===================== Product Identification =====================
MSDS NAME:3084, DALIC SOLUTION SILVER (NON-CYANIDE), 30308403
NIIN:00N092770
Status Code:A
MSDS Number: CJVQF
=== Responsible Party ===
Company:SIFCO SELECTIVE PLATING DIVISION OF SIFCO INDUSTRIES INC.
Address:5708 SCHAAF ROAD
City:CLEVELAND
State:OH
ZIP:44131-1394
Country:US
Info Phone Num:216-524-0099
Emergency Phone Num:216-524-0099
Resp. Party Other MSDS Num.:3084
Chemtrec Ind/Phone:(800)424-9300
CAGE:11924
=== Contractor Identification ===
Company:SIFCO SELECTIVE PLATING DIV OF SIFCO INDUSTRIES INC.
Address:5708 SCHAAF ROAD
Box:City:CLEVELAND
State:OH
ZIP:44131-1394
Country:US
Phone:216-524-0099/ FAX: -6331
CAGE:11924
============= Composition/Information on Ingredients =============
Name:SILVER
CAS:7440-22-4
RTECS #:VW3500000
Minumum % Wt:7.
Maxumum % Wt:13.
OSHA PEL:0.01 MG/M3
ACGIH TLV:0.1 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:POTASSIUM HYDROXIDE
CAS:1310-58-3
RTECS #:TT2100000
Minumum % Wt:5.
Maxumum % Wt:10.
ACGIH STEL:C2 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:NITRIC ACID
CAS:7697-37-2
RTECS #:QU5775000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:5 MG/M3;2 PPM
ACGIH TLV:5.2 MG/M3;2 PPM
ACGIH STEL:10 MG/M3;4 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:72.
Maxumum % Wt:87.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: MAY CAUSE EYE IRRITATION. SKIN
CONTACT: MAY CAUSE SKIN IRRITATION. MAY CAUSE ALGYRIA OR BLUE-BLACK
STAINS ON SKIN IF NOT WASHED OFF IMMEDIATELY. SKIN ABSORPTION:
SUBSTANCE DOES NOT ABSORB THROUGH SKIN. INHALATION: VAPOR OR MIST
MAY BE HARMFUL IF INHALED. MAY CAUSE SNEEZING, NASAL DISCHARGE,
COUGHING, HEADACHES, DIZZINESS, NAUSEA, FATIGUE OR DIFFICULTY
BREATHING. INGESTION: THIS MATERIAL MAY B E HARMFUL OR FATAL IF
SWALLOWED. CHRONIC EFFECTS: PROLONGED OR REPEATED EXPOSURE MAY
CAUSE DAMAGE TO SKIN, EYES, NASAL CAVITY AND LUNGS. MAY CAUSE
SEVERE AND DELAYED HEALTH EFFECTS SUCH AS INFLAMMATIO N OF LUNGS
AND CHEMICAL BRONCHITIS.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:FIRST AID PROVIDERS MUST TAKE PROPER PRECS FOR THEIR OWN
SAFETY BEFORE ENTERING CONTAM AREAS TO ASSIST CHEM ACCIDENT VICTIMS
& HNDLG THEIR CONTAM CLTHG & EQUIP. ANOTHER PERSON SHOULD IMMED
CALL EMER M ED SERVICE, 911-OPERATOR, HOSPITAL, PHYSICIAN,
OPHTHALMOLOGIST OR POIS CTL CTR, AS APPLIC. GIVE FOLLOWING INFO:
LOCATION OF ACCIDENT, YOUR PHONE NUMBER, DESCRIPTION OF ACCIDENT,
NAME OF CHEM AGENT & P ROD, NUMBER & CNDTN OF CASUALTIES, WHAT IS
BEING DONE FOR VICTIMS. STAY ON PHONE UNTIL OTHER PARTY HANGS UP!
REMOVE VICTIM FROM CONTAM AREA TO CLEAN, QUIET, VENTD AREA. CALM &
REASSURE (SUPDAT)
===================== Fire Fighting Measures =====================
Autoignition Temp:Autoignition Temp Text:NA
Extinguishing Media:ALL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . STRUCTURAL FIRE FIGHTER'S PROTECTIVE CLOTHING MAY NOT
PROVIDE ADEQUATE PROTECTION.
