===================== Product Identification =====================
MSDS NAME:ANCAMINE MCA CURING AGENT, HMCA-U
NIIN:00N092135
Status Code:A
MSDS Number: CJQPH
=== Responsible Party ===
Company:AIR PRODUCTS AND CHEMICALS INC
Address:7201 HAMILTON BLVD
City:ALLENTOWN
State:PA
ZIP:18195-1501
Country:US
Info Phone Num:800-345-3148
Emergency Phone Num:800-523-9374
CAGE:00742
=== Contractor Identification ===
Company:AIR PRODUCTS AND CHEMICALS INC
Address:7201 HAMILTON BLVD
Box:City:ALLENTOWN
State:PA
ZIP:18195-1501
Country:US
Phone:800-345-3148/ 800-752-1597
CAGE:00742
============= Composition/Information on Ingredients =============
Name:BENZYL ALCOHOL
CAS:100-51-6
RTECS #:DN3150000
> Wt:35.
Name:IPD, REACTION PRODUCTS WITH PHENOL/FORMALDEHYDE
CAS:25265-17-2
< Wt:35.
Name:ISOPHORONE DIAMINE; (ISOPHORONEDIAMINE (IPD))
CAS:2855-13-2
< Wt:35.
Name:PHENOL
CAS:108-95-2
RTECS #:SJ3325000
< Wt:10.
OSHA PEL:19 MG/M3;5 PPM
ACGIH TLV:19 MG/M3;5 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED. CORR TO EYES,
RESP SYS, & SKIN. SEV EYE IRRIT. SEV RESP TRACT IRRIT. SEV SKIN
IRRIT. TARGET ORGANS: EYE, SKIN, LIVER/HEPATIC SYS, KIDNEY, SPLEEN,
PANCREAS, RESP SYS. ACUTE: PROD VAP IN LOW CONCS CAN CAUSE
LACRIMATION, CONJ & CORNEAL EDEMA WHEN ABSORBED INTO TISSUE OF EYE
FROM ATM. CORNEAL EDEMA MAY GIVE RISE TO PERCEPTION OF 'BLUE HAZ'
'OR FOG'' AROUND LIGHTS. EFT IS TRANSIEN T & HAS NO KNOWN RESIDUAL
EFT. BURNS OF EYE MAY CAUSE BLINDNESS. CNTCT W/SKIN MAY CAUSE
DRYNESS (DEFAT), ITCHING &/RASH. CNTCT OF UNDILUTED PROD
W/EYES/SKIN QUICKLY CAUSES SEV IRRIT & PAIN & MAY CAUSE BURNS,
NECROSIS & (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ: PERM INJURY. INGEST MAY CAUSE DEATH
UNLESS TREATED PROMPTLY. INHAL OF VAPS MAY SEVERELY DMG CONTACTED
TISS & PRDCE SCARRING. INHAL OF AEROSOLS & MISTS MAY SEVERLY DMG
CONTACTED TISSUE & PROD UCE SCARRING. PROD IS READILY ABSORBED
THROUGH SKIN & MAY CAUSE NAUSEA, HDCH & GEN DISCOMFORT. SIGNS &
SYMPS OF EXPOS (POSS LONG TERM EFTS): REPEATED &/ PRLNG EXPOS MAY
RESULT IN: LIVER DISORDERS (SUC H AS JUNDICE/LIVER ENLARGEMENT),
KIDNEY DISORDERS (SUCH AS EDEMA/PROTEINURIA), ADVERSE RESP EFTS
(SUCH AS COUGH, TIGHTNESS OF CHEST/SHORTNESS OF BREATH), ADVERSE
EYE EFTS (SUCH AS CONJ/CORNEAL DMG), ( SUPDAT)
Medical Cond Aggravated by Exposure:ASTHMA. CHRONIC RESPIRATORY DISEASE
(E.G. BRONCHITIS, EMPHYSEMA). EYE DISEASE. KIDNEY DISORDERS. LIVER
DISORDERS. SKIN DISORDERS AND ALLERGIES.
