===================== Product Identification =====================
MSDS NAME:SULFURIC ACID 96%
Status Code:A
MSDS Number: CLFVY
=== Responsible Party ===
Company:MALLINCKRODT INC, SPECIALTY PRODUCTS DIV
Address:PO BOX 800
City:PARIS
State:KY
ZIP:40362
Info Phone Num:314-982-5000
Emergency Phone Num:314-539-1600
CAGE:DO440
=== Contractor Identification ===
Company:MALLINCKRODT INC (CANCELED W/REPLACEMENT 62910)
City:PARIS
State:KY
ZIP:40361
Country:US
CAGE:7P097
Company:MALLINCKRODT INC, SPECIALTY PRODUCTS DIV
Address:PO BOX 800
City:PARIS
State:KY
ZIP:40362
Phone:314-982-5000
CAGE:DO440
Company:WARDS NATURAL SCIENCE ESTABLISHMENT INC
Address:5100 W HENRIETTA RD
Box:92912
City:ROCHESTER
State:NY
ZIP:14692-9012
Country:US
Phone:(716) 359-2502
Contract Num:MDA414-00-P-0384
CAGE:63759
Company:WARDS NATURAL SCIENCE ESTABLISHMENT INC
Address:5100 W HENRIETTA RD
Box:92912
City:ROCHESTER
State:NY
ZIP:14692-9012
Country:US
Phone:(716) 359-2502
Contract Num:MDA414-01-P-1784
CAGE:63759
============= Composition/Information on Ingredients =============
Name:SULFURIC ACID
CAS:7664-93-9
RTECS #:WS5600000
= Wt:96.
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
ACGIH STEL:3 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 ORAL RAT: 2140 MG/KG
Health Hazards Acute and Chronic:INHALATION: INHALATION PRODUCES
DAMAGING EFFECTS ON THE MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT.
MAY CAUSE LUNG EDEMA. INGESTION: CORROSIVE. SKIN CONTACT:
CORROSIVE. EYE CONTACT: CORROSIVE. CHRONIC EXPOSURE: LONG-TERM
EXPOSURE TO MIST OR VAPORS MAY CAUSE DAMAGE TO TEETH.
Effects of Overexposure:INHALATION: SYMPTOMS MAY INCLUDE IRRITATION OF
THE NOSE, & LABORED BREATHING. INGESTION: SWALLOWING CAN CAUSE
SEVERE BURNS TO THE MOUTH, THROAT & STOMACH, LEADING TO DEATH. CAN
CAUSE SORE THROAT, VOMI TING, DIARRHEA. SKIN CONTACT: SYMPTOMS OF
REDNESS, PAIN & SEVERE BURNS CAN OCCUR. EYE CONTACT: SPLASHES CAN
CAUSE BLURRED VISION, REDNESS, PAIN & SEVERE TISSUE BURNS.,
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE
MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
======================= First Aid Measures =======================
First Aid:INHALED-REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
CALL PHYSICIAN. INGESTION-DO NOT INDUCE VOMITING! GIVE LARGE
QUANTITIES OF WATER OR MILK IF AVAILABLE. CALL A PHYSICIAN
IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
SKIN-IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES
WHILE REMOVING CONTAMINATED CLOTHES & SHOES. CALL A PHYSICIAN.
EYES-WASH WITH PLENTY OF WATER FOR AT LEAST 15 MINS, LIFTING LOWER
& UPPER EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IMMEDIATELY.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE. DO NOT USE
WATER ON MATERIAL. HOWEVER, WATER SPRAY MAY BE USED TO KEEP FIRE
EXPOSED CONTAINERS COOL.
Fire Fighting Procedures:IN THE EVENT OF FIRE, WEAR FULL PROTECTIVE
CLOTHING & NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH
FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE
PRESSURE MODE. STRUCTURA L FIREFIGHTER`S PROTECTIVE CLOTHING IS
INEFFECTIVE FOR FIRES INVOLVING THIS MATERIAL. STAY AWAY FROM
SEALED CONTAINERS.
Unusual Fire/Explosion Hazard:NOT COMBUSTIBLE, BUT SUBSTANCE IS A
STRONG OXIDIZER AND ITS HEAT OF REACTION WITH REDUCING AGENTS OR
COMBUSTIBLES MAY CAUSE IGNITION.
================== Accidental Release Measures ==================
Spill Release Procedures:DIKE & COVER LEAKING, SPILLED LIQUID WITH
DIRT, VERMICULITE, KITTY-LITTER OR OTHER INERT ABSORBENT. COVER
SPILL WITH SODIUM BICARBONATE/SODA ASH & MIX. CLEAN-UP PERSONNEL
REQUIRE PROTECTIVE CLOTHING & RESPIRATORY PROTECTION FROM VAPORS &
MISTS. NEUTRALIZED WASTE MAY BE CONTAINERIZED & DISPOSED IN RCRA
APPROVED WASTE DISPOSAL FACILITY. FLUSH SPILL AREA WITH DILUTE SODA
ASH SOLUTIO/DISCARD TO SEWER.
