===================== Product Identification =====================
MSDS NAME:51 ROCKSPAR POLYURETHANE VARNISH INTERIOR-EXT WOOD FINISH
Status Code:A
MSDS Number: CKYPW
=== Responsible Party ===
Company:GLIDDEN CO MEMBER OF ICI WORLD PAINTS
Address:925 EUCLID AVE
Box:15049
City:CLEVELAND
State:OH
ZIP:44115
Country:US
Info Phone Num:216-344-8000
Emergency Phone Num:800-545-2643
CAGE:72818
=== Contractor Identification ===
Company:GLIDDEN CO MEMBER OF ICI WORLD PAINTS
Address:925 EUCLID AVE
Box:15049
City:CLEVELAND
State:OH
ZIP:44115
Country:US
Phone:216-344-8000
CAGE:72818
============= Composition/Information on Ingredients =============
Name:HEXANOIC ACID, 2-ETHYL-, COBALT(2+) SALT
CAS:136-52-7
Minumum % Wt:.1
Maxumum % Wt:1.
OSHA PEL:.05 MG/M3
ACGIH TLV:.02 MG/M3
Name:BENZENE
CAS:71-43-2
RTECS #:CY1400000
Minumum % Wt:.01
Maxumum % Wt:.1
OSHA PEL:1 PPM
OSHA STEL:5 PPM
ACGIH TLV:.5 PPM
ACGIH STEL:2.5 PPM
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:STODDARD SOLVENT
CAS:8052-41-3
RTECS #:WJ8925000
Minumum % Wt:10.
Maxumum % Wt:20.
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Name:BENZENE, 1,2,4-TRIMETHYL-
CAS:95-63-6
RTECS #:DC3325000
Minumum % Wt:.1
Maxumum % Wt:1.
Name:DISTILLATES (PETROLEUM), HYDROTREATED LIGHT
CAS:64742-47-8
RTECS #:OA5504000
Minumum % Wt:10.
Maxumum % Wt:20.
OSHA PEL:100 PPM
ACGIH TLV:100 PPM
Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC
CAS:64742-95-6
RTECS #:WF3400000
Minumum % Wt:1.
Maxumum % Wt:5.
Name:SOYBEAN OIL, POLYMER WITH PENTAERYTHRITOL, TDI AND TUNG OIL
CAS:67989-28-0
Minumum % Wt:20.
Maxumum % Wt:30.
Name:SILICA SOL, AMORPHOUS, CRYSTALLINE-FREE
CAS:112926-00-8
RTECS #:VV7315000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:6 MG/M3
ACGIH TLV:10 MG/M3
Name:NAPHTHA (PETROLEUM), HEAVY ALKYLATE
CAS:64741-65-7
Minumum % Wt:10.
Maxumum % Wt:20.
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Name:FATTY ACIDS, TALL-OIL, POLYMERS WITH ETHYLENE GLYCOL,
GLYCEROL, ISOPHTHALIC ACID, PENTAERYTHRITOL AND PROPYLENE GLYCOL
CAS:68333-62-0
Minumum % Wt:20.
Maxumum % Wt:30.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:CONTAINS A CHEMICAL THAT IS MODERATELY
TOXIC BY INHALATION. NOTICE-REPORTS HAVE ASSOCIATED REPEATED AND
PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT
BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL
OR FATAL.
Explanation of Carcinogenicity:BENZENE, COBALT
Effects of Overexposure:INHALATION: LOSS OF APPETITE, MUCOUS MEMBRANE
IRRITATION, DROWSINESS, DIZZINESS AND/OR LIGHTHEADEDNESS, HEADACHE,
UNCOORDINATION, NAUSEA, CENTRAL NERVOUS SYSTEM DEPRESSION,
INTOXICATION, ALLERGIC RESP ONSE, ASTHMATIC REACTION. SKIN:
DERMATITIS, DEFATTING. MAY RESULT IN DERMAL ABSORPTION OF
COMPONENTS OF THIS PRODUCT. EYE: CONJUNCTIVITIS. INGESTION: LUNG
INFLAMMATION AND DAMAGE DUE TO ASPIRATION OF MATERIAL INTO LUNGS,
MOUTH AND THROAT IRRITATION, MUCOUS MEMBRANE IRRITATION, NAUSEA,
VOMITING, GASTRO-INTESTINAL DISTURBANCES, CENTRAL NERVOUS SYSTEM
DEPRESSION, INTOXICATION, CONVULSIONS.
Medical Cond Aggravated by Exposure:EYE, SKIN, RESPIRATORY DISORDERS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE AND SUPPORT
CONTINUED BREATHING. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY.
