===================== Product Identification =====================
MSDS NAME:PL-400, 72-400
NIIN:00N092252
Status Code:A
MSDS Number: CJQNX
=== Responsible Party ===
Company:OSI SEALANTS INC
Address:7405 PRODUCTION DR
City:MENTOR
State:OH
ZIP:44060
Country:US
Info Phone Num:440-225-8900
Emergency Phone Num:800-424-9300
Preparer's Name:MARK HORTON
Chemtrec Ind/Phone:(800)424-9300
CAGE:TO261
=== Contractor Identification ===
Company:OSI SEALANTS INC
Address:7405 PRODUCTION DR
Box:City:MENTOR
State:OH
ZIP:44060
Country:US
Phone:440-225-8900
CAGE:TO261
============= Composition/Information on Ingredients =============
Name:TOLUENE. LD50 (ORAL, RAT): 636 MG/KG
CAS:108-88-3
RTECS #:XS5250000
< Wt:15.
OSHA PEL:see Table Z-2
ACGIH TLV:188 MG/M3;50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:N-HEXANE. LD50 (ORAL, RAT): 45 ML/KG
CAS:110-54-3
RTECS #:MN9275000
< Wt:30.
OSHA PEL:1800 MG/M3;500 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:SILICA, CRYSTALLINE-QUARTZ; (SILICA, QUARTZ)
CAS:14808-60-7
RTECS #:VV7330000
< Wt:1.
OSHA PEL:see Table Z-3
ACGIH TLV:0.1 MG/M3
Name:CALCIUM CARBONATE; (CALCIUM CARBONATE MANUFACTURED). LD50
(ORAL, RAT): 6450 MG/KG
CAS:471-34-1
RTECS #:FF9335000
< Wt:35.
OSHA PEL:15 MG/M3
Name:SILICA; (SILICA, AMORPHOUS)
CAS:7631-86-9
< Wt:5.
OSHA PEL:6 MG/M3
Name:1,3-BUTADIENE
CAS:106-99-0
RTECS #:EI9275000
OSHA PEL:2200 MG/M3;1000 PPM
ACGIH TLV:4.4 MG/M3;2 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:LEAD; (INORGANIC LEAD)
CAS:7439-92-1
RTECS #:OF7525000
ACGIH TLV:0.15 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:ARSENIC
CAS:7440-38-2
RTECS #:CG0525000
ACGIH TLV:0.01 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: IRRIT, BUT WILL NOT
PERMANENTLY INJURE EYE TISS. SKIN: CAUSES IRRIT. ALLERGIC RXNS ARE
POSS. INHAL: HDCHS, DIZZ, NAUS, DECREASED BLOOD PRESS, CHANGES IN
HEART RATE & CYANOSIS MAY RESULT F ROM OVER-EXP TO VAP. MAY CAUSE
RESP TRACT IRRIT. INGEST: IRRIT TO MOUTH, THROAT & STOMACH.
CHRONIC: CHRONIC: TOLUENE & LEAD APPEAR ON NAVY LISTING OF OCCUP
CHEM REPROD HAZS. SEEK CONSULTATION FROM APP ROPRIATE HLTH
PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS
INFO . CHRONIC INHAL OF TOLUENE VAP CAN PRODUCE DEPRESSION TO CNS,
LEADING TO FAINTING, DIFFICULTY IN BRTHG, NAUS , VOMIT, & MEMORY
LOSS.(EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE - QUARTZ: IARC
MONOGRAPHS. VOL 68, PG 41, 1997: GROUP 1. NTP 8TH ANNUAL REPORT ON
CARCINOGENS, 1998: REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN.
ARSENIC: IARC MONOGRAPHS, SUPP LEMENT VOL 7, PG 100, 1987:GRP 1.
NTP 8TH ANNUAL REPORT ON CARC, 1998: KNOWN TO BE HUMAN CARCIN.
Effects of Overexposure:HLTH HAZ: THIS PRODUCT CONTAINS SOLVENTS.
REPORTS ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE
TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. REPORTS
ALSO INDICATE THAT SOL VENTS CAUSE LIVER DAMAGE, KIDNEY DAMAGE,AND
MUCOUS MEMBRANE IRRITATION. BE WARNED THAT INTENTIONAL MISUSE BY
DELIBERATELY INHALING THE VAPORS AND/OR THE PRODUCT CONTENTS (A
PROCESS OFTEN CALLED "SNIFF ING") MAY BE HARMFUL OR FATAL.
