===================== Product Identification =====================
MSDS NAME:TITANIUM IV BUTOXIDE, 77124
NIIN:00N092841
Status Code:A
MSDS Number: CJVRD
=== Responsible Party ===
Company:JOHNSON MATTHEY CATALOG CO INC
Address:30 BOND ST
City:WARD HILL
State:MA
ZIP:01835-8099
Country:US
Info Phone Num:978-521-6300
Emergency Phone Num:978-521-6300
Preparer's Name:DARREL SANDERS
Chemtrec Ind/Phone:(800)424-9300
CAGE:0JVJ1
=== Contractor Identification ===
Company:JOHNSON MATTHEY CATALOG CO INC ALFA AESAR
Address:30 BOND ST
Box:City:WARD HILL
State:MA
ZIP:01835-0747
Country:US
Phone:978-521-6300
CAGE:0JVJ1
============= Composition/Information on Ingredients =============
Name:TITANIUM(IV) BUTOXIDE LD50: (ORAL, RAT) 3122 MG/KG
CAS:5593-70-4
RTECS #:XR1585000
= Wt:100.
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE TOXICITY: PRIMARY IRRITANT
EFFECT: ON THE SKIN: CORROSIVE EFFECT ON SKIN AND MUCOUS MEMBRANES.
IRRITANT TO SKIN AND MUCOUS MEMBRANES. ON THE EYE: STRONG CORROSIVE
EFFECT. IRRITATING EFFECT. SENS ITIZATION: NO SENSITIZING EFFECTS
KNOWN. SUBACUTE TO CHRONIC TOXICITY: TITANIUM AND TITANIUM
COMPOUNDS ARE CONSIDERED PHYSIOLOGICALLY INERT. THERE ARE NO
REPORTED CASES IN THE LITERATURE WHERE TITANIU M AS SUCH HAS CAUSED
HUMAN INTOXICATION. ADDITIONAL TOXICOLOGICAL INFORMATION:
SWALLOWING WILL LEAD TO A STRONG CORROSIVE EFFECT ON MOUTH AND
THROAT AND TO THE DANGER OF PERFORATION OF ESOPHAGUS AND ( EFFECTS
OF OVEREXPOSURE)
Effects of Overexposure:HEALTH HAZARDS: STOMACH. TO THE BEST OF OUR
KNOWLEDGE THE ACUTE AND CHRONIC TOXICITY OF THIS SUBSTANCE IS NOT
FULLY KNOWN. NO CLASSIFICATION DATA ON CARCINOGENIC PROPERTIES OF
THIS MATERIAL IS AVAILAB LE FROM THE EPA, IARC, NTP, OSHA OR ACGIH.
======================= First Aid Measures =======================
First Aid:GENERAL INFORMATION: IMMEDIATELY REMOVE ANY CLOTHING SOILED
BY THE PRODUCT. INHALATION: SUPPLY FRESH AIR. IF REQUIRED, PROVIDE
ARTIFICIAL RESPIRATION. KEEP PATIENT WARM. SEEK IMMEDIATE MEDICAL
ADVICE. SKIN CONTACT: IMMEDIATELY WASH WITH WATER AND SOAP AND
RINSE THOROUGHLY. SEEK IMMEDIATE MEDICAL ADVICE. EYE CONTACT: RINSE
OPENED EYE FOR AT LEAST 15 MINUTES UNDER RUNNING WATER. THEN
CONSULT A DOCTO R. INGESTION: SEEK IMMEDIATE MEDICAL ADVICE.
===================== Fire Fighting Measures =====================
Flash Point:=50.C, 122.F
Lower Limits:NOT DETERM
Upper Limits:NOT DETERM
Extinguishing Media:EXTINGUISHING POWDER. DO NOT USE WATER. FOR SAFETY
REASONS UNSUITABLE EXTINGUISHING AGENTS: WATER.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:PRODUCT IS NOT EXPLOSIVE. HOWEVER,
FORMATION OF EXPLOSIVE AIR/VAPOR MIXTURES ARE POSSIBLE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROT EQUIP. KEEP UNPROTECTED PERS AWAY.
ENSURE ADEQ VENT. KEEP AWAY FROM IGNIT SOURCE. DO NOT ALLOW MATL TO
BE RELEASED TO THE ENVIRONMENT W/OUT PROPER GOVT PERMITS. ABSORB
W/LIQ-BINDING MATL (SA ND, DIATOMITE, ACID BINDERS, UNIVERSAL
BINDERS, SAWDUST). USE NEUTRALIZING AGENT. DISPOSE CONTAM MATL AS
WASTE ACCORDING TO SECTION 13, DISP CONSIDERATIONS. ENSURE ADEQ
VENT. KEEP AWAY FROM (SUPDAT)
====================== Handling and Storage ======================
Handling and Storage Precautions:INFO ON SAFE HNDLG: KEEP CNTNR TIGHTLY
SEALED. STORE IN COOL, DRY PLACE IN TIGHTLY CLSD CNTNRS. ENSURE
GOOD VENT AT THE WORKPLACE. INFO ABOUT PROTECTION AGAINST
EXPLOSIONS & FIRES: KEEP IGNIT SOURCES AWAY. PROTECT AGAINST
ELECTROSTATIC CHARGES. FUMES CAN COMBINE W/AIR TO FORM AN EXPLOSIVE
MIXTURE.
