===================== Product Identification =====================
MSDS NAME:AHE90306TNO LN903, LIQUID NAILS ADHESIVE,
Status Code:A
MSDS Number: CLFVL
=== Responsible Party ===
Company:MACCO ADHESIVES
Address:925 EUCLID AVENUE
City:CLEVELAND
State:OH
ZIP:44115
Country:US
Info Phone Num:1-800-545-2643
Emergency Phone Num:1-800-545-2643
Resp. Party Other MSDS Num.:AHE 90306TNO
CAGE:UO049
=== Contractor Identification ===
Company:MACCO ADHESIVES
Address:925 EUCLID AVENUE
Box:City:CLEVELAND
State:OH
ZIP:44115
Country:US
Phone:1-800-545-2643
CAGE:UO049
============= Composition/Information on Ingredients =============
Name:LIMESTONE
CAS:1317-65-3
RTECS #:EV9580000
Minumum % Wt:40.
Maxumum % Wt:50.
OSHA PEL:5 MG/M3 TWA
ACGIH TLV:10 MG/M3 TWA
Name:KAOLIN
CAS:1332-58-7
RTECS #:GF1670500
Minumum % Wt:10.
Maxumum % Wt:20.
OSHA PEL:5 MG/M3 TWA
ACGIH TLV:2 MG/M3 TWA
Name:QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
Minumum % Wt:.1
Maxumum % Wt:1.
OSHA PEL:0.1 MG/KG TWA
ACGIH TLV:0.1 MG/M3 TWA
Name:BENZENE, 1,3-DIETHENYL-, PLOYMER WITH 1,3-BUTADIENE AND
ETHENYLBENZENE. (STYRENE-BUTADIENE POLYMER)
CAS:26471-45-4
Minumum % Wt:1.
Maxumum % Wt:5.
Name:MAGNESIUM CARBONATE
CAS:546-93-0
RTECS #:OM2470000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:5 MG/M3 TWA
ACGIH TLV:10 MG/M3 TWA
Name:MINERAL OIL, HEAVY NAPHTHENIC DISTILLATE. (PETROLEUM
HYDROCARBON)
CAS:64742-52-5
RTECS #:PY8035000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:5 MG/M3 TWA
ACGIH TLV:5 MG/M3 TWA
ACGIH STEL:10 MG/M3
Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC. (LIGHT
ALIPHATC SOLVENT NAPHTHA (PETROLEUM))
CAS:64742-89-8
Minumum % Wt:10.
Maxumum % Wt:20.
OSHA PEL:300 PPM TWA
Name:2-PROPANONE. (ACETONE)
CAS:67-64-1
RTECS #:AL3150000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:1000 PPM
ACGIH TLV:500 PPM TWA
ACGIH STEL:750 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:DISTILLATES (PETROLEUM), STEAM-CRACKED, POLYMERS WITH LIGHT
STEAM-CRACKED PETROLEUM NAPHTHA. (AROMATIC HYDROCARBON RESIN)
CAS:68410-16-2
Minumum % Wt:10.
Maxumum % Wt:20.
Name:RESIN ACIDS AND ROSIN ACIDS, ESTERS WITH GLYCEROL. (ROSIN
GLYCEROL ESTER)
CAS:8050-31-5
Minumum % Wt:1.
Maxumum % Wt:5.
ACGIH TLV:5 MG/M3 TWA
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: PROLONGED INHALATION MAY
LEAD TO MUCOUS MEMBRANE IRRITATION, FATIGUE, DROWSINESS, DIZZINESS,
AND/OR LIGHTHEADNESS, HEADACHE, UNCOORDINATION, NAUSEA, VOMITING,
ABDOMINAL PAIN, COUGHING, DIF FICULTY WITH SPEECH, CENTRAL NERVOUS
SYSTEM DEPRESSION, ANESTHETIC EFFECT OR NARCOSIS, DIFFICULTY OF
BREATHING, BLOOD ABNORMALITIES, LIVER DAMAGE, KIDNEY DAMAGE, LOSS
OF CONSCIOUSNESS, ASPHYXIATION, DEATH. SKIN: IRRITATION.
