===================== Product Identification =====================
MSDS NAME:04667AUX-3
NIIN:01-465-9667
Status Code:A
MSDS Number: CKYPS
=== Responsible Party ===
Company:HENTZEN COATINGS INC
Address:6937 WEST MILL ROAD
Box:18749
City:MILWAUKEE
State:WI
ZIP:53218
Country:US
Info Phone Num:414-353-4200
Emergency Phone Num:414-353-4200
Resp. Party Other MSDS Num.:36173 GREY ZENTHANE PLUS
Chemtrec Ind/Phone:(800)424-9300
CAGE:09225
=== Contractor Identification ===
Company:HENTZEN COATINGS INC
Address:6937 WEST MILL ROAD
Box:18749
City:MILWAUKEE
State:WI
ZIP:53218
Country:US
Phone:414-353-4200
CAGE:09225
============= Composition/Information on Ingredients =============
Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
= Wt:.35
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
Name:HEXAMETHYLENE DIISOCYANATE HOMOPOLYMER
CAS:28182-81-2
RTECS #:NQ9170000
Minumum % Wt:30.
Maxumum % Wt:40.
Other REC Limits:MFR'S TWA 0.5 MG/M3
Name:QUARTZ (SIO2), CRYSTALLINE SILICA
CAS:14808-60-7
RTECS #:VV7330000
Minumum % Wt:15.
Maxumum % Wt:20.
OSHA PEL:0.1 MG/M3
ACGIH TLV:0.1 MG/M3
Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
Minumum % Wt:5.
Maxumum % Wt:10.
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
Name:1,6-HEXAMETHYLENE DIISOCYANATE MONOMER
CAS:822-06-0
RTECS #:MO1740000
= Wt:.04
OSHA PEL:.005 PPM
ACGIH TLV:0.034 MG/M3;.005 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:METHYL AMYL KETONE
CAS:110-43-0
RTECS #:MJ5075000
Minumum % Wt:20.
Maxumum % Wt:30.
OSHA PEL:465 MG/M3;100 PPM
ACGIH TLV:233 MG/M3;50 PPM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: EYE- IRRITATION, MAY CAUSE
CORNEAL DAMAGE. SKIN- IRRITATION, DEFATTING, SKIN SENSITIZATION IN
SOME INDIVDUALS. INGESTION: IRRITATION, POSSIBLE CORROSIVE ACTION
TO GI TRACT, ASPIRATION HAZARD, M AY LEAD TO CHEMICAL PNEUMONITIS.
CHRONIC:PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE, LIVER AND KIDNEY
DAMAGE, DERMATITIS. CERTAIN INDIVIDUALS WILL DEVELOP ISOCANATE
SENSITIZATION (CHEMICAL ASTHMA).
Explanation of Carcinogenicity:THIS PRODUCT HAS NOT BEEN TESTED AS A
WHOLE FOR CARCINOGENICITY. IARC HAS LISTED CRYSTALLINE SILICA AS
GROUP 1 CARCINOGENIC TO HUMANS. NTP CLASSIFIES RESPIRABLE SILICA AS
CLASS 2. CARBON BLACK GP 2B ( IARC).
Effects of Overexposure:EYE: IRRITATION, REDNESS, BLURRED VISION.
SYMPTOMS OF SKIN IRRITATION MAY INCLUDE REDDENING, RASH SWELLING,
SCALING OR BLISTERING, DEFATTING, EXPOSURE TO SOLVENTS WITH
PERMANENT BRAIN AND NERVOUS SYST EM DAMAGE, LIVER AND KIDNEY
DAMAGE. ISOCANATE SENSITIZATION (CHEMICAL ASTHMA), SYMPTOMS COULD
BE IMMEDIATE OR DELAYED UP TO SEVERAL HOURS AFTER EXPOSURE AND
COULD INCLUDE CHEST TIGHTNESS,WHEEZING, COU GH OR ASTHMATIC ATTACK.
INGESTION:ABDOMINAL PAIN, NAUSEA, VOMITING, DIARRHEA.
Medical Cond Aggravated by Exposure:ASTHMA AND OTHER RESPIRATORY
AILMENTS; SKIN ALLERGIES AND ECZEMA; CHEMICAL SENSITIZATION.
======================= First Aid Measures =======================
Eyes: FLUSH IMMEDIATELY WITH LOW PRESSURE LUKEWARM RUNNING
WATER FOR AT LEAST 15 MINUTES WHILE LIFTING EYELIDS. GET MEDICAL
HELP. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING IMMEDIATELY. WASH
AFFECTE D AREAS THOROUGHLY WITH SOAP AND WATER. WASH CONTAMINATED
CLOTHING THOROUGHLY BEFORE REUSE. FOR SEVERE EXPOSURE, GET UNDER
SAFETY SHOWER AFTER REMOVING CLOTHING, THEN GET MEDICAL ATTENTION.
FOR LESS ER EXPOSURES, SEEK MEDICAL ATTENTION IF IRRITATION
DEVELOPS OR PERSISTS.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=38.9C, 102.F
Lower Limits:1.1
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM OR ALCOHOL FOAM.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPEMTN INCLUDING
SELF-CONTAINED BREATHING APPARATUS SHOULD BE WORN. DURING A FIRE,
IRRITATING AND HIGHLY TOXIC GASES (SEE REACTIVITY DATA) AND SMOKE
ARE PRESENT FROM THE DECOMPOSIT ION/COMBUSTION PRODUCTS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINER MAY EXPLODE WHEN EXPOSED
TO EXTREME HEAT OR BURST WHEN CONTAMINATED WITH WATER (CARBON
DIOXIDE RELEASED). DO NOT APPLY TO HOT SURFACES. NEVER USE WELDING
OR CUTTING TORCH ON OR NEAR PRODUCT CONTAINER (EVEN EMPTY) BECAUSE
PRODUCT (EVEN RESIDUE) CAN IGNITE EXPLOSIVELY.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL AND
REMOVE ALL SOURCES OF IGNITION (FLAMES, HOT SURFACES, ELECTRICAL,
STATIC AND FRICTIONAL SPARKS). VENTILATE AREA,EQUIP CLEAN UP CREW
WITH APPROPRIATE PROTECTIV E EQUIPMENT. AVOID BREATHING VAPORS.