Unusual Fire/Explosion Hazard:CONTAINERS CAN BUILD UP PRESSURE AND
BURST IF EXPOSED TO HEAT (FIRE). WATER RUNOFF CAN CAUSE
ENVIRONMENTAL DAMAGE. DIKE AREA FOR LATER DISPOSAL. NFPA - 704M
SYSTEM: HEALTH: 2, FLAMMABILITY: 0, REACTIV ITY: 0.
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT TOUGH OR WALK THRU SPILLED MATERIAL.
ISOLATE HAZ AREA & KEEP PEOPLE AWAY. NOTIFY YOUR FACILITY EMER
COORDINATOR. ELIMINATE ALL SOURCES OF IGNITION. PROVIDE MAXIMUM
VENT. DO NOT RELEASE INTO SOI L, SEWERS, OR NATURAL BODIES OF
WATER. WEAR PROPER PERSONAL PROT EQUIP (PPE). CAREFULLY MOP UP OR
VACUUM SPILL & TRIPLE RINSE W/WATER INTO SUITABLE PLASTIC CNTNR.
RELEASE OF A (TOXICOLOGICAL INFO)
Neutralizing Agent:DILUTE HYDROCHLORIC ACID (6M).
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED IN
UPRIGHT POSITION. STORE AT 60-90F AWAY FROM INCOMPATIBLE MATERIALS
AND PHYSICAL HAZARDS. DO NOT REMOVE OR DEFACE CONTAINER LABLES.
Other Precautions:USE "BUDDY SYSTEM" WHEN WORKING WITH CHEMICALS. DO
NOT GET IN EYES, ON SKIN, ON CLOTHING. DO NOT BREATHE VAPOR, MIST
OR GAS. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. TRIPLE RINSE CONTAINER CLEAN BEFORE DISCARDING. PUT
NOTHING ELSE IN THIS CONTAINER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS ARE NOT FEASIBLE, THE
RESPIRATORY PROTECTION PROGRAM MUST COMPLY WITH OSHA'S 29 CFR
1910.134, 30 CFR 11 AND ANSI Z88.2 REQUIREMENTS.
Ventilation:LOCAL EXHAUST VENTILATION IS REQUIRED TO MEET THE
PERMISSIBLE EXPOSURE LIMITS (PEL) DURING THE USE OF THIS PRODUCT.
Protective Gloves:NITRILE, NEOPRENE, VINYL, LATEX GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . IMPERVIOUS BOOTS, APRON, PROTECTIVE CLOTHING AS
REQUIRED BY JOB CONDITIONS. DO NOT WEAR CONTACT LENSES.
Supplemental Safety and Health
FIRST AID PROC: HIM, KEEP HIM WARM. EYES: HOLD EYELIDS APART & FLUSH
EYES W/PLENTY OF WATER FOR AT LEAST 15 MIN. SKIN: IN CASE OF
CONTACT, IMMED FLUSH SKIN W/PLENTY OF WATER FOR AT LEAST 15 MIN
WHILE REMOVING CONTAM CLTHG & SHOES. THOROUGHLY (OTHER INFO)
================== Physical/Chemical Properties ==================
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:<0.C, 32.F
Spec Gravity:1.223-1.228
pH:8.4-8.8
Evaporation Rate & Reference:<1 (ETHYL ETHER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR TO LIGHT YELLOW LIQUID; NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG AICDS, STRONG OXIDIZERS, ACETYLENE, ORGANIC HALOGENS.
Stability Condition to Avoid:STABLE UNDER NORMAL AMBIENT CONDITIONS IN
TIGHTLY CLOSED CONTAINERS. AVOID OVERHEATING.
Hazardous Decomposition Products:AG, NO*X, CO*X, K*2O.
=================== Toxicological Information ===================
Toxicological Information:NOT AVAILABLE. SPILL PROC: REPORTABLE
QUANTITY (RQ) REQUIRES NOTIFICATION OF PROPER AUTHORITIES. DISPOSE
OF ACCORDING TO LOCAL, STATE & FEDERAL REGS.