======================= First Aid Measures =======================
First Aid:EYE: HOLD EYELIDS APART & IMMED FLUSH W/PLENTY OF H*2O FOR AT
LEAST 15 MIN. SEEK MED ADVICE. SKIN: REMOVE PROD & IMMED FLUSH
AFFECTED AREA W/H*2O FOR AT LEAST 15 MIN. REMOVE CONTAMD CLTHG &
SHOES. DES TROY CONTAMD LEATHER APPAREL. COVER AFFECTED AREA
W/STERILE DRESSING/CLEAN SHEETING & TRANSPORT FOR MED CARE. DO NOT
APPLY GREASES/OINTMENTS. CONTROL SHOCK, IF PRESENT. LAUNDER CONTAMD
CLTHG PRIOR TO REUSE. INHAL: MOVE PATIENT TO FRESH AIR. IF
BREATHING HAS STOPPED/IS LABORED GIVE ASSISTED RESP (E.G.
MOUTH-TO-MOUTH). PVNT ASPIR OF VOMIT. TURN VICTIM'S HEAD TO SIDE.
SEEK MED ADVICE. (OTHER INFO)
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:=110.C, 230.F
Extinguishing Media:IGNITION WILL GIVE RISE TO A CLASS B FIRE. IN CASE
OF LARGE FIRE USE: WATER SPRAY, ALCOHOL FOAM. IN CASE OF SMALL FIRE
USE: CARBON DIOXIDE (CO*2), DRY CHEMICAL, DRY SAND/LIMESTONE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . RETAIN EXPENDED LIQUIDS FROM FIRE FIGHTING FOR LATER
DISPOSAL.
Unusual Fire/Explosion Hazard:MAY GENERATE TOXIC OR IRRITATING
COMBUSTION PRODUCTS. CONTACT OF LIQUID WITH SKIN MUST BE PREVENTED.
MAY GENERATE CARBON MONOXIDE GAS. MAY GENERATE TOXIC NITROGEN OXIDE
GASES. MAY GENERATE AMMONIA GAS . PERSONNEL IN VICINITY AND
DOWNWIND SHOULD BE EVACUATED.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAINMENT TECHNIQUES (REMOVAL OF IGNITION
SOURCES, DIKING ETC): STOP LEAK, IF POSS. VENT SPACE INVOLVED.
REDUCE VAP SPREADING W/H*2O SPRAY. SHUT OFF/REMOVE ALL IGNITION
SOURCES. CONSTRUCT A DIKE TO PVNT SPREADING. CLEAN-UP PROC: IF
RECOVERY IS NOT FEASIBLE, ADMIX W/DRY SOIL, SAND/NON-REACTIVE
ABSORB & PLACE IN CNTNR/DUMPSTER PENDING DISPOSAL. TRANSFER TO
CNTNRS BY SUCTION, (OTHER INFO)
====================== Handling and Storage ======================
Handling and Storage Precautions:STORAGE: KEEP AWAY FROM: ACIDS,
OXIDIZERS. KEEP IN COOL, DRY, VENTILATED STORAGE AND IN CLOSED
CONTAINERS. DO NOT STORE IN IRON OR OTHER REACTIVE METAL
CONTAINERS. HANDLING: AVOID CONTACT WITH SKIN OR EYES. AVOID
BREATHING OF VAPORS. HANDLE IN WELL VENTILATED WORK SPACE.
Other Precautions:AVOID USING IN ANY SPRAY APPLICATION WITHOUT STRICT
CONFORMANCE TO ALL APPLICABLE ELECTRICAL CODES AND THE OSHA LIMIT
FOR MAXIMUM ALLOWABLE AIRBORNE CONCENTRATIONS. EMERGENCY SHOWERS
AND EYE WASH STAT IONS SHOULD BE READILY ACCESSIBLE. ADHERE TO WORK
PRACTICE RULES ESTABLISHED BY GOVERNMENT REGULATIO NS (E.G. OSHA).