PROLONGED OR REPEATED CONTACT CAN CAUSE DERMATITIS, DEFATTING.
EYE: IRRITATION. PROLONGED OR REPEATED CONTACT CAN CAUSE
CONJUNCTIVITIS, BLURRED VISION, TEARING OF EYES, REDN ESS (SIGNS &
SYMPTOMS OF OVEREXPOSURE)
Explanation of Carcinogenicity:QUARTZ (CAS 14808-60-7): NTP: YES, IARC:
YES 1. PETROLEUM HYDROCARBON (CAS 64742-52-2): IARC: YES 1.
CONTAINS CRYSTALLINE SILICA WHICH IS CONSIDERED A HAZARD BY
INHALATION. IARC HAS CLASSIFIED CRYSTA LLINE SILICA AS CARCINOGENIC
TO HUMANS (GROUP 1). NTP HAS CLASSIFIED CRYSTALLINE SILICA A
REASONABLY ANTICIPATED CARCINOGEN. (SIGNS & SYMPTOMS OF
OVEREXPOSURE)
Effects of Overexposure:N/P. HEALTH HAZARDS ACUTE AND CHRONIC
(CONT): OF EYES, SEVERE EYE IRRITATION. INGESTION MAY CAUSE LUNG
INFLAMMATION & DAMAGE DUE TO ASPIRATION OF MATERIAL INTO LUNGS,
MUCOUS MEMBRANE IRRITATION, NAUSEA, VOMITING, DIARRHEA,
GASTRO-INTESTINAL DISTURBANCES, ABDOMINAL PAIN, CENTRAL NERVOUS
SYSTEM DEPRESSION. EXPLANATION OF CARCINOGENICITY (CONT):
CRYSTALLINE SILICA IS ALSO A KNOWN CAUSE OF SILICOSIS, A
NONCANCEROUS LUNG DISEASE.
Medical Cond Aggravated by Exposure:EYE, SKIN, RESPIRATORY DISORDERS,
LUNG DISORDERS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE AND SUPPORT
CONTINUED BREATHING. GET EMERGENCY MEDICAL ATTENTION. HAVE TRAINED
PERSON GIVE OXYGEN IF NECESSARY. GET MEDICAL HELP FOR ANY BREATHING
DIFFICULTY. REMOVE TO FRESH AIR IF INHALATION CAUSES EYE WATERING,
HEADACHES, DIZZINESS, OR OTHER DISCOMFORT. GET MEDICAL ATTENTION IF
DISCOMFORT OR IRRITATION PERSISTS. SKIN CONTACT: FLUSH FROM SKIN
WITH WATER. THEN WASH THOROUGHLY WITH SOAP AND WATER. REMOVE
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE RE-USE. IF
IRRITATION OCCURS, CONSULT A PHYSICIAN. EYE CONTACT: FLUSH
IMMEDIATELY WITH LARGE AMOUNTS OF WATER, (OTHER INFORMATION)
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:=-4.4C, 24.F
Lower Limits:1.2%
Upper Limits:7.0%
Extinguishing Media:DRY CHEMICAL OR FOAM, WATER FOG, CARBON DIOXIDE.
Fire Fighting Procedures:WATER MAY BE USED TO COOL AND PROTECT EXPOSED
CONTAINERS. FIREFIGHTERS SHOULD USE FULL PROTECTIVE CLOTHING, EYE
PROTECTION, AND (NIOSH APPROVED - ) SELF-CONTAINED BREATHING
APPARATUS. UNUSU AL FIRE & EXPLOSION HAZARD (CONT): UNDER
FIRE CONDITIONS EMITTING IRRITANT AND/OR TOXIC GASES.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT OR FIRE. VAPORS MAY IGNITE EXPLOSIVELY AT
AMBIENT TEMPERATURES. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL
LONG DISTANCES TO A SOURCE OF IGNI TION AND FLASH BACK. CLOSED
CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. MAY
DECOMPOSE (FIREFIGHTING PROC)
================== Accidental Release Measures ==================
Spill Release Procedures:COMPLY WITH ALL APPLICABLE HEALTH AND
ENVIRONMENTAL REGULATIONS. ELIMINATE ALL SOURCES OF IGNITION.
