===================== Product Identification =====================
MSDS NAME:CUPRIC SULFATE PENTAHYDRATE APPROX 99%, C7631
NIIN:00N092447
Status Code:A
MSDS Number: CJVRJ
=== Responsible Party ===
Company:SIGMA CHEMICAL CO
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:314-771-5765
Emergency Phone Num:314-771-5765
CAGE:21076
=== Contractor Identification ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:CUPRIC SULFATE PENTAHYDRATE
CAS:7758-99-8
RTECS #:GL8900000
= Wt:99.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED. MAY BE
HARMFUL IF INHALED. MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.
CAUSES SEVERE EYE IRRITATION. CAUSES SKIN IRRITATION. MATERIAL IS
IRRITATING TO MUCOUS MEMBRANES AN D UPPER RESPIRATORY TRACT. MAY
CAUSE ALLERGIC SKIN REACTION. ABSORPTION INTO THE BODY LEADS TO THE
FORMATION OF METHEMOGLOBIN WHICH, IN SUFFICIENT CONCENTRATIONS,
CAUSES CYANOSIS. ONSET MAY BE DELAYED 2 TO 4 HOURS OR LONGER.
EXPOSURE CAN CAUSE DAMAGE TO THE EYES, GASTROINTESTINAL
DISTURBANCES. CHRONIC: POSSIBLE RISK OF CONGENITAL MALFORMATION IN
THE FETUS. MAY CAUSE REPRODUCTIVE DISORDERS. (EFFECT S OF
OVEREXPOSURE)
Effects of Overexposure:HEALTH HAZARDS: TARGET ORGANS: LIVER, KIDNEYS,
BLOOD. ADDITIONAL INFORMATION: CHRONIC COPPER POISONING IS TYPIFIED
BY HEPATIC CIRRHOSIS, BRAIN DAMAGE AND DEMYELINATION, KIDNEY
DEFECTS, AND COPPER DEPO SITION IN THE CORNEA AS EXEMPLIFIED BY
HUMANS WITH WILSON'S DISEASE. IT HAS ALSO BEEN REPORTED THAT COPPER
POISONING HAS LEAD TO HEMOLYTIC ANEMIA AND ACCELERATES
ARTERIOSCLEROSIS.
======================= First Aid Measures =======================
First Aid:SKIN: IMMEDIATELY WASH WITH SOAP AND COPIOUS AMOUNTS OF
WATER. EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. INHALATION: REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE AR TIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. INGESTION: WASH OUT MOUTH WITH WATER PROVIDED PERSON
IS CONSCIOUS. CALL A PHYSICIAN. REMOVE AND WASH CONTAMINATED
CLOTHING PROMPTLY.
===================== Fire Fighting Measures =====================
Extinguishing Media:NON-COMBUSTIBLE. USE EXTINGUISHING MEDIA
APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH APPROVED RESPIRATOR, CHEMICAL
SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP,
PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST.
VENTILATE AREA AND WASH SPILL S ITE AFTER MATERIAL PICKUP IS
COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE DUST. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . WEAR OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
TOX INFO: KIDNEY, URETER, BLADDER (OTHER CHANGES); BLOOD (HEMORR, OTHER
HEMOLYSIS W/OR W/OUT ANEMIA); NUTRITIONAL & GROSS METABOLIC (WT
LOSS/DECRD WT GAIN). ONLY SELECTED REGISTRY OF TOX EFTS OF CHEM
SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN
RTECS FOR COMPLETE INFO.
================== Physical/Chemical Properties ==================
Vapor Pres:7.3 MM @ 25C
Spec Gravity:2.284
Appearance and Odor:BLUE CRYSTALS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CORRODES STEEL. FINELY POWDERED METALS.
Stability Condition to Avoid:HEAT. SENSITIVE TO AIR. EFFLORESCENT.
Hazardous Decomposition Products:TOXIC FUMES OF SULFUR OXIDES.
=================== Toxicological Information ===================
Toxicological Information:RTECS #: GL8900000 - COPPER (II) SULFATE,
PENTAHYDRATE (1:1:5). TOXICITIY DATA: ORL-HMN LDLO: 1088 MG/KG;
IPRAA8 18, 807, 1965. UNR-MAN LDLO: 221 MG/KG; 85DCAI 2, 73, 1970.
ORL-RAT LD50: 300 MG/KG; 85 ARAE 2, 182, 1977. SKN-RAT LD50: >2
GM/KG; NNGADV 18, S161, 1993. IPR-RAT LD50: 18700 UG/KG; GISAAA 53
(4), 78, 1988. IPR-MUS LD50: 33 MG/KG; BCPCA6 14, 289, 1965.
IPR-MAM LD50: 7500 UG/KG; JANSAG 55, 337, 1982. TARGET ORGAN DATA:
AUTONOMIC NERV SYS (OTHER: PARASYMPATHOMIMETIC); BEHAVIORAL
(SOMNOLENCE, COMA); GI (CHANGES IN STRUCTURE/FUNC OF SALIVARY
GLANDS, HYPERMOTILITY, DIARR, NAUS/VOMIT); LIVE R (JAUN,
HEPATOCELLULAR); (SUP DAT)
===================== Ecological Information =====================
Ecological:DATA NOT YET AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL
SERVICE TO DISPOSE OF THIS MATERIAL. OBSERVE ALL FEDERAL, STATE AND
LOCAL ENVIRONMENTAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
===================== Regulatory Information =====================
SARA Title III Information:THIS PRODUCT IS SUBJECT TO SARA SECTION 313
REPORTING REQUIREMENTS - COPPER COMPOUNDS.
Federal Regulatory Information:EUROPEAN INFO: CAUTION: SUBSTANCE NOT
YET FULLY TESTED. HARMFUL. R 22: HARMFUL IF SWALLOWED. R 36/38:
IRRITATING TO EYES & SKIN. S 22: DO NOT BREATHE DUST. REVIEWS,
STDS, & REGS: OEL=MAK. EPA FIFRA 19 88 PESTICIDE SUBJECT TO
REGISTRATION/RE-REGISTRATION FEREAC 54, 7740, 1989. OEL-ARAB
REPUBLIC OF EGYPT, OEL-DENMARK, OEL-GERMANY, OEL-THE PHILIPPINES,
OEL-POLAND, OEL-THAILAND: TWA 0.1 MG(CU)/M3 (FUME ) JAN 1993.
OEL-AUSTRALIA, OEL-BELGIUM, OEL-FINLAND, OEL-FRANCE, OEL-INDIA,
OEL-THE NETHERLANDS, OEL -SWEDEN, OEL-UNITED KINGDOM: TWA 0.2
MG(CU)/M3 (FUME) JAN 1993. (OTHER INFO)
State Regulatory Information:OTHER INFO: OEL-UNITED KINGDOM: TWA 1
MG(CU)/M3 JAN 1993. NOES 1983: HZD X5421; NIS 13; TNF 979; NOS 21;
TNE 10821; TFE 3606. NTP TOXICITY STUDIES, RPT# TOX-29, OCTOBER
1997.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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