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT REQUIRED UNDER NORMAL CNDTNS IN WELL-VENT
WORKPLACE. UNDER FOLLOWING CNDTNS RESP MAY BE REQD: WHEN PROD VAP
CONC EXCEEDS LIMITS LISTED IN SECTION 2, DURING REPAIR & CLEANING
OF EQUIP, DURING TRAN SFER/DISCHARGE OF PROD, SAMPLING, SPRAY
APPLICATIONS. FOR A COMPLETE LISTING OF RESPIRATORY PROTECTION
CONTACT NEHC .
Ventilation:MAINTAIN AIR CONCENTRATIONS IN WORK SPACES IN ACCORD WITH
STANDARDS OUTLINED IN SECTIONS 2 AND 3.
Protective Gloves:NEOPRENE RUB/IMPERMEABLE/CUFFED BUTYLRUB/NITRILE RUB/
POLYVINYL CHLORIDE.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGTH
FACESHIELD .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
IMPERVIOUS CLOTHING. SLICKER SUIT. RUBBER BOOTS. FULL RUBBER SUIT
(RAIN GEAR). BUTYL OR LATEX PROTECTIVE CLOTHING.
Work Hygienic Practices:WHEN HANDLING, DO NOT EAT, DRINK/SMOKE. WASH AT
END OF EACH WORKSHIFT & BEFORE EATING , SMOKING/USING TOILET.
PROMPTLY REMOVE CLTHG THAT BECOMES CONTAMD. USE APPROP HAND & SKIN
LOTIONS (OTHER INFO)
Supplemental Safety and Health
HLTH HAZ: ADVERSE SKIN EFTS (SUCH AS DEFAT, RASH/IRRIT), ADVERSE SKIN
EFTS (SUCH AS RASH, IRRIT/CORR). EFTS FROM INHAL OF VAPS MAY BE
DELAYED. DRYNESS OF NASAL PASSAGES MAY BE EXPERIENCED WHEN MATL IS
INHALED OVER LONG PERIOD OF TIME. RPTD &/PRLNG EXPOS TO LOW CONC OF
VAP MAY CAUSE: SORE THROAT WHICH ARE TRANSIENT.
================== Physical/Chemical Properties ==================
Boiling Pt:=204.C, 399.2F
Vapor Pres:(MM HG @ 21C(70F):<10.34
Spec Gravity:1.02 (H*2O=1)
pH:ALKALINE
Solubility in Water:<1.00%
Appearance and Odor:STRAW YELLOW MOBILE LIQUID WITH IRRITATING ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MINERAL ACIDS (I.E. SULFURIC, PHOSPHORIC, ETC.). ORGANIC ACIDS (I.E.
ACETIC ACID, CITRIC ACID ETC.). OXIDIZING AGENTS (I.E.
PERCHLORATES, NITRATES ETC.). FOR A COMPLETE LISTING OF MATERIALS
TO AVOID CONTACT NEHC .
Hazardous Decomposition Products:(FROM BURNING, HEATING/RXN W/OTHER
MATLS). CARBON MONOXIDE IN FIRE. CARBON DIOXIDE IN A FIRE. AMMONIA
WHEN HEATED. NITROGEN OXIDES IN A FIRE. FOR A COMPLETE LISTING OF
HAZ DECOMP PROD CNTCT NEHC .
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:ACUTE ORAL TOXICITY (LD50, RAT) 1752.00
MG/KG. ACUTE DERMAL TOXICITY (LD50, RABBIT) >2000.00 MG/KG (NO
DEATHS). ACUTE INHALATION TOXICITY (LC50, RAT) NO DATA. OTHER ACUTE
EFFECTS: NO DATA. IRRITATION EFFECTS DATA: CORROSIVE TO THE SKIN
OF A RABBIT. CHRONIC/SUBCHRONIC DATA: ABSORPTION OF PHENOLIC
SOLUTIONS THROUGH THE SKIN MAY BE VERY RAPID & CAN CAUSE DEATH.
