VENT TO CONTROL EXPOS LEVELS BELOW
AIRBORNE EXPOS LIMS (SEE INGS). IF PRACTICAL, USE LOC (ING 22)
Protective Gloves:CHEMICAL GOGGLES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
WEAR PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART #: CARBARYL INSECTICIDE. FIRE FIGHT PROC: EQUIP
CNTCT W/FALLOUT & RUNOFF. MINIMIZE AMT OF H*2O USED FOR FIRE
FIGHTING. DO NOT ENTER ANY ENCLSD AREA W/OUT FULL PROT EQUIP. KEEP
CN TNRS COOL W/WATER SPRAY. CONTAIN & ISOLATE RUNOFF & DEBRIS FOR
PROPER DISP. (ING 3)
================== Physical/Chemical Properties ==================
Solubility in Water:INSOLUBLE
Appearance and Odor:TAN, ODORLESS POWDER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH ACIDS AND BASES.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE OXIDES OF CARBON AND NITROGEN AND TRACE AMOUNTS OF METHYL
ISOCYANATE.
==================== Disposal Considerations ====================
Waste Disposal Methods:FOR LRG SPILLS: MATL COLLECTED THAT CANNOT BE
REPROCESSED SHOULD BE DISPOSED OF IN A LANDFILL APPRVD FOR
PESTICIDE DISP/I/A/W/APPLIC FED, STATE/LOCAL PROCS. PROD DISP:
SOLARIS GROUP IS COMMITTED TO RE SPONSIBLE ENVIRONMENTAL PRACTICES
& (ING 17)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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