VENTILATE AREA WITH EXPLOSION-PROOF EQUIPMENT. SPILLS MAY BE
COLLECTED WITH ABSORBENT MATERIALS. USE NON-SPARKING TOOLS.
EVACUATE ALL UNNECESSARY PERSONNEL. PLACE COLLECTED MATERIAL IN
PROPER CONTAINER. COMPLETE PERSONAL PROTECTIVE EQUIPMENT MUST BE
USED DURING CLEANUP. (OTHER INFORMATION)
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE BELOW 80F. KEEP AWAY FROM HEAT,
SPARKS AND OPEN FLAME. OTHER PRECAUTIONS (CONT): TRANSFERRING
TO PREVENT ACCUMULATION OF STATIC CHARGE. WASH HANDS THOROUGHLY
AFTER HANDLING, ESPECIALLY BEFOR E EATING OR SMOKING.
Other Precautions:USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE
INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT WITH SKIN
AND EYES, AND BREATHING OF VAPORS. KEEP CONTAINERS TIGHTLY CLOSED
AND UPRIGHT WHEN NO T IN USE. EMPTY CONTAINERS MAY CONTAIN
HAZARDOUS RESIDUES. GROUND EQUIPMENT WHEN (HANDLING AND STORA GE
PRECAUTIONS)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW
APPLICABLE EXPOSURE STANDARDS WHEN USING THIS MATERIAL. WHEN
RESPIRATORY PROTECTION IS DETERMINED TO BE NECESSARY , USE A NIOSH
(CANADIAN Z94.4) APPROVED ELA STOMERIC SEALING-SURFACE FACEPIECE
RESPIRATOR OUTFITTED WITH ORGANIC VAPOR CARTRIDGES AND PAINT SPRAY
(DUST/MIST) PREFILTERS. (SUPPLEMENTAL SAFETY AND HEALTH)
Ventilation:PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT
BUILD-UP OF VAPORS. USE EXPLOSION-PROOF EQUIPMENT. USE NON-SPARKING
EQUIPMENT.
Protective Gloves:IMPERVIOUS GLOVES
Eye Protection:SAFETY GLASSES OR GOGGLES (ANSI APPROVED - ).
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
CRITERIA . IMPERVIOUS CLOTHING, FACE SHIELD.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, SMOKING OR USING TOILET. LAUNDER CONTAMINATED CLOTHES
BEFORE REUSE.
Supplemental Safety and Health
ITEM NAME (CONT): MULTI-PURPOSE CONSTRUCTION ADHESIVE. PRODUCT
USE: ADHESIVE / CAULK. RESPIRATORY PROTECTION (CONT):
DETERMINE THE PROPER LEVEL OF PROTECTION BY CONDUCTING APPROPRIATE
AI R MONITORING. CONSULT 29 CFR 1910.134 FOR SELECTION OF
RESPIRATORS (CANADIAN Z94.4).
================== Physical/Chemical Properties ==================
Boiling Pt:=56.1C, 133.F
Vapor Pres:NOT AVAILABLE
Spec Gravity:1.443
pH:NOT AVAILABLE
Solubility in Water:NO
Appearance and Odor:PASTE, TAN COLOR. ODOR: NOT SPECIFIED BY
MANUFACTURER .
Percent Volatiles by Volume:32.31
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS, BASES, AMINES, NITRIC ACID
Stability Condition to Avoid:ELEVATED TEMPERATURES, CONTACT WITH
OXIDIZING AGENT, SPARKS, OPEN FLAME, IGNITION SOURCES
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, ACRID
FUMES, FORMALDEHYDE, OXIDES OF SULFUR, TOXIC GASES.