===================== Ecological Information =====================
Ecological:NOT AVAILABLE. FEDERAL REG INFO: ANY POLYCHLORINATED
BIPHENYLS (PCB). INTERNATIONAL REGULATIONS: WHMIS CLASSIFICATION:
CLASS D-2B.
==================== Disposal Considerations ====================
Waste Disposal Methods:SHIP TO APPRVD TREATMENT/DISPOSAL FACILITY.
DISPOSE OF ACCORDING TO LOCAL, STATE & FED REGS. EPA WASTE ID
NUMBER: D011. FOLLOW APPLIC REGS FOR DISPOSAL OF EMTPY CNTNRS &
RINSATE. THE DISPOSAL INFO APP LIES TO MATL AS MANUFACTURED. CONTAM
MAY AFFECT DISPOSAL REQS. RESPONSIBILITY FOR PROPER WASTE DISPO SAL
IS W/GENERATOR OF WASTE.
=================== MSDS Transport Information ===================
Transport Information:DOT, IATA, ICAO, IMO DESCRIPTION: PROPER SHIPPING
NAME: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, NOS, (SILVER,
POTASSIUM HYDROXIDE). HAZARD CLASS: 9. IDENTIFICATION NUMBER: UN
3082. PACKAGING GRO UP (PG) III. LABEL REQUIREMENTS: 9 -
MISCELLANEOUS DANGEROUS GOODS. UNIT CONTIANER: 1/2 LITER, 1 LITER
POLYETHYLENE BOTTLE. PACKAGING: MEETS PERFORMANCE ORIENTED
PACKAGING REQUIREMENTS. REPORTABLE QUA NTITY (RQ): >4000. 1996
NAERG GUIDE #: 171.
===================== Regulatory Information =====================
SARA Title III Information:SIFCO SELECTIVE PLATING IS REQD TO INFORM
YOU, THAT THIS PROD CONTAINS A TOXIC CHEM OR CHEMS SUBJECT TO THE
REPORTING REQS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION A CT OF 1986 AND 40 CFR PART 372, IF
SPECIFIED ANNUAL THRESHOLDS ARE MET OR EXCEEDED: SILVER COMPOUNDS
(AS AG) - CAS # 7440-22-4 - WT % (MINIMUM) 13; NITRIC ACID - CAS #
7697-37-2 - WT % (MINIMUM) 5. YO UR OTHER SUPPLIERS OF TRADE NAME
PRODS OR MIXTURES CONTAINING SECTION 313 CHEMS MUST ALSO NOTIFY
YOU. IF YOU REPACKAGE OR OTHERWISE REDISTRIBUTE THIS PROD TO
INDUSTRIAL CUSTOMERS YOU ARE REQD TO FURNI SH SIMILAR NOTIFICATION
TO THEM.
Federal Regulatory Information:CERCLA & EPCRA - THRESHOLD PLANNING QTY:
N/A. (RELEASE) REPORTABLE QTY: >4000 LITERS. EXTREMELY HAZ
SUBSTANCE: NITRIC ACID. EPCRA HAZ CATEGORIES - IMMED (ACUTE)
HEALTH: YES; DELAYED (CHRONIC) HEALTH: YES; FIRE: NO; SUDDEN
RELEASE OF PRESS: NO; REACTIVITY: NO. TSCA STATEMENT: ALL INGREDS
OF THIS PROD ARE LISTED UNDER THE TOXIC SUBSTANCES CONTROL ACT
(TSCA). ODS CERTIFICATION: THIS PROD DOES NOT CON TAIN & IS NOT
MANUFACTURED W/OZONE DEPLETING SUBSTANCES (ODS). VOC CERTIFICTION:
THIS PROD DOES NOT CONTAIN ANY VOLATILE ORGANIC COMPOUNDS. PCB
CERTIFICATION: THIS PROD DOES (STATE REGS)
State Regulatory Information:CALIFORNIA PROP 65: NOT APPLICABLE. FED
REGS: NOT CONTAIN ANY POLYCHLORINATED BIPHENYLS (PCB).
INTERNATIONAL REGULATIONS: WHMIS CLASSIFICATION: CLASSD-2B.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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