===================== Product Identification =====================
MSDS NAME:1021, SIFCO DALIC SOLUTION NO.1 ETCHING
NIIN:01-267-4645
Status Code:A
MSDS Number: CLFVP
=== Responsible Party ===
Company:SIFCO SELECTIVE PLATING DIV OF SIFCO INDUSTRIES INC.
Address:5708 SCHAAF ROAD
City:CLEVELAND
State:OH
ZIP:44131-1394
Country:US
Info Phone Num:216-524-0099/ FAX: -6331
Emergency Phone Num:(800)424-9300
Resp. Party Other MSDS Num.:1021
Chemtrec Ind/Phone:(800)424-9300
CAGE:11924
=== Contractor Identification ===
Company:SIFCO SELECTIVE PLATING DIV OF SIFCO INDUSTRIES INC.
Address:5708 SCHAAF ROAD
Box:City:CLEVELAND
State:OH
ZIP:44131-1394
Country:US
Phone:216-524-0099/ FAX: -6331
Contract Num:SP0450-01-M-ZD41
CAGE:11924
============= Composition/Information on Ingredients =============
Name:SULFURIC ACID
CAS:7664-93-9
RTECS #:WS5600000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
ACGIH STEL:3 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:AMMONIUM SULFATE
CAS:7783-20-2
RTECS #:BS4500000
Minumum % Wt:7.
Maxumum % Wt:13.
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:82.
Maxumum % Wt:92.
===================== Hazards Identification =====================
LD50 LC50 Mixture:NO DATA PROVIDED BY MANUFACTURER
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: CAUSES EYE IRRITATION, BURNS
POSSIBLE. MAY CAUSE PAIN, TEARING, REDDENING AND SWELLING
ACCOMPANIED BY A STINGING SENSATION IN THE EYES. SKIN: CAUSES SKIN
IRRITATION. MAY CAUSE SKIN BURNS. MAY CAU SE ALLERGIC SKIN
REACTION. INHALATION: IRRITATING TO THE EYES, NOSE, THROAT, AND
LUNGS. MAY CAUSE SNEEZING, NASAL DISCHARGE, COUGHING, HEADACHES,
DIZZINESS, NAUSEA, FATIGUE OR DIFFICULTY IN BREATHING. INGESTION:
IRRITATING TO MOUTH, THROAT, AND STOMACH. MAY CAUSE BURNS TO MUCOUS
MEMBRANES. CHRONIC: PROLONGED OR REPEATED EXPOSURE MAY CAUSE DAMAGE
TO SKIN, EYES, RESPIRATORY SYSTEM AND TEETH.
Explanation of Carcinogenicity:ACGIH: SUSPECTED.
Effects of Overexposure:EYE: CAUSES EYE IRRITATION, BURNS POSSIBLE. MAY
CAUSE PAIN, TEARING, REDDENING AND SWELLING ACCOMPANIED BY A
STINGING SENSATION IN THE EYES. SKIN: CAUSES SKIN IRRITATION. MAY
CAUSE SKIN BURNS. MAY CAU SE ALLERGIC SKIN REACTION. INHALATION:
IRRITATING TO THE EYES, NOSE, THROAT, AND LUNGS. MAY CAUSE
SNEEZING, NASAL DISCHARGE, COUGHING, HEADACHES, DIZZINESS, NAUSEA,
FATIGUE OR DIFFICULTY IN BREATHING. INGESTION: IRRITATING TO
MOUTH, THROAT, AND STOMACH. MAY CAUSE BURNS TO MUCOUS MEMBRANES.
Medical Cond Aggravated by Exposure:PREEXISTING SKIN AND EYE
CONDITIONS; RESPIRATORY SYSTEM DISORDERS.
======================= First Aid Measures =======================
Eyes: HOLD LIDS APART & FLUSH WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES. SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR
AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING & SHOES.
THOROUGHL Y DECONTAMINATE (OR DISCARD) CLOTHING & SHOES.
INHALATION: REMOVE TO FRESH AIR. LAY VICTIM DOWN, LEGS RAISED.
LOOSEN TIGHT CLOTHING, COVER WITH A BLANKET. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION . IF BREATHING IS DIFFICULT, GIVE OXYGEN.
INGESTION: DO NOT INDUCE VOMITING, UNLESS ADVISED BY EMS. GIVE
VICTIM LARGE QUANTITIES OF WATER OR MILK. GIVE MILK OF MAGNESIA OR
FRESH EGGS. NOTHING BY MOUTH IF UNCONSCIOUS.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:N.A
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:ALL
Fire Fighting Procedures:NIOSH/MSHA APPROVED POSITIVE-PRESSURE
SELF-CONTAINED BREATHING APPARATUS. STRUCTURAL FIRE FIGHTERS'
PROTECTIVE CLOTHING MAY NOT PROVIDE ADEQUATE PROTECTION.
Unusual Fire/Explosion Hazard:CONTACT WITH METALS MAY FORM FLAMMABLE
HYDROGEN GAS. CONTAINERS CAN BUILD UP PRESSURE AND BURST IF EXPOSED
TO HEAT (FIRE). WATER RUNOFF CAN CAUSE ENVIRONMENTAL DAMAGE. DIKE
AREA FOR LATER DISPOSAL.
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
ISOLATE HAZARD AREA AND KEEP PEOPLE AWAY. NOTIFY YOUR FACILITY
EMERGENCY COORDINATOR. ELIMINATE ALL SOURCES OF IGNITION. PROVIDE
MAXIMUM VENTILATION. DO NOT RELEASE INTO SOIL, SEWERS, OR NATURAL
BODIES OF WATER. WEAR PROTECTIVE EQUIPMENT (PPE). SEE OTHER
INFORMATION.