PREEXISTING RESPIRATORY OR SKIN CONDITION(S) MAY BE AGGRAVATED BY
EXPOSURE. OVEREXPOSURE MAY CAUSE NASAL DAMAGE.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/H*2O FOR AT LEAST 15 MIN. GET MED ATTN. SKIN:
REMOVE CONTAMD CLTHG & SHOES. WASH AFFECTED AREA(S) THOROUGHLY
W/SOAP & H*2O. IF IRRIT PERSIST, SEEK MED ATTN. INHAL: REMOVE TO
FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DIFFICULT,
GIVE OXYGEN. GET IMMED MED ATTN. INGEST: GET MED ATTN IMMED. IF
SWALLOWED. DO NOT INDUCE VOMIT. GIVE VICTIM GLASS OF WATER OR MILK.
CALL MD/POIS CTL CTR IMMED. NEVER GIVE ANYTHING BY MOUTH TO UNCON
PERS. SHOULD VOMITING OCCUR, BE SURE TO KEEP VICTIM'S HEAD BELOW
HIPS TO AVOID ASPIRATION OF VOMITUS INTO LUNGS.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:=22.2C, 72.F
Lower Limits:1.2%
Upper Limits:7.5%
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . MAY BE IGNITED BY HEAT, SPARKS OR FLAME. CONTAINERS
EXPOSED TO FIRE SHOULD BE KEPT COOL WITH WATER SPRAY. CONTAINERS
CAN BUILD UP PRESSURE I F EXPOSED TO HEAT (FIRE).
Unusual Fire/Explosion Hazard:FIRE PRODUCES IRRIT/POISONOUS GAS. VAPS
MAY FORM EXPLOSIVE MIX W/AIR. VAP CAN TRAVEL TO SOURCE OF IGNITION
& FLASH BACK. "EMPTY" CNTNRS RETAIN PROD RESIDUE (LIQ &/VAP) & CAN
BE DANGEROUS. DO NOT PRESS URIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND/EXPOSED SUCH CNTNRS TO HEAT, FLAME, SPARKS, STATIC
ELECTRICITY, (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:VENT AREA & REMOVE ALL SOURCES OF IGNITION.
EVACUATE UNNECESSARY PERSONNEL. LARGE SPILLS SHOULD BE HANDLED
CAREFULLY. PUT ON RESP PROT & NECESSARY PERS PROT EQUIP. DIKE/
IMPOUND SPILLED LIQ. ABSORB SP ILL W/INERT MATL (E.G. DRY
SAND/EARTH), THEN PLACE IN CHEM WASTE CONTAINER. REPEAT
SORBENT/SWEEP CYCLE UNTIL SPILL HAS DRIED UP. AVOID RUNOFF INTO
STORM SEWERS & DITCHES WHICH LEAD TO WATERWAYS.
====================== Handling and Storage ======================
Handling and Storage Precautions:HANDLING: USE ONLY IN A WELL
VENTILATED AREA. KEEP OUT OF REACH OF CHILDREN. GROUND AND BOUND
CONTAINERS WHEN TRANSFERRING MATERIAL. IF USER OPERATIONS GENERATE
DUST, FUME, OR MIST, USE VENTILATION TO KEEP EXPOSURE TO AIRBORNE
CONTAMINENTS BELOW THE EXPOSURE LIMITS.
Other Precautions:STORAGE: KEEP AWAY FROM HEAT, SPARKS AND FLAME. KEEP
CONTAINER CLOSED WHEN NOT IN USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH APPROVED RESPIRATORY PROTECTION WHEN
THE PRODUCT IS MIXED OR APPLIED IN A POORLY VENTILATED AREA OR IF
WORKPLACE LEVELS OF INGREDIENTS EXCEED THE TLV. FOLLOW APPLICABLE
FEDERAL, STATE, AND LOCAL REGULATIONS.
Ventilation:LOCAL EXHAUST VENT MAY BE NECESSARY TO CONTROL ANY AIR
CONTAMINANTS TO WITHIN THEIR TLVS DURING THE USE OF THIS PRODUCT.
Protective Gloves:RUBBER, NEOPRENE OR VINYL ALCOHOL GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA .
Work Hygienic Practices:DO NOT TAKE INTERNALLY. REMOVE CONTAMINATED
CLOTHING AND WASH BEFORE REUSE. AVOID CONTACT WITH EYES, SKIN, AND
CLOTHING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:>65.C, 149.F
B.P. Text:149-232F
Vapor Density:HVR/AIR
Spec Gravity:1.1500
Evaporation Rate & Reference:SLOWER THAN BUTYL ACETATE
Solubility in Water:SLIGHT <0.1%
Appearance and Odor:SOLID SEMI-PASTE; STRONG SOLVENT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH OXIDIZING MATERIAL.
Stability Condition to Avoid:SOURCES OF IGNITION. LONG TERM EXPOSURE TO
ELEVATED TEMPERATURES.
Hazardous Decomposition Products:NO INFORMATION.
Conditions to Avoid Polymerization:WILL NOT OCCUR UNDER NORMAL
CONDITIONS.
=================== Toxicological Information ===================
Toxicological Information:PRODUCT DERMAL LD50, PRODUCT ORAL LD50,
PRODUCT LC50: NO INFORMATION. COMPONENT TOXICOLOGICAL INFORMATION:
CHEMICAL NAME: TOLUENE. DERMAL LD50: 12124 MG/KG. LC50: 49
GM/M3/4H. N-HEXANE: LC50 48000 P PM/4H.
===================== Ecological Information =====================
Ecological:NO INFORMATION.
==================== Disposal Considerations ====================
Waste Disposal Methods:REVIEW ALL LOCAL, STATE, AND FEDERAL REGULATIONS
CONCERNING HEALTH AND POLLUTION FOR APPROPRIATE DISPOSAL
PROCEDURES.
=================== MSDS Transport Information ===================
Transport Information:DOT PROPER SHIPPING NAME: ADHESIVE. DOT HAZARD
CLASS: FLAMMABLE LIQUID. HAZARD SUBCLASS: N/A. DOT UN/NA NUMBER:
UN1133. PACKING GROUP: III. DOT PLACARD AT: 1000 LBS. DOT CLASS
NUMBER: 3. UN PROPER SH IPPING NAME: ADHESIVE. UN HAZARD CLASS:
FLAMMABLE LIQUID. UN CLASS NUMBER: AIR 3. MARINE: 3. HAZARD
SUBCLASS: AIR. N/A MARINE: N/A. UN UN/NA NUMBER: UN1133. UN
PACKING GROUP: AIR III. MARINE: III. IN PLACARD AT: N/A.
===================== Regulatory Information =====================
SARA Title III Information:CERCLA - SARA HAZARD CATEGORY: THIS PROD HAS
BEEN REVIEWED ACCORDING TO THE EPA 'HAZ CATEGORIES' PROMULGATED
UNDER SECTION 311 & 312 OF THE SARA TITLE III AND IS CONSIDERED,
UNDER APPLICABLE DEFINITIO NS, TO MEET THE FOLLOWING CATEGORIES:
IMMED HEALTH HAZ CHRONIC HEALTH HAZ. THIS PRODUCT CONTAINS THE
FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING REQUIREMENTS OF
SECTION 313 OF TITLE III OF THE SUPER FUND AMENDMENTS AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372: CHEMICAL NAME:
TOLUENE. CAS NUMBER: 108-88-3.WT/WT % LESS THAN 15.0%. CHEMICAL
NAME: N-HEXANE. CAS NUMBER: 110-54-3. WT/WT % IS LES S THAN 30.0%.
Federal Regulatory Information:U. S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION STANDARD (29
CFR 1910.1200). INTETNATIONAL REGULATIONS: AS FOLLOWS-CANADA WHMIS:
THIS MSDS HAS BEEN PREPAR ED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS. CANADIAN WHMIS
CLASS: NO INFORMATION AVAILABLE.
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING: THE
CHEMICAL(S) NOTED BELOW AND CONTAINED IN THIS PRODUCT, ARE KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM: CHEMICAL NAME: 1, 3-BUTADIENE. CAS NUMBER:
106-99-0. CHEMICAL NAME: TOLUENE. CAS NUMBER: 108-88-3. CHEMICAL
NAME: SILICA, QUARTZ. CAS NUMBER: 14808-60-7. CHEMICAL NAME:
INORGANIC LEAD. CAS NUMBER: 7439-92-1. C HEMICAL NAME: ARSENIC. CAS
NUMBER: 7440-38-2.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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