Other Precautions:REQS TO BE MET BY STOREROOMS & RECEPTACLES: NO SPEC
REQS. INFO ABOUT STORAGE IN ONE COMMON STORAGE FACILITY: STORE AWAY
FROM OXIDIZING AGENTS. STORE AWAY FROM WATER/MOISTURE. FURTHER
INFO: KEEP CNTNR TIGHTLY SEALED. STORE IN COOL, DRY CNDTNS IN WELL
SEALED CNTNRS. STORE UNDER LOCK & KEY & W/ACCESS ( SUPDAT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE SUITABLE NIOSH APPROVED RESPIRATOR WHEN HIGH
CONCENTRATIONS ARE PRESENT.
Ventilation:PROPERLY OPERATING CHEMICAL FUME HOOD DESIGNED FOR
HAZARDOUS CHEMICALS AND HAVING AN AVERAGE FACE VELOCITY OF AT LEAST
100 FEET PER MINUTE.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGTH
FACESHIELD .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . PROTECTIVE WORK CLOTHING.
Work Hygienic Practices:THE USUAL PRECAUTIONARY MEASURES FOR HANDLING
CHEMS SHOULD BE FOLLOWED. KEEP AWAY FROM FOODSTUFFS, BEVERAGES &
FEED. REMOVE ALL SOILED & CONTAM CLTHG IMMED. WASH HANDS BEFORE
BREAKS (SUPDAT)
Supplemental Safety and Health
SPILL PROC: IGNIT SOURCES. SEE SECTION 7 FOR INFO ON SAFE HNDLG,
SECTION 8 FOR INFO ON PERSONAL PROT EQUIP & SECTION 13 FOR DISP
INFO. OTHER PRECS: RESTRICTED TO TECHNICAL EXPERTS OR THEIR
ASSISTANTS ONLY. HYGIENE PRACTS: AND AT THE END OF WORK.
================== Physical/Chemical Properties ==================
Boiling Pt:>310.C, 590.F
B.P. Text:310-314C
Melt/Freeze Pt:=-55.C, -67.F
Decomp Temp:Decomp Text:NOT DETERMINED
Vapor Pres:NOT DETERMINED
Spec Gravity:0.998
Solubility in Water:REACTS
Appearance and Odor:CLEAR LIQUID; ALCOHOL-LIKE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, WATER/MOISTURE, ACIDS. REACTS WITH WATER AND ACIDS.
Stability Condition to Avoid:DECOMPOSITION WILL NOT OCCUR IF USED AND
STORED ACCORDING TO SPECIFICATIONS.
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE.
=================== Toxicological Information ===================
Toxicological Information:SEE HEALTH HAZARDS.
===================== Ecological Information =====================
Ecological:DO NOT ALLOW MATERIAL TO BE RELEASED TO THE ENVIRONMENT
WITHOUT PROPER GOVERNMENTAL PERMITS.
==================== Disposal Considerations ====================
Waste Disposal Methods:PRODUCT: CONSULT STATE, LOCAL AND NATIONAL
REGULATIONS FOR PROPER DISPOSAL. UNCLEANED PACKAGINGS: DISPOSAL
MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:DOT REGS - HAZARD CLASS: 3. IDENTIFICATION
NUMBER: UN2924. PACKING GROUP: III. PROPER SHIPPING NAME (TECHNICAL
NAME): FLAMMABLE LIQUID, CORROSIVE, N.O.S., TITANIUM (IV) BUTOXIDE.
LAND TRANSPORT ADR/RI D (CROSS BORDER) = ADR/RID CLASS: 3. ITEM:
33C. DANGER CODE (KELMER): 38. UN NUMBER: 2924. DESCRIPTION OF
GOODS: FLAMMABLE LIQUID, CORROSIVE, N.O.S., TITANIUM (IV) BUTOXIDE.
MARITIME TRANSPORT IMDG - IMDG CLASS: 3. UN NUMBER: 2924.
PACKAGING GROUP: III. PROPER SHIPPING NAME: FLAMMABLE LIQUID,
CORROSIVE, N.O.S., TITANIUM (IV) BUTOXIDE. AIR TRANSPORT ICAO-TI &
IATA-DGR - ICAO/IATA CLASS: 3. (OTHER I NFO)
===================== Regulatory Information =====================
Federal Regulatory Information:PRODUCT RELATED HAZARD INFO - HAZARD
SYMBOLS: C CORROSIVE. RISK PHRASES: 10 FLAMMABLE. 34 CAUSES BURNS.
SAFETY PHRASES: 24/25 AVOID CONTACT WITH SIN AND EYES. 36/37/39
WEAR SUITABLE PROTECTIVE CLOTHIN G, GLOVES AND EYE/FACE PROTECTION.
NATIONAL REGULATIONS - ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN
THE US ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
CHEMICAL SUBSTANCE INVENTORY. INFO ABOUT LIMITATION OF USE: FOR
USE ONLY BY TECHNICALLY QUALIFIED INDIVIDUALS.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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