Neutralizing Agent:SODIUM BICARBONATE, SODA ASH/SLAKED LIME.
====================== Handling and Storage ======================
Handling and Storage Precautions:USE "BUDDY SYSTEM" WHEN WORKING WITH
CHEMICALS. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. DO NOT BREATHE
VAPOR, MIST OR GAS. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY
AFTER HANDLING. TRIPLE RINSE CONTAINER CLEAN BEFORE DISCARDING.
PUT NOTHING ELSE IN THIS CONTAINER.
Other Precautions:STORE AT 60-90F AWAY FROM INCOMPATIBLE MATERIALS AND
PHYSICAL HAZARDS. DO NOT REMOVE OR DEFACE CONTAINER LABELS. KEEP
CONTAINER TIGHTLY CLOSED IN UPRIGHT POSITION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS ARE NOT FEASIBLE, THE
RESPIRATORY PROTECTION PROGRAM MUST COMPLY WITH OSHA 20 CFR
1910.134 REQUIREMENTS.
Ventilation:LOCAL EXHAUST VENTILATION IS REQUIRED TO MEET THE
PERMISSIBLE EXPOSURE LIMITS (PEL) DURING THE USE OF THIS PRODUCT.
Protective Gloves:NITRILE, NEOPRENE, VINYL, LATEX GLOVES.
Eye Protection:FACE SHIELD AND SAFETY GLASSES W/SIDE SHIELDS OR
SPLASH-PROOF CHEMICAL GOGGLES.
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, WASHING
FACILITIES NEAR WORK AREA. IMPERVIOUS BOOTS, APRON, PROTECTIVE
CLOTHING AS REQUIRED BYJOB CONDITIONS.
Work Hygienic Practices:DO NOT WEAR CONTACT LENSES. WASH THOROUGHLY
AFTER HANDLING.
Supplemental Safety and Health
NO DATA PROVIDED BY MANUFACTURER
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:<0.C, 32.F
Vapor Pres:N.A.
Vapor Density:N.A.
Spec Gravity:1.075-1.085
pH:0-1
Evaporation Rate & Reference:<1 (ETHYL ETHER=1)
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID, NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH REACTIVE METALS, STRONG BASES, OXIDIZERS.
Stability Condition to Avoid:STABLE UNDER NORMAL AMBIENT CONDITIONS.
Hazardous Decomposition Products:H2, SOX, NH3.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:NOT AVAILABLE.
===================== Ecological Information =====================
Ecological:NOT AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:SHIP TO APPROVED TREATMENT/DISPOSAL FACILITY.
DISPOSE OF ACCORDING TO LOCAL, STATE, AND FEDERAL REGULATIONS. EPA
WASTE ID NUMBER: D002. FOLLOW THE APPLICABLE REGULATIONS FOR
DISPOSAL OF EMPTY CONTAINR S AND RINSATE. THE DISPOSAL INFORMATION
APPLIES TO THE MATERIAL AS MANUFACTURED. CONTAMINATION MAY A FFECT
THE DISPOSAL REQUIREMENTS.
=================== MSDS Transport Information ===================
Transport Information:US DOT/IATA/ICAO/IMO DESCRIPTION: PROPER SHIPPING
NAME: SULFURIC ACID, WITH NOT MORE THAN 51% ACID. HAZARD CLASS: 8.
IDENTIFICATION NUMBER: UN2796. PACKAGING GROUP (PG): II. LABEL
REQUIREMENTS: 8 - CO RROSIVE. UNIT CONTAINER: 1,4,8,20 LITER
POLYETHYLENE CONTAINER MEETS PERFORMANCE ORIENTED PACKAGAING
REQUIREMENTS. REPORTABLE QUANTITY (RQ): >9,000 LITERS. ERG# 157.
===================== Regulatory Information =====================
SARA Title III Information:SIFCO SELECTIVE PLATING IS REQUIRED TO
INFORMA YOU, THAT THIS PRODUCT CONTAINS A TOXIC CHEMICAL OR
CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF
TITLE III OF SARA AND 40 CFR PART 3 72, IF SPECIFIED ANNUAL
THRESHOLDS AARE MET OR EXCEEDED: SULFURIC ACID, CAS# 7664-93-9, 5%;
AMMONIUM SULFATE, CAS# 7783-20-2, 13%. IF YOU REPACKAGE OR
OTHERWISE REDISTRIBUTE THIS PRODUCT TO INDUSTRIAL CUSTOMERS YOU
ARE FUTHER REQUIRED TO FURNISH SIMILAR NOTIFICATION TO THEM.
Federal Regulatory Information:CERCLA & EPCRA: THRESHOLD PLANNING
QUANTITY: >9,000 LITERS. (RELEASE) REPORTABLE QUANTITY: >9,000
LITERS. EXTREMELY HAZARDOUS SUBSTANCE: SULFURIC ACID. EPCRA HAZARD
CATEGORIES: IMMEDIATE (ACUTE) HEAL TH: YES. DELAYED (CHRONIC)
HEALTH: YES FIRE/SUDDEN RELEASE OF PRESSURE/REACTIVITY: NO. TSCA:
ALL INGREDIENTS OF THIS PRODUCT ARE LISTED UNDER THE TSCA. ODS:
THIS PRODUCT DOES NOT CONTAIN & IS NOT MANU FACTURED WITH OZONE
DEPLETING SUBSTANCES 9ODS). VOC: THIS PRODUCT DOES NOT CONTAIN ANY
VOLATILE ORGA NIC COMPOUNDS (VOC). PCB: PRODUCT DOES NOT CONTAIN
ANY POLYCHLORINATE BIPHENYLS (PCB).
State Regulatory Information:CALIFORNIA PROPOSITION 65: NOT APPLICABLE.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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