===================== Product Identification =====================
MSDS NAME:5614/5113/5114 BLACK DRY INK/TONER (REPLENISHER), 502S63961
NIIN:00N078035
Status Code:A
MSDS Number: CJQPV
=== Responsible Party ===
Company:XEROX CORPORATION
Address:100 N MUSTARD RD
City:OKLAHOMA CITY
State:OK
ZIP:73126
Country:US
Info Phone Num:800-828-6571
Emergency Phone Num:716-422-2177
Resp. Party Other MSDS Num.:A-0124; 602E03130
CAGE:TO144
=== Contractor Identification ===
Company:NAVY ENVIRONMENTAL HEALTH CENTER
Address:2510 WALMER AVENUE
Box:City:NORFOLK
State:VA
ZIP:23513-2617
Country:US
Phone:804-444-4657, DSN 564-4657 X 272
CAGE:SO010
Company:XEROX CORPORATION
Address:100 N MUSTARD RD
Box:City:OKLAHOMA CITY
State:OK
ZIP:73126
Country:US
Phone:800-828-6571
CAGE:TO144
============= Composition/Information on Ingredients =============
Name:TONER CONTAINING STYRENE/ACRYLATE POLYMER, CARBON BLACK,
POLYPROPYLENE WAX, STYRENE-ETHYLENE/BUTYLENE COPOLYMER.
Minumum % Wt:75.
Maxumum % Wt:90.
Name:STYRENE-BUTYL ACRYLATE POLYMER; (STYRENE/ACRYLATE POLYMER)
CAS:25767-47-9
Minumum % Wt:80.
Maxumum % Wt:90.
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) >5 G/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:MINIMAL RESPIRATORY TRACT
IRRITATION MAY OCCUR AS WITH EXPOSURE TO LARGE AMOUNTS OF ANY
NON-TOXIC DUST. CHRONIC:RESULTS OBTAINED FROM A XEROX SPONSORED,
CHRONIC TONER INHAL STUDY, DEMONSTRATED N O LUNG CHANGE IN RATS FOR
LOWEST (1 MG/M3) EXPOS LEVEL (I.E. LEVEL MOST RELEVANT TO POTNTL
HUMAN EXPOS). A VERY SLIGHT DEGREE OF FIBROSIS WAS NOTED IN 25% OF
ANIMALS AT MIDDLE (4 MG/M3) EXPOS LEVEL, W HILE A SLIGHT DEGREE OF
FIBROSIS WAS NOTED IN ALL ANIMALS AT HIGHEST (16 MG/M3) EXPOS
LEVEL. THESE FINDINGS ARE ATTRIBUTED TO "LUNG OVERLOADING", A
GENERIC RESPONSE TO EXCESSIVE AMTS OF ANY DUST RETAI NED IN LUNGS
FOR (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CARBON BLACK:IARC MONOGRAPHS ON
EVALUATION OF CARCINOGENIC RISK OF CHEMICAL TO MAN:VOL 65, PG
24-27, 1995:GROUP 2B.
Effects of Overexposure:HLTH HAZ: PRLNG PERIOD. THIS STUDY WAS
CONDUCTED USING A SPECIAL TEST TONER TO COMPLY W/EPA TESTING
PROTOCOL. THE TEST TONER WAS TEN TIMES MORE RESPIRABLE THAN
COMMERCIALLY AVAIL XEROX TONER & WOULD NOT BE FUNCTIONALLY
SUITABLE FOR XEROX EQUIPMENT. MORE RESPIRABLE THAN COMMERCIALLY
AVAIL XEROX TONER & WOULD NOT BE FUNCTIONALLY SUITABLE FOR XEROX
EQUIPMENT.
Medical Cond Aggravated by Exposure:NONE WHEN USED AS DESCRIBED BY
PRODUCT LITERATURE.
======================= First Aid Measures =======================
Eyes:FLUSH W/WATER FOR AT LEAST 15 MINUTES. SKIN:WASH W/SOAP
& WATER. INHAL:REMOVE FROM EXPOSURE. INGEST:DILUTE STOMACH CONTENTS
W/SEVERAL GLASSES OF WATER.
===================== Fire Fighting Measures =====================
Lower Limits:N.A.
Upper Limits:N.A.
Extinguishing Media:WATER, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . AVOID INHALATION OF SMOKE.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP/VACUUM SPILLED TONER & CAREFULLY
TRANSFER INTO SEALABLE WASTE CNTNR. SWEEP SLOWLY TO MIN GENERATION
OF DUST DURING CLEAN-UP. IF VACUUM IS USED, MOTOR MUST BE RATED AS
DUST TIGHT. CONDUCTIVE H OSE BONDED TO MACHINE SHOULD BE USED TO
REDUCE STATIC BUILDUP (SEE FIRE & EXPLO DATA SECTION). RESIDUE CAN
BE REMOVED W/SOAP & COLD WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID PROLONGED INHALATION OF
EXCESSIVE DUST.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WHEN USED AS INTENDED IN XEROX
EQUIPMENT. USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN .
Protective Gloves:IMPERVIOUS GLOVES .NONE REQUIRED WHEN USED AS
INTENDED IN XEROX EQUIP.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH & DELUGE SHOWER MTG ANSI DESIGN
CRITERIA . FOR USE OTHER THAN NORMAL CUSTOMER - OPERATING
PROCEDURES (SUCH AS IN BULK TONER PROCESSING FACILITIES), GOGGLES &
RESP MAY BE REQUIRED. (SUPDAT)
Supplemental Safety and Health
OTHER PROT EQUIP: FOR MORE INFO,CNTCT XEROX. TOX INFO:PEL:15 MG/M3
(TOTAL DUST). 5 MG/M3 (RESP DUST).STEL:NE. CEILING: NE. XEROX EXPOS
LIMIT:2.5 MG/M3 (TOTAL DUST) 0.4 MG/M3 (RESP DUST). TOX INFO: ADD N
INFO: RSLTS OBTAINED FROM XEROX SPONSORED, CHRONIC TONER INHAL
STUDY, DEMONSTRATED NO LUNG CHANGE IN RATS(OTHER INFO)
================== Physical/Chemical Properties ==================
Spec Gravity:5 (H*2O=1)
Appearance and Odor:BLACK GRANULAR; FAINT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:PRODUCTS OF COMBUSTION MAY BE TOXIC.
AVOID BREATHING SMOKE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS .
INCINERATE ONLY IN CLSD CNTNR. THIS MATL IS NOT HAZ WASTE ACCORDING
TO FED (40 CFR 261). STATE & LOC WASTE DISP REQUIREMENTS MAY
HOWEVER, BE MORE RESTR ICTIVE. CONSULT W/APPROP STATE & LOC AUTHS
FOR SPECIFIC INFO.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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