=================== Toxicological Information ===================
Toxicological Information:SUPPLEMENTAL HEALTH INFORMATION: CONTAINS A
CHEMICAL THAT MAY BE ABSORBED THROUGH THE SKIN. NOTICE - REPORTS
HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO
SOLVENTS WITH PERMANENT BRAIN AND NEERVOUS SYSTEM DAMAGE.
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE
CONTENTS MAY BE HARMFUL OR FATAL. OTHER EFFECTS OF OVEREXPOSURE MAY
INCLUDE TOXICITY TO THE KIDNEYS . REPRODUCTIVE EFFECTS: NO
REPRODUCTIVE EFFECTS ARE ANTICIPATED. MUTAGENICITY: NO MUTAGENIC
EFFECTS ARE ANTICIPATED. TERATOGENICITY: NO TERATOGENIC EFFECTS
ARE ANTICIPATED. (ECOLOGICAL INFO)
===================== Ecological Information =====================
Ecological:NO ECOLOGICAL TESTING HAS BEEN DONE BY ICI PAINTS ON THIS
PRODUCT AS A WHOLE. TOXICOLOGICAL INFO (CONT): LIMESTONE
(CAS 1317-65-3): CARCINOGENICITY: NTP-NO, IARC-NO, OSHA-NO,
ACGIH-NO; LD50: 64 50 MG/KG (ORL, RAT). CLAY (CAS 1332-58-7):
CARCINOGENICITY: NTP-NO, IARC-NO, OSHA-NO, ACGIH-NO. QUARTZ (CAS
14808-60-7): CARCINOGENICITY: NTP-YES, IARC-YES 1, OSHA-NO,
ACGIH-NO. MAGNESIUM CARBONATE (CAS 546-93-0): CARCINOGENICITY:
NTP-NO, IARC-NO, OSHA-NO, ACGIH-NO; LD50: 16 MG/KG (ITR, MOU).
PETROLEUM HYDROCARBON (CAS 64742-52-5): CARCINOGENICITY: NTP-NO,
IARC-YES 1, OSHA-NO, ACGIH-NO; LD50: >2000 MG/KG (SKN,
RBT).(ECOLOGICAL INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
=================== MSDS Transport Information ===================
Transport Information:DOT: ADHESIVE,3, UN1133,III. IMDG: ADHESIVE,3,
UN1133,III, LIMITED QUANTITY. IATA: NOT AVAILABLE. TDG: NOT
AVAILABLE. ECOLOGICAL INFO (CONT): LIGHT ALIPHATIC SOLVENT
NAPHTHA (PETROLEUM) (C AS 64742-89-8): CARCINOGENICITY: NTP-NO,
IARC-NO, OSHA-NO, ACGIH-NO; LD50: >3.16 G/KG (SKN, RBT), >5 G/KG
(ORL, RAT). ACETONE (CAS 67-64-1): CARCINOGENICITY: NTP-NO,
IARC-NO, OSHA-NO, ACGIH-NO; LD50: 5800 MG/KG (ORL, RAT), >9400
MG/KG (SKN, GPG). AROMATIC HYDROCARBON RESIN (CAS 68410-16-2):
CARCINOGENICITY: NTP-NO, IARC-NO, OSHA-NO, ACGIH-NO. ROSIN
GLYCEROL ESTER (CAS 8050-31-5): CARCINOGENICIT Y: NTP-NO, IARC-NO,
OSHA-NO, ACGIH-NO.
===================== Regulatory Information =====================
SARA Title III Information:ACETONE (CAS 67-64-1): SARA 302 - NO, SARA
313 - NO.
Federal Regulatory Information:ACETONE (CAS 67-64-1): CERCLA 302.4 -
YES, HAZ AIR POLLUTANT - NO, MARINE POLTNT - NO. AS OF THE DATE
OF THIS MSDS, ALL COMPONENTS OF THIS MSDS ARE LISTED (OR ARE EXEMPT
FROM LISTING) ON THE TSCA INVENTORY. THIS PRODUCT HAS BEEN
CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR (
CONTROLLED PRODUCT REGULATIONS) AND THE MSDS CONTAINS ALL THE
INFORMATION REQUIRED BY CPR.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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