===================== Product Identification =====================
MSDS NAME:PLASTIC ROOF CEMENT, 0340
Status Code:A
MSDS Number: CLFKY
=== Responsible Party ===
Company:GARDNER ASPHALT CORP
Address:4161 E 7TH AVENUE
Box:5449
City:TAMPA
State:FL
ZIP:33605
Country:US
Info Phone Num:800-237-1155/813-248-2101
Emergency Phone Num:800-424-9300
Chemtrec Ind/Phone:(800)424-9300
CAGE:0VZ30
=== Contractor Identification ===
Company:GARDNER ASPHALT CORP
Address:4161 E 7TH AVENUE
Box:5449
City:TAMPA
State:FL
ZIP:33605
Country:US
Phone:800-237-1155/813-248-2101
CAGE:0VZ30
============= Composition/Information on Ingredients =============
Name:PETROLEUM ASPHALT
CAS:8052-42-4
RTECS #:CI9900000
< Wt:45.
ACGIH TLV:5.0 MG/M3 (FUME)
Name:STODDARD SOLVENT
CAS:8052-41-3
RTECS #:WJ8925000
< Wt:20.
OSHA PEL:2900 MG/M3;500 PPM
ACGIH TLV:100 PPM
Name:CELLULOSE FIBER. (TLV=AS RESPIRABLE DUST)
CAS:9004-34-6
RTECS #:FJ5691460
< Wt:10.
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3 (DUST)
Name:MINERAL FILLER. (MFR. CAS# 581-31-74-8) (TLV=AS RESPIRABLE
DUST)
< Wt:35.
ACGIH TLV:10MG/M3 (DUST)
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: PETROLEUM SOLVENTS AND ASPHALT
COMPONENTS CAN CAUSE SEVERE IRRITATION, REDNESS, TEARING AND
BLURRED VISION. SKIN: PETROLEUM SOLVENTS AND ASPHALT COMPONENTS -
PROLONGED OR REPEATED CONTACT CAN CAU SE MODERATE IRRITATION,
DEFATTING AND DERMATITIS. INHALATION: PETROLEUM SOLVENTS -
EXCESSIVE INHALATION OF VAPORS CAN CAUSE IRRITATION OF NOSE AND
THROAT, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACH E, POSSIBLE
UNCONSCIOUSNESS AND EVEN ASPHYXIATION. INGESTION: ASPIRATION
HAZARD. VARIABILITY AMONG INDIVIDUALS: HEALTH STUDIES HAVE SHOWN
THAT INDIVIDUAL SENSITIVITIES VARY FROM PERSON TO PERSON. AS A
PRECAUTION, (OVEREXPOSURE)
Explanation of Carcinogenicity:IN 1994, THE INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC) RECONFIRMED ITS EARLIER ASSESSMENT THAT
STUDIES OF WORKERS EXPOSED TO ASPHALT PROVIDE INADEQUATE EVIDENCE
OF CRCINOGENICITY. IARC HAS PR EVIOUSLY CLASSIFIED ASPHALT AS A
GROUP 3 SUBSTANCE, NOT CLASSIFIABLE AS TO ITS CARCINOGENICITY TO
HUMANS.
Effects of Overexposure:HEALTH HAZARDS ACUTE AND CHRONIC (CONT'D):
EXPOSURE TO VAPORS, LIQUIDS, MISTS OR FUMES SHOULD BE MINIMIZED.
EFFECTS OF OVEREXPOSURE: BREATHING ASPHALT AEROSOL OR ASPHALT SMOKE
FOR PROTRACTED PERIODS O F TIME HAS PRODUCED DAMAGE TO THE LUNGS OF
MICE. AMONG THE CHANGES OBSERVED WERE: BRONCHITIS, PENEUMONITIS AND
ABSCESS FORMATION.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING CENTRAL
NERVIOUS SYSTEM DISEASE, SKIN DISORDERS, OR CHRONIC RESPIRATORY
DISEASE SHOULD AVOID EXPOSURE TO THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING
AND SHOES. THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER. IF
IRRITATION PER SISTS OR REDNESS DEVELOPS AND PERSISTS, GET MEDICAL
ATTENTION. INHALATION: REMOVE INDIVIDUAL TO FRESH AIR; IF BREATHING
IS DIFFICULT, ADMINISTER OXYGEN, IF BREATHING HAS STOPPED,
ADMINISTER ARTIFICAL RESPIRATION. KEEP PERSON WARM AND QUIET. GET
MEDICAL ATTENTION IMMEDIATELY. INGESTION: DO NOT INDUCE VOMITING.
