===================== Product Identification =====================
MSDS NAME:846 2681,KODAK FLEXICOLOR SM TANK FIXER/C-41SM
NIIN:01-443-3344
Status Code:A
MSDS Number: CKYRY
=== Responsible Party ===
Company:EASTMAN KODAK COMPANY
Address:343 STATE STREET
City:ROCHESTER
State:NY
ZIP:14650
Country:US
Info Phone Num:716-722-5151/(800) 242-2424
Emergency Phone Num:716 722-5151
Preparer's Name:NOT PROVIDED
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
Contract Num:SP0500-96-D-9413-M379
CAGE:19139
============= Composition/Information on Ingredients =============
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:75.
Maxumum % Wt:80.
Other REC Limits:NOT PROVIDED
Name:AMMONIUM THIOSULFATE
CAS:7783-18-8
RTECS #:XN6465000
= Wt:10.
Other REC Limits:NOT PROVIDED
Name:AMMONIUM THIOCYANATE
CAS:1762-95-4
RTECS #:XK7875000
= Wt:8.
Other REC Limits:NOT PROVIDED
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:SODIUM SULFITE
CAS:7757-83-7
RTECS #:WE2150000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NOT PROVIDED
Name:AMMONIUM SULFITE
CAS:10196-04-0
< Wt:1.
Other REC Limits:NOT PROVIDED
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION:
EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. IF HYDROGEN
CYANIDE GAS IS LIBERATED DUE TO CONTACT WITH A STRONG
OXIDIZER/ACID, IT MAY CAUSE DIZZINESS, HEADACH E, RAPID
RESPIRATION, RAPID PULSE, UNCONSCIOUSNESS, CONVULSIONS, DEATH. IF
SULFUR DIOXIDE GAS IS FORMED, IT IS IRRITATING TO RESPIRATORY
TRACT. EYES: CAUSES IRRITATION. SKIN: CAUSES IRRITATION. HARMFU L
IF ABSORBED THROUGH SKIN. THIS MATERIAL HAS A LOW POTENTIAL TO
CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN SKIN
SENSITIZATION HAVE BEEN REPORTED. INGESTION: HARMFUL IF SWALLOWED.
MAY CAUS E IRRITATION OF GASTROINTESTINAL TRACT.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NON E - NATIONAL
TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION (OSHA): NONE
Effects of Overexposure:INHALATION: IF HYDROGEN CYANIDE GAS IS
LIBERATED DUE TO CONTACT WITH A STRONG OXIDIZER OR ACID, IT MAY
CAUSE DIZZINESS, HEADACHE, RAPID RESPIRATION, RAPID PULSE,
UNCONSCIOUSNESS, CONVULSIONS AND DEATH . EYES: CAUSES IRRITATION.
SKIN: CAUSES IRRITATION. INGESTION: MAY CAUSE IRRITATION OF THE
GASTROINTESTINAL TRACT.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING,
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.
======================= First Aid Measures =======================
First Aid:INHALATION: MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET
MEDICAL ATTENTION IF SYMPTOMS OCCUR. EYES: IMMEDIATELY FLUSH WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF
SYMPTOMS OCCUR. SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR
AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH CONTAMINATED CLOTHING
BEFORE R EUSE. DESTROY OR THOROUGHLY CLEAN CONTAMINATED SHOES.
INGESTION: INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN
OR POISON CON TROL CENTER IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE ALCOHOL FOAM, CARBON DIOXIDE (CO2), DRY
CHEMICAL, WATER SPRAY.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG REDUCING
AGENT. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT RELEVANT
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED TO
PREVENT THE LOSS OF WATER. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES.
KEEP FROM CONTACT WITH OXIDIZING MATERIALS.
Other Precautions:IF ACCIDENTALLY MIXED WITH A STRONG OXIDIZER OR ACID,
DO NOT BREATHE GAS. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING.
USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.
CHLORINE BLEACH MA Y LIBERATE POISONOUS GAS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED UNDER NORMAL CONDITIONS OF
USE. HOWEVER IN THE UNLIKELY EVENT THAT HAZARDOUS DECOMPOSITION
PRODUCTS ARE RELEASED, EMERGENCY RESPONSE PERSONNEL MUST WEAR A
FULL-FACE POSITIVE-PRES SURE AIR SUPPLIED RESPIRATOR. IF
RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED TO ASSURE
COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING
APPROPRIATE FOR RISK OF EXPOSURE
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
SUPPLEMENTARY LOCAL EXHAUST VENTILATION, CLOSED SYSTEMS, OR RESPIRATORY
PROTECTION MAY BE NEEDED IN SPECIAL CIRCUMSTANCES. DO NOT ADD
CLEANING AGENTS TO PROCESSOR TANKS UNLESS TANK AND RECIRCULATION L
INES HAVE BEEN COMPLETELY DRAINED AND THOROUGHLY RINSED WITH WATER.
FOR MORE INFORMATION, CALL (800) 242-2424, EXT. 60.
================== Physical/Chemical Properties ==================
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:(68F):24 MBAR (18 MM HG)
Vapor Density:0.6
Spec Gravity:1.090
pH:6.5
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:LIGHT YELLOW LIQUID - SLIGHT VINEGAR ODOR
Percent Volatiles by Volume:75-80 WT
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS (E.G. SODIUM HYPOCHLORITE (BLEACH)),
COMBUSTIBLE MATERIAL, HALOGENATED MATERIALS, STRONG ACIDS (E.G.
SULFURIC ACID), BASES. CONTACT WITH STRONG OXIDIZING AGENTS OR
ACIDS LIBERATES POISONOUS GAS AND
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF NITROGEN, OXIDES OF SULFUR, AMMONIA, CHLORAMINE,
CYANIDES, CARBONYL SULFIDE.
=================== Toxicological Information ===================
Toxicological Information:EFFECTS OF EXPOSURE: GENERAL: CONTAINS:
AMMONIUM THIOCYANATE. OVEREXPOSURE TO THIOCYANATES HAS BEEN SHOWN
TO CAUSE THYROID ENLARGEMENT, DECREASE IN METABOLIC RATE, AND
SYMPTOMS OF HYPOTHYROIDISM IN HU MANS AND ANIMALS.
===================== Ecological Information =====================
Ecological:POTENTIAL TOXICITY: FISH LC50 MG/L: >100. DAPHNID EC50
MG/L: >100. ALGAL IC50 MG/L: >100. ORGANICS READILY DEGRADABLE
(>70%): YES (14 DAYS). POTENTIAL BIOACCUMULATION: LOG POW <1. COD
(APPROXIMAT E G/L): 83. BOD5 (APPROXIMATE G/L): 45. WASTE
TREATMENT MICROORGANISMS EC50 (MG/L): >100
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS E VEN AFTER CONTAINER IS EMPTIED.
=================== MSDS Transport Information ===================
Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD
TIME), MONDAY THROUGH FR IDAY.
===================== Regulatory Information =====================
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: AMMONIUM THIOSULFATE, AMMONI UM THIOCYANATE (AS CHEMICAL
SOURCE OF AQUEOUS AMMONIA)
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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