Neutralizing Agent:SODA ASH
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A DRY, VENTILATED STORAGE
AREA WITH ACID RESISTANT FLOORS & GOOD DRAINAGE. PROTECT FROM
PHYSICAL DAMAGE. KEEP OUT OF DIRECT SUNLIGHT & AWAY FROM HEAT,
WATER & INCOMPATIBLE MATERIALS. DO NOT W ASH OUT CONTAINER & USE
FOR OTHER PURPOSES.
Other Precautions:WHEN DILUTING ALWAYS ADD THE ACID TO WATER, NEVER ADD
WATER TO THE ACID.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF THE TLV IS EXCEEDED A FULL FACEPIECE CHEMICAL
CARTRIDGE RESPIRATOR MAY BE WORN, IN GENERAL, UP TO 100 TIMES THE
TLV OR THE MAXIMUM USE CONCENTRATION SPECIFIED BY THE RESPIRATOR
SUPPLIER, WHICHEVER IS LESS. ALTERNATIVELY, A SUPPLIED AIR FULL
FACEPIECE RESPIRATOR OR AIRTIMED HOOD MAY BE WORN.
Ventilation:A SYSTEM OF LOCAL &/OR GENERAL EXHAUST IS RECOMMENDED TO
KEEP EMPLOYEE EXPOSURE BELOW AIRBORNE EXPOSURE LIMITS. LOCAL
EXHAUST IS PREFERRED.
Protective Gloves:WEAR IMPERVIOUS PROTECTIVE GLOVES.
Eye Protection:USE CHEMICAL SAFETY GOGGLES &/OR FULL FACE SHIELD.
Other Protective Equipment:WEAR IMPERVIOUS PROTECTIVE CLOTHING,
INCLUDING BOOTS, GLOVES, LAB COAT, APRON OR COVERALLS TO PREVENT
SKIN CONTACT. MAINTAIN EYE WASH FOUNTAIN & QUICK DRENCH FACILITIES
IN WORK AREA.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING
WITH THIS MATERIAL. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PRECAUTIONARY MEASURES: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO
NOT BREATHE MIST. KEEP CONTAINER TIGHTLY CLOSED. USE ONLY WITH
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. THIS SUBSTA
NCE IS CLASSIFIED AS A POISON UNDER THE FEDERAL CAUSTIC POISON ACT.
WARDS INC. P/N: 37-5770.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:=310.C, 590.F
B.P. Text:CALCULATED.
Melt/Freeze Pt:=-14.C, 6.8F
M.P/F.P Text:CALCULATED.
Vapor Pres:1 MMHG
Vapor Density:<0.3@25C
Spec Gravity:1.84
Solubility in Water:INFINITE @20C.
Appearance and Odor:COLORLESS, OILY LIQUID. ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, BASES, ORGANIC MATERIAL, HALOGENS, METAL ACETYLIDES, OXIDES &
HYDRIDES, STRONG OXIDIZING & REDUCING AGENTS & MANY OTHER REACTIVE
SUBSTANCES.
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE
AND STORAGE.
Hazardous Decomposition Products:TOXIC FUMES OF OXIDES OF SULFUR. WILL
REACT WITH WATER OR STEAM TO PRODUCE TOXIC & CORROSIVE FUMES.
REACTS WITH WITH CYANIDES & SULFIDES TO FORM TOXIC HCN & H2S.REACTS
W/CARBONATE TO FORM CO2.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:ORAL RAT LD50: 2140 MG/M3. INHALATION GUINEA
PIG LC50: 18 MG/M3. OSHA PERMISSIBLE EXPOSURE LIMIT: 1 MG/M3 (TWA).
ACGIH THRESHOLD LIMIT VALUE (TLV): 1 MG/M3 (TWA).
==================== Disposal Considerations ====================
Waste Disposal Methods:ENSURE COMPLIANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:DOT HAZARD CLASS: CORROSIVE MATERIAL.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 311/312 REPORTING: ACUTE, CHRONIC,
REACTIVE. SECTION 302: RQ=1000 LBS. TPQ=1000 LBS. SARA SECTION 313
CHEMICALS: NAME LIST-YES. CHEMICAL CATEGORY-NO.
Federal Regulatory Information:CERCLA SECTION 103: RQ=1000 LBS. RCRA
SECTION 261.33: NO.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|