TRANSPORT TO HOSPITAL IMMEDIATELY. GET MEDICAL (STATE REG)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=40.6C, 105.F
PETROLEUM SOLVEN
Autoignition Temp:>232.2C, 450.F
Autoignition Temp Text:>450
Lower Limits:6.0%
Upper Limits:0.9%
Extinguishing Media:EXTINGUISHING WITH DRY CHEMICAL AND CO2 OR
UNIVERSAL TYPE FOAM AND WATER FOG ARE EFFECTIVE BUT MAY CAUSE
FROTHING. DO NOT USE WATER. PETROLEUM BASED COMPOUNDS FLOAT ON
WATER.
Fire Fighting Procedures:WEAR A NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT . FIGHT AS A FUEL OIL FIRE.
Unusual Fire/Explosion Hazard:DECOMPOSITION PRODUCTS UNDER FIRE
CONDITIONS: MAY FORM TOXIC MATERIALS; CARBON DIOXIDE AND CARBON
MONOXIDE AND NITROGEN OXIDES.
================== Accidental Release Measures ==================
Spill Release Procedures:SHUT OFF AND ELIMINATE ALL IGNITION SOURCES.
KEEP PEOPLE AWAY. RECOVER FREE PRODUCT. ADD SAND, EARTH OR OTHER
SUITABLE ABSORBENTS TO SPILL AREA. MINIMIZE SKIN CONTACT AND
BREATHING VAPORS. VENTILATED CONFINED SPACES. OPEN ALL WINDOWS AND
DOORS. KEEP PRODUCT OUT OF SEWERS AND WATER COURSES BY DIKING OR
IMPOUNDING. ADVISE AUTHORITIES IF (STATE REG)
Neutralizing Agent:N/P.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED. KEEP
CONTAINERS COOL, DRY & AWAY FROM SOURCES OF IGNITION. USE PRODUCT
WITH ADEQUATE VENTILATION. MATERIAL IS COMBUSTIBLE. MATERIAL
REQUIRES ELECTRICAL GROUNDING DURING MATERIAL TRANSFER PROCESS.
ALL ELECTRICAL EQUIPMENT IN STORAGE OR HANDLING AREAS (OTHER
PRECAUTION)
Other Precautions:HAND/STOR (CONT'D): SHOULD BE INSTALLED PER NFPA
REQUIREMENTS. KEEP CONTAINERS CLOSED WHEN NOT IN USE. DO NOT STORE
NEAR HEAT, SPARKS, FLAME, STRONG OXIDANTS. TO PREVENT FIRE OR
EXPLOSION RISK FROM ST ATIC ACCUMULATION & DISCHARGE, EFFECTIVELY
GROUND PROD TRANSFER SYSTEM IN ACCORDANCE W/NFPA STANDARD FOR
PETROLEUM PROD.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AIR CONCENTRATIONS OF FUMES DETERMINE THE LEVEL
OF PROTECTION NEEDED. USE ONLY NIOSH APPROVED RESPIRATORY EQUIPMENT
WITHIN THE LIMITS OF THE PROTECTION FACTORS FOR THAT EQUIPMENT.
Ventilation:VENTILATION SUFFICIENT TO PREVENT EXCEEDING RECOMMENDED
EXPOSURE LIMIT OR BUILDUP OF EXPLOSIVE CONCENTRATIONS OF VAPOR IN
AIR. USE EXPLOSION-PROOF (SUPP SAFETY)
Protective Gloves:CHEMICAL RESISTANT GLOVES SUCH AS NEOPRENE,
NITRILE-BUTADIENE RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GLASSES, SPLASH GOGGLES,
FACE SHIELD. (SUPP SFTY)
Other Protective Equipment:EYEWASH/DELUGE SHOWER MEETING ANSI STD. WEAR
GLOVES & CLOTHES WHICH IS IMPERVIOUS TO PETROLEUM SOLVENTS &
ASPHALT COMPONENTS TO AVOID CONTAM CLOTHING WHICH COULD RESULT IN
PROLONGED/REPEAT SKIN CONTACT.
Work Hygienic Practices:CLEANSE HANDS THOROUGHLY BEFORE EATING,
SMOKING. MINIMIZE BREATHING VAPORS OR MIST. REMOVE CONTAMINATED
CLOTHING; LAUNDER OR DRY CLEAN BEFORE REUSE. REMOVE CONTAMINATED
SHOES; THOROUGHLY (SUPP SAFETY)
Supplemental Safety and Health
WORK HYGIENE (CONT'D): CLEAN & DRY BEFORE REUSE. PRODUCT READILY
REMOVED FROM SKIN BY WATERLESS HAND CLEANERS FOLLOWED BY WASHING
THOROUGHLY WITH SOAP AND WATER. EYE PROTECTION (CONT'D): CONTACT
LENSE S SHOULD NOT BE WORN WHEN WORKING WITH THIS MATERIAL.
