===================== Product Identification =====================
MSDS NAME:GLYCOL ETHER DM
NIIN:01-089-5514
MSDS Number: BGLKH
=== Responsible Party ===
Company:ASHLAND CHEMICAL COMPANY
Box:2219
City:COLUMBUS
State:OH
ZIP:43216
Country:US
Info Phone Num:614-790-3333
Emergency Phone Num:1-800-274-5263
CAGE:5A188
=== Contractor Identification ===
Company:ASHLAND CHEMICAL CO
Address:5200 PAUL BLAZEL MEMORIAL PARKWAY
Box:City:DUBLIN
State:OH
ZIP:43017
Country:US
Phone:614-889-4505
CAGE:5A188
Company:CHEMICAL SPECIALISTS AND DEVELOPMENT INC
Address:2210 HACKBERRY LN
Box:687
City:CONROE
State:TX
ZIP:77305
Country:US
Phone:409-756-1065
CAGE:4N760
============= Composition/Information on Ingredients =============
Name:DIETHYLENE GLYCOL MONOMETHYL ETHER
CAS:111-77-3
RTECS #:KL6125000
= Wt:100.
Other REC Limits:NONE
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: LIVER, TESTES, &
KIDNEYS. EYES: MAY CAUSE MILD IRRITATION. SKIN: MAY CAUSE MILK
IRRITATION. INGESTION: SWALLOWING SMALL AMOUNTS OF MATERIAL DURING
NORMAL HANDLING IS NOT LIKELY TO CA USE HARMFUL EFFECTS. LARGE
AMOUNTS MAY BE HARMFUL. INHALATION: BREATHING LARGE AMOUNTS MAY BE
HARMFUL.
Explanation of Carcinogenicity:PRODUCT IS NOT LISTED AS A CARCINOGEN BY
IARC, NTP, OR OSHA.
Effects of Overexposure:SIGNS & SYMPTOMS OF EXPOSURE TO THIS MATERIAL
THROUGH BREATHING, SWALLOWING, AND/OR PASSAGE OF THE MATERIAL
THROUGH THE SKIN MAY INCLUDE: STOMACH OR INTESTINAL UPSET (NAUSEA,
VOMITING, DIARRHEA), IRRI TATION (NOSE, THROAT, AIRWAYS). EYES:
STINGING, TEARING, & REDNESS. SKIN: REDNESS & BURNING.
Medical Cond Aggravated by Exposure:MAY AGGRAVATE PRE-EXISTING
DISORDERS OF: LIVER ABNORMALITIES, TESTIS DAMAGE, & KIDNEY DAMAGE.
======================= First Aid Measures =======================
Eyes: IMMEDIATELY FLUSH GENTLY WITH WATER FOR AT LEAST 15 MIN
WHILE HOLDING EYELIDS APART. SEEK IMMEDIATE MEDICAL ATT'N. SKIN:
REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH SOAP & WATER.
IF SY MPTOMS PERSIST, SEEK MEDICAL ATT'N. INGESTION: SEEK MEDICAL
ATT'N. IF INDIVIDUAL IS DROWSY OR UNCONSCIOUS, DON'T GIVE ANYTHING
BY MOUTH; PLACE INDIVIDUAL ON THE LEFT SIDE WITH THE HEAD DOWN. IF
INDIV IDUAL IS CONSCIOUS & ALERT, INDUCE VOMITING BY GIVING SYRUP
OF IPECAC OR BY GENTLY PLACING TWO FINGERS AT THE BACK OF THE
THROAT. INHALATION: IF SYMPTOMS PRESENT, IMMED. MOVE PERSON AWAY
FROM EXPOSUR E & INTO FRESH AIR. SEEK DOCTOR.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:=91.7C, 197.F
Autoignition Temp:Autoignition Temp Text:NO DAT
Lower Limits:NO DATA
Upper Limits:NO DATA
Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL
Fire Fighting Procedures:WATER MAY BE USED TO EXTINGUISH FIRE BY
COOLING, & DILUTING LIQUID WITH WTER. WEAR A SELF-CONTAINED
BREATHING APPARATUS WITH A FULL PACEPIECE OPERATED IN THE POSITIVE
PRESSURE DEMAND MODE WITH APPROPR IATE TURN-OUT GEAR & CHEMICAL
RESISTANT PERSONAL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL
ALONG THE GROUND OR BE MOVED BY VENTILATION & IGNITED BY HEAT,
PILOT LIGHTS, OTHER FLAMES & IGNITION SOURCES AT LOCATIONS DISTANT
FROM MATERIAL HANDLING POINT.
================== Accidental Release Measures ==================
Spill Release Procedures:SM SPILL: ABSORB LIQUID ON VERMICULITE, FLOOR
ABSORBENT, OR OTHER ABSORBENT MATERIAL & TRANSFER TO HOOD. LG
SPILL: ELIMINATE ALL IGNITION SOURCES. WEAR PROTECTIVE EQUIPMENT.
STOP SPILL AT SOURCE. PRE VENT FROM ENTERING DRAINS, SEWERS,
STREAMS OR OTHER BODIES OF WATER. PUMP OR VACUUM TRANSFER SPILLED
PRODUCT TO CLEAN CONTAINERS. ABSORBE UNRECOVERABLE PRODUCT. NOTIFY
AUTHORITIES AS REQUIRED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS WHEN EMPTIED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF OVEREXPOSURE HAS BEEN DETERMINED OR
DOCUMENTED, NIOSH/MSHA
Ventilation:PROVIDE SUFFICIENT VENTILATION TO MAINTAIN EXPOSURE BELOW
PEL/TLV. SUPPLEMENT WITH LOCAL EXHAUST IF NEEDED.
Protective Gloves:NITRILE RUBBER
Eye Protection:CHEMICAL SPLASH GOGGLES/ SAFETY GLASSES
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:V4
Boiling Pt:B.P. Text:NO DATA
Melt/Freeze Pt:=-85.C, -121.F
Vapor Pres:.000 @ 68 F (FOR PRODUCT)
Vapor Density:4.150
Spec Gravity:1.021 - 1.025 @ 68 DEG F
VOC Grams/Liter:8.51
Viscosity:3.4 CPS
Evaporation Rate & Reference:0.02 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETELY MISCIBLE
Appearance and Odor:COLORLESS LIQUID, MILD ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:NONE PROVIDED BY MFR.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:NO DATA
===================== Ecological Information =====================
Ecological:NO DATA
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE, AND FEDERAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:COMBUSTIBLE LIQUID, NOS (DIETHYLENE GLYCOL
MONOMETHYL ETHER), NA1993, PG III
===================== Regulatory Information =====================
SARA Title III Information:NO SARA 302 COMPONENTS. DELAYED AND FIRE
HAZARD CLASS FOR SECTION 311/312. SARA 313 COMPONENTS: DIETHYLENE
GLYCOL MONOMETHYL ETHER.
Federal Regulatory Information:RSCA- THE INTENTIONAL INGREDIENTS OF
THIS PRODUCT ARE LIASTED. NO CERCLA RQ ITEMS.
State Regulatory Information:CALIFORNIA PROPOSITION 65: NONE. NEW
JERSEY RTK LABEL INFORMATION: DIETHYLENE GLYCOL MONOMETHYL ETHER.
PENNSYLVANIA RTK LABEL INFORMATION: ETHANOL, 2-(2-METHOXYETHOXY)-
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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