SKIN: FLUSH FROM SKIN WITH WATER. THEN WASH THOROUGHLY WITH SOAP
AND WATER. REMOVE CONTAMINATED CLOTHING. EYE: FLUSH IMMEDIATELY
WITH LARGE AMOUNTS OF WATER, ESPECIALLY UNDER LIDS FOR AT LEAST 15
MINUTES. IN ALL CASES, GET MEDICAL ATTENTION IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:=39.4C, 103.F
Lower Limits:.7%
Upper Limits:13.3%
Extinguishing Media:DRY CHEMICAL OR FOAM, WATER FOG, CARBON DIOXIDE
Fire Fighting Procedures:WATER MAY BE USED TO COOL AND PROTECT EXPOSED
CONTAINERS. FIREFIGHTERS SHOULD USE FULL PROTECTIVE CLOTHING, EYE
PROTECTION, AND SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT OR FIRE. VAPORS CAN FORM EXPLOSIVE
MIXTURES IN AIR AT ELEVATED TEMPERATURES. MAY DECOMPOSE UNDER FIRE
CONDITIONS EMITTING IRRITANT AND/OR T OXIC GASES.
================== Accidental Release Measures ==================
Spill Release Procedures:COMPLY WITH ALL APPLICABLE HEALTH AND
ENVIRONMENTAL REGULATIONS. ELIMINATE ALL SOURCES OF IGNITION.
VENTILATE AREA. EVACUATE ALL UNNECESSARY PERSONNEL. LARGE
SPILLS-SHUT OFF LEAK IF SAFE TO DO SO. DIK E AND CONTAIN SPILL.
PUMP TO STORAGE OR SALVAGE VESSELS. USE ABSORBENT TO PICK UP EXCESS
RESIDUE. KEEP SALVAGABLE MATERIAL AND RINSE WATER OUT OF SEWERS AND
WATER COURSES.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE BELOW 100 F. KEEP AWAY FROM
HEAT, SPARKS, AND OPEN FLAME.
Other Precautions:USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE
INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN. AVOID CONTACT WITH
SKIN AND EYES, AND BREATHING OF VAPORS. WASH HANDS THOROUGHLY AFTER
HANDLING, ESPECIAL LY BEFORE EATING OR SMOKING. KEEP CONTAINERS
TIGHTLY CLOSED AND UPRIGHT WHEN NOT IN USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW
APPLICABLE EXPOSURE STANDARDS WHEN USING THIS MATERIAL. WHEN
RESPIRATORY PROTECTION IS DETERMINED TO BE NECESSARY, USE A
NIOSH/MSHA APPROVED ELASTOMERIC SEAL ING SURFACE FACEPIECE
RESPIRATOR OUTFITTED WITH ORGANIC VAPOR CARTRIDGES AND PAINT SPRAY
PREFILTERS.
Ventilation:PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT
BUILD-UP OF VAPORS. USE EXPLOSION-PROOF EQUIPMENT.
Protective Gloves:IMPERVIOUS
Eye Protection:SAFETY GLASSES OR GOGGLES
Other Protective Equipment:EYE WASH, SAFETY SHOWER, IMPERVIOUS
CLOTHING, FACE SHIELD
Supplemental Safety and Health
WT/GAL = 7.56
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:281-400 F
Spec Gravity:0.907
Appearance and Odor:CLEAR LIQUID
Percent Volatiles by Volume:61.81
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS, BASES, HYDROGEN CHLORIDE, VINYL POLYMERS, METAL
COMPOUNDS, HYDROGEN FLUORIDE, MAGNESIUM.
Stability Condition to Avoid:ELEVATED TEMPERATURES, SPARKS, OPEN FLAME,
IGNITION SOURCES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, ACID
FUMES, TOXIC GASES.
=================== Toxicological Information ===================
Toxicological Information:BENZENE IS LISTED AS A CARCINOGEN.
CARCINOGENICITY: IARC HAS CLASSIFIED COBALT AND CERTAIN COBALT
COMPOUNDS AS POSSIBLY CARCINOGENIC TO HUMANS. INJECTION OF METALLIC
COBALT, COBALT ALLOYS, AND CERTAI N COBALT COMPOUNDS HAS RESULTED
IN THE DEVELOPMENT OF LOCALIZED TUMORS IN LABORATORY ANIMALS.
SILICA GEL, AMORPHOUS: LD50:>2000.00 MG/KG SKN RBT, LD50:>31.60
GM/KG ORL RAT, LC50:>2.00 PPM; LIGHT AROM ATIC SOLVENT NAPHTHA:
LD50:>5.00 GM/KG ORL RAT, LC50:>3670.00 PPM IHL RAT; BENZENE: LD50:
930.00 MG/KG ORL RAT, LD50:>9400.00 MG/KG SKN RBT; MINERAL SPIRITS:
LD50:>3.00 GM/KG SKN RBT, LD50:>5.00 GM/KG ORL RAT
===================== Ecological Information =====================
Ecological:NO ECOLOGICAL TESTING HAS BEEN DONE BY ICI PAINTS ON THIS
PRODUCT AS A WHOLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
=================== MSDS Transport Information ===================
Transport Information:DOT: PAINT, COMBUSTIBLE LIQUID, UN 1263, PGIII
===================== Regulatory Information =====================
SARA Title III Information:COBALT ALKANOATE: SARA 313: YES, HAZ AIR
POLLUTANT : YES; BENZENE: SARA 313: YES, CERCLA 302.4: YES, HAZ AIR
POLLUTANT: YES
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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