LESSER EXPOSURES CAN CAUSE DAMAGE TO TH E KIDNEYS, LIVER, PANCREAS,
& SPLEEN, & EDEMA OF THE LUNGS. CHRONIC EXPOSURES CAN CAUSE DEATH
FROM LIVER & KIDNEY DAMAGE. THIS PRODUCT HAS BEEN TESTED & SHOWN
NOT TO CAUSE SENSITIZATION IN GUINEA PIGS .
===================== Ecological Information =====================
Ecological:ENVIRONMENTAL FATE: 2855-13-2 ISOPHORONEDIAMINE:
BIODEGRADABLE. 108-95-2 PHENOL: BIODEGRADABILITY = 99.5% AT 7 DAYS.
ADDITIONAL INFORMATION: NO DATA.
==================== Disposal Considerations ====================
Waste Disposal Methods:COMPLY WITH ALL FEDERAL, STATE AND LOCAL
REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:DOT NON-BULK SHIPPING NAME: AMINES, LIQUID
CORROSIVE, N.O.S. (ISOPHORONEDIAMINE) // 8 // UN2735 // PG III. DOT
BULK SHIPPING NAME: REFER TO AIR PRODUCTS BILL OF LANDING. IMO
SHIPPING DATA: REFER TO AI R PRODUCTS BILL OF LANDING. ICAO/IATA
SHIPPING DATA: AMINES, LIQUID, CORROSIVE, N.O.S.
(ISOPHORONEDIAMINE) // 8 // UN2735 // III // SHIPMENT PER 49 CFR
171.11.
===================== Regulatory Information =====================
SARA Title III Information:EPA SARA TITLE III SECTION 312 (40CFR370)
HAZ CLASS IMMED HLTH HAZ. EPA SARA TITLE III SECTION 313 (40CFR372)
TOX CHEMS ABOVE " DEMINIMIS" LEVEL ARE PHENOL. EUROPEAN ECONOMIC
COMMUNITY (EEC): EINECS M ASTER INVENTORY: INCLUDED ON INVENTORY.
EEC SYMBOL: CORROSIVE (C). EEC RISK (R) PHRASES: CAUSES BURNS
(R34). HARMFUL BY INHAL & IF SWALLOWED (R20/22). EEC SAFETY
PHRASES: IN CASE OF CONTACT W/EYES, RI NSE IMMED W/PLENTY OF WATER
& SEEK MED ADVICE (S26). WEAR SUITABLE PROT CLOTHING, GLOVES &
EYE/FACE PROTECTION (S36/37/39). IN CASE OF ACCIDENT/IF YOU FEEL
UNWELL, SEEK MED ADVICE IMMED (SHOW THE LABE L WHERE POSSIBLE)
(S45).
Federal Regulatory Information:U S FEDERAL REGULATIONS: TOXIC
SUBSTANCES CONTROL ACT (TSCA)-ALL COMPONENTS ARE INCLUDED IN THE
EPA TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCE
INVENTORY. OSHA HAZARD COMMUNICATION STANDAR D (29CFR1910.1200)
HAZARD CLASS(ES) CORROSIVE, LIVER TOXIN, KIDNEY TOXIN.
INTERNATIONAL REGULATIONS: CANADA: DSL: INCLUDED ON INVENTORY.
WHMIS HAZARD CLASSIFICATION: CLASS E CORROSOVE. WHMIS TRADE SEC RET
REGISTRY NUMBER(S): NONE. WHMIS SYMBOLS: TEST TUBE/HAND.
State Regulatory Information:PROPOSITION 65 SUBSTANCES (COMPONENT(S)
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND/OR
REPRODUCTIVE TOXICITY AND SUBJECT TO WARNING AND DISCHARGE
REQUIREMENTS UNDER THE "SAFE DRINKING WATER A ND TOXIC ENFORCEMENT
ACT OF 1986"): NONE. NEW JERSEY TRADE SECRET REGISTRY NUMBER(S):
NONE.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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