===================== Product Identification =====================
MSDS NAME:PHENYLHYDRAZINE HCL SIGMA GRADE, P7126
NIIN:00N092686
Status Code:A
MSDS Number: CJVRL
=== Responsible Party ===
Company:SIGMA CHEMICAL CO
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:314-771-5765
Emergency Phone Num:314-771-5765
CAGE:21076
=== Contractor Identification ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:PHENYLHYDRAZINE HYDROCHLORIDE
CAS:59-88-1
RTECS #:MV9000000
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED,
OR ABSORBED THROUGH SKIN. CAUSES EYE AND SKIN IRRITATION. MATERIAL
IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. MAY
CAUSE ALLERGIC SKIN REACTION . EXPOSURE CAN CAUSE: DAMAGE TO THE
LIVER, DAMAGE TO THE KIDNEYS, DAMAGE TO THE LUNGS. CHRONIC:
CARCINOGEN. MAY ALTER GENETIC MATERIAL. TARGET ORGAN(S): BLOOD.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH
COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHNG AND SHOES. IF INHALED REMOVE TO FRESH AIR. IF
NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH WITH WATER
PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. REMOVE AND WASH
CONTAMINATED CLOTHING PROM PTLY.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT TO PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR NIOSH APPRVD SCBA, RUBBER
BOOTS AND HEAVY RUBBER GLOVES. WEAR DISPOSABLE COVERALLS AND
DISCARD THEM AFTER USE. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE
DISPOSAL. AVOID RAISING D UST. VENTILATE AREA AND WASH SPILL SITE
AFTER MATERIAL PICKUP IS COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE DUST. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
READILY ABSORBED THROUGH SKIN. TOXIC. IRRITANT. CARCINOGEN. STRONG
SENSITIZER. MUTAGEN. KEEP TIGHTL Y CLOSED. STORE IN A COOL DRY
PLACE.
Other Precautions:MAY CAUSE HERITABLE GENETIC DAMAGE. TARGET ORGAN(S):
BLOOD. IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL
ADVICE IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE). IN CASE OF
CONTACT WITH EYES, RI NSE IMMEDIATELY WITH PLENTY OF WATER & SEEK
MED ADVICE. WEAR SUITABLE PROT CLTHG, GLOVES AND EYE/FAC E
PROTECTION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
TOXICITY INFO: SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL
ENTRY IN RTECS FOR COMPLETE INFORMATION. FED REGULATORY INFO:
NIOSH* DHHS #92-100,1992. NOHS 1974: HZD 81928; NIS 2; TNF 115; NOS
5 ; TNE 1708. NOES 1983: HZD 81928; NIS 3; TNF 63; NOS 4; TNE 645;
TFE 445. EPA TSCA SECTION 8(B) (OTHER INFO)
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:>250.C, 482.F
M.P/F.P Text:250C-254C
Appearance and Odor:WHITE POWDER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS.
Hazardous Decomposition Products:NITROGEN OXIDES, HYDROGEN CHLORIDE
GAS, CARBON MONOXIDE, CARBON DIOXIDE.
=================== Toxicological Information ===================
Toxicological Information:RTECS #: MV9000000. HYDRAZINE, PHENYL-,
HYDROCHLORIDE. TOX DATA: IPR-RAT LD50: 161 MG/KG. ABMGAJ
18,617,1967. ORL-MUS LD50:2100 MG/KG. QJDRAZ 9,1455,1969. SCU-MUS
LD50: 89 MG/KG. FRPSAX 9,274,1954. IV N-MUS LD50:900 UG/KG. QJDRAZ
9,1455,1969. TARGET ORGAN DATA: LUNGS, THORAX OR RESP (CYANOSIS),
(TUMORS). SKIN AND APPENDAGES (CORROSIVE). EFTS ON NEWBORN
(BEHAVIORAL). NUTRITIONAL & GROSS METABOLIC (W T LOSS/DECREASED WT
GAIN). TUMORIGENIC (EQUIVOCAL TUMORGENIC AGENT BY RTECS CRITERIA).
ONLY SELECTED REGISTRY OF TOXIC EFTS OF CHEMICAL (SUPDAT)
===================== Ecological Information =====================
Ecological:DATA NOT YET AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
===================== Regulatory Information =====================
Federal Regulatory Information:EUROPEAN INFO: TOXIC. R 45. MAY CAUSE
CANCER. R 46. MAY CAUSE HERITABLE GENETIC DMG. R 43. MAY CAUSE
SENSITIZATION BY SKIN CONTACT. R 36/37/38. IRRITATING TO EYES,
RESPIRATORY SYSTEM AND SKIN. S 22. D O NOT BREATHE DUST. S 45. IN
CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MED ADVICE IMMED (SHOW
LABEL WHERE POSSIBLE). S 26. IN CASE OF CONT W/EYES, RINSE IMMED
W/PLENTY OF WATER & SEEK MED ADVICE. S 36/37/39. WEAR SUITABLE
PROT CLTHG, GLOVES AND EYE/FACE PROT. REVIEWS, STANDARDS, &
REGULATIONS: OE L=MAK. NIOSH REL TO HYDRAZINES-AIR:CA CL 0.03
PPM/120M (SUPDAT)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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