AVOID SKIN CONTACT. PREVENT ENTRY INTO DRAINS, SEWERS AND
WATERWAYS. NOTIFY APPROPRIATE AUTHORITIES IF NECESSARY.
Neutralizing Agent:AMMONIA SOLUTION (3-8%), DETERGENT (2%) & WATER
(90-95%) OR A SOLUTION OF UNION CARBIDE'S TERGITOL TMN-10 (20%).
====================== Handling and Storage ======================
Handling and Storage Precautions:PRECAUTION MUST BE TAKEN SO THAT
PERSONS HANDLING THIS PRODUCT DO NOT BREATHE THE VAPORS OR HAVE IT
CONTACT THE EYES OR SKIN. IN SPRAY OPERATIONS, PROTECTION MUST BE
AFFORDED AGAINST EXPOSURE TO BOTH VAPOR AND SPRAY MIST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:THE SURGEON GENERAL REQUIRES AIRLINE RESPIRATORS
TO BE USED UNLESS AIR SAMPLING SHOWS EXPOSURE TO BE BELOW OSHA
LIMITS. THEN EITHER AIR-PURIFYING CHEMICAL CARTRIDGE RESPIRATORS OR
AIRLINE RESPIRATORS ARE REQUIRED. AIR SAMPLING SHOULD BE DONE TO
MEASURE AAIRBORNE CONCENTRATIONS OF MONOMER & POLYMER HDI & ORGANIC
SOLVENTS.
Ventilation:DURING THE SPRAY APPLICATION OF THESE COATIONGS, THE USE OF
A SUPPLIED-AIR RESPIRATOR (EITHER POSITIVE PRESSURE OR CONTINUOUS
FLOW TYPE) IS MANDATORY
Protective Gloves:PERMEATION RESISTANT GLOVES.
Eye Protection:USE SAFETY EYEWEAR WITH SPLASH GUARDS OR SIDE SHIELDS
Other Protective Equipment:A FULL FACE SHIELD MAY BE APPROPRIATE.
CONTACT LENSES SHOULD NOT BE WORN. IF SKIN CREAMS ARE USED, KEEP
THE AREA PROTECTED ONLY BY THE CREAM TO A MINIUM.
Work Hygienic Practices:SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE
AVAILABLE. EDUCATE AND TRAIN EMPLOYEES IN THE SAFE USE OF THE
PRODUCT.
Supplemental Safety and Health
MEDICAL SUPERVISION OF ALL EMPLOYEES WHO HANDLE OR COME IN CONTACT WITH
THIS PRODUCT IS RECOMMENDED. THIS SHOULD INCLUDE PRE-EMPLOYMENT
AND PERIODIC MEDICAL EXAMINATIONS WITH RESPIRATORY FUNCTION TES TS
(FEV,FVC AS A MINIMUM). PERSONS WITH ASTHMA-TYPE CONDITIONS,
BRONCHITIS, OTHER CHRONIC RESPIRATORY DISEASES
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:295.0F-305.0F
Vapor Pres:2.14
Vapor Density:3.94
Spec Gravity:1.217
VOC Pounds/Gallon:360
VOC Grams/Liter:3.
Evaporation Rate & Reference:.400 (N-BUTYL ACETATE=1)
Solubility in Water:REACTS WITH WATER
Appearance and Odor:OPAQUE LIQUID, SOLVENT ODOR
Percent Volatiles by Volume:20-30
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONTAMINATION WITH WATER, EPOXY CATALYSTS, ALCOHOLS, GLYCOL ETHERS,
BASES, METAL COMPLEXES OR OTHER ACTIVE MATERIALS.
Hazardous Decomposition Products:MAY PRODUCE HAZARDOUS FUMES WHEN
HEATED TO DECOMPOSITION AS IN WELDING. FUMES MAY CONTAIN THE
FOLLOWING CARBON MONOXIDE, CARBON DIOXIDE, CHLORINE, HYDROGEN
CHLORIDE AND POSSIBLE CYANIDE, & HDI.
==================== Disposal Considerations ====================
Waste Disposal Methods:RECYCLE, FUEL BLEND OR INCINERATE. DISPOSE OF IN
ACCORDANCE WITH APPLICABLE LAWS AND REGULATIONS. IT IS THE
RESPONSIBILITY OF THE OWNER OF THE WASTE TO DISPOSE OF IT PROPERLY.
LABORATORY ANALYSIS IS RECOMMENDED TO PROFILE THE WASTE FOR
PROPER DISPOSAL DETERMINATION.
=================== MSDS Transport Information ===================
Transport Information:PSN: PAINT,3,UN1263,III. LABEL: FLAMMABLE LIQUID.
===================== Regulatory Information =====================
SARA Title III Information:HEXAMETHYLENE DIISOCYANATE MONOMER (CAS
822-06-0) (% BY WT= 0.045) IS SUBJECT TO THE REPORTING REQUIREMENT
OF SEC 313 ( 40 CFR 372).
Federal Regulatory Information:THE INGREDIENTS OF THIS PRODUCT ARE ON
THE TSCA INVENTORY.
======================= Other Information =======================
======================================================================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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