VENTILATION (CONT'D): EQUIPMENT.NO SMOKING OR OPEN LIGHTS.
================== Physical/Chemical Properties ==================
Boiling Pt:=148.9C, 300.F
B.P. Text:300 -390F
Vapor Pres:APPROX. 6MM HG 106F
Vapor Density:3.9 AIR=1.
Spec Gravity:LESS THAN 1
Viscosity:500,000-1,500,000 CPS@77F
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE
Appearance and Odor:A MODERATELY THICK BLACK COATING W/SLIGHT PETROLEUM
HYDROCARBON SOLVENT ODOR.
Percent Volatiles by Volume:<25%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS SUCH AS LIQUID CHLORINE, CONCENTRATED OXYGEN, SODIUM
HYPOCHLORITE OR CALCIUM HYPOCHLORITE.
Stability Condition to Avoid:AVOID HEAT OR OPEN FLAME. PRODUCT WILL NOT
VIOLENTLY REACT WITH WATER.
Hazardous Decomposition Products:DECOMPOSITION PRODUCTS UNDER FIRE
CONDITIONS: MAY FORM TOXIC MATERIALS: CARBON DIOXIDE AND CARBON
MONOXIDE AND NITROGEN OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN AN ENVIRONMENTALLY SAFE MANNER AND
IN ACCORDANCE WITH GOVERNMENTAL REGULATIONS. "EMPTY" CONTAINERS
RETAIN RESIDUE (LIQUID AND/OR VAPOR) AND CAN BE DANGEROUS. DO NOT
PRESSURIZE, CUT, WEL D, BRAZE, SOLDER, DRILL, GRIND, EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, OTHER SOURCES OF IGNI TION, THEY
MAY EXPLODE AND (STATE REGULATORY)
=================== MSDS Transport Information ===================
Transport Information:TRANSPORTATION INCIDENT INFO: FOR FURTHER
INFORMATION RELATIVE TO SPILLS RESULTING FROM TRANSPORATION
INCIDENTS, REFER TO LATEST DEPARTMENT OF TRANSPORATATION GUIDEBOOK
FOR HAZARDOUS MATERIALS INCIDEN TS, DOT P 5800.3. DOT
IDENTIFICATION NUMBER: NOT ESTABLISHED.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 313 - TOXIC CHEMICALS: THIS PRODUCT
DOES NOT CONTAIN TOXIC CHEMICALS OF SECTION 313 OF TITLE III OF
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF (SARA) AND 40 CFR
PART 372. SARA TITLE III, SECTION 311 - HAZARD CATREGORIES: ACUTE
= FUMES ONLY. SARA TITLE II, SECTION 302(A) - EXTREMELY HAZARDOUS
SUBSTANCES: THIS PRODUCT DOES NOT CONTAIN EXTREMELY HAZARDOUS
SUBSTANCES OF SECTION 302(A).
Federal Regulatory Information:CERCLA - COMPREHENSIVE ENVIRONMENTAL
RESPONSE, COMPENSATION AND LIABILITY ACT SECTION 102 HAZARDOUS
SUBSTANCES, 42 U.S.C. 9602: PETROLEUM AND PETROLEUM FRACTIONS ARE
EXCLUDED FROM THE LIST OF CERCLA H AZARDOUS SUBSTANCES BY SECTION
101(14) OF CERCLA. EPA HAZARD CLASSIFICATION CODE: NOT APPLICABLE.
State Regulatory Information:N/P. DISPOSAL (CONT'D): CAUSE INJURY OR
DEATH. DO NOT ATTEMPT TO CLEAN SINCE RESIDUE IS DIFFICULT TO
REMOVE. FOR WORK ON TANKS, REFER TO OSHA REGULATION ANSI Z49.1 AND
OTHER GOVERMENTAL AND INDUSTRIA L REFERENCES PERTAINING TO
CLEANING, REPAIRING, WELDING OR OTHER CONTEMPLATED OPERATIONS.
FIRST AID (CONT'D): ATTENTION. NOTE TO PHYSICIAN: PERFORM GASTRIC
LAVAGE IN ACCORDANCE WITH PROCEDURES FOR ING ESTION OF PETROLEUM
PRODUCTS. SPILL/RELEASE PROCEDURE (CONT'D): PRODUCT HAS ENTERED OR
MAY ENTER SEW ERS, WATER COURSES OR EXTENSIVE LAND AREAS. ASSURE
CONFORMITY WITH APPLICABLE GOVERNMENTAL REGULATIONS.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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