===================== Product Identification =====================
MSDS NAME:CALCO UNLEADED GASOLINE
NIIN:00-148-7103
MSDS Number: BGWLH
=== Responsible Party ===
Company:CHEVRON ENVIRONMENTAL HEALTH CENTER,INC.
Address:15299 SAN PABLO AVE.
Box:4054
City:RICHMOND
State:CA
ZIP:94804-0054
Country:US
Info Phone Num:415-233-3737
Emergency Phone Num:415-233-3737
CAGE:0AHD1
=== Contractor Identification ===
Company:CHEVRON ENVIRONMENTAL HEALTH CENTER INC
Address:15299 SAN PABLO AVE
Box:4054
City:RICHMOND
State:CA
ZIP:94804
Country:US
Phone:800-582-3835
CAGE:0AHD1
============= Composition/Information on Ingredients =============
Name:GASOLINE
CAS:8006-61-9
RTECS #:LX3300000
Fraction by Wt: TO 100%
OSHA PEL:300 PPM/500 STEL
ACGIH TLV:300 PPM/500STEL;9192
Name:BENZENE (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: 1.2-1.4%
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9192
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 4.3-6.5%
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:XYLENES (O-,M-,P- ISOMERS) (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 5.1-7.7%
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:METHYL TERT-BUTYL ETHER (SARA III)
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: <10%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:CYCLOHEXANE (SARA III)
CAS:110-82-7
RTECS #:GU6300000
Fraction by Wt: 0.5-2.4%
OSHA PEL:300 PPM
ACGIH TLV:300 PPM, 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 1.2-1.4%
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL RAT LD50 18,800 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:PRODUCT IS IRRITATING TO
EYE,SKIN,RESPIRATORY TRACT AND DEPRESSES THE CENTRAL NERVOUS
SYSTEM. CHRONIC OVER EXPOSURE MAY CAUSE LIVER,KIDNEY, OR CENTRAL
NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:CONTAINS BENZENE;LISTED BY ALL THREE.
ALSO AN API STUDY FOUND LIVER CANCER IN MICE EXPOSED TO GASOLINE
VAPORS.
Effects of Overexposure:EYE/SKIN CONTACT:TRANSITORY IRRITATION.
INHALED:RESPIRATORY IRRITATION,CENTRAL NERVOUS SYSTEM DEPRESSION
INCLUDING,EUPHORIA,HEADACHE,DIZZINESS,DROWINESS,FATIGUE,TREMORS,CON
VULSIONS,NAUSEA,VOMITING,DIA RRHEA,LOSS OF CONSCIOUSNESS.AND
FINALLYDEATH. INGESTED:G/I IRRITATION,PLUS SYMPTOMS SIMILAR TO
THOSE UNDER "INHALED".
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE,SKIN CONDITIONS OR
IMPAIRED LIVER,KIDNEY FUNCTION MAY BE AGGRAVATED BY THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH WITH WATER 15 MIN. SKIN:WASH WITH SOAP & WATER.
REMOVE CONTAMINATED CLOTHING;LAUNDER BEFORE REUSE. INHALED:REMOVE
TO FRESH AIR.RESUSCITATE OR GIVE OXYGEN AS NEEDED. GET MEDICAL
CARE. INGESTE D:GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE
VOMITING. IF VOMITING OCCURS,MINIMIZE ASPIRATION HAZARD.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:<-49F
Lower Limits:1.3
Upper Limits:7.6
Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,FOAM,WATER FOG. WATER
MAY BE INEEFFECTIVE,AS,PRODUCT WILL FLOAT AND MAY SPREAD FIRE.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS IN
ENCLOSED AREAS. WATER SPRAY MAY BE USED TO COOL FIRE EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR,ACCUMULATING
IN LOW AREAS,TRAVELING ALONG GROUND AND MAY FLASH BACK FROM DISTANT
IGNITION SOURCE.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE IGNITION SOURCES. ISOLATE AREA. USE
PROTECTIVE EQUIPMENT AS NECESSARY. STOP LEAK AND CONTAIN SPILL.
DIKE AS NEEDED TO KEEP SPILL FROM DRAINS,WATER WAYS ETC. WATER FOG
MAY BE USED TO REDUCE V APORS & PERSONAL HAZARD. REPORT SPILL PER
LAW.
Neutralizing Agent:NONE
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL,DRY,ISOLATED,WELL
VENTILATED WATER AREA. KEEP IGNITION SOURCES AWAY. GROUND
CONTAINERS TO PREVENT STATIC DISCHARGE DURING TRANSFERS.
Other Precautions:FIRE AND EXPLOSION ARE THE ACUTE HAZARDS OF THIS
PRODUCT. TAKE EXTRAORDINARY STEPS TO PREVENT THEM.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF NEEDED,USE NIOSH/MSHSA RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGE OR PREFERRABLY, POSITIVE PRESSURE AIR
SUPPLIED RESPIRATOR OR SELF CONTAINED BREATHING APPARATUS.
Ventilation:USE EXPLOSION PROOF VENTILATION EQUIPMENT TO MAINTAIN
EXPLOSURE BELOW PEL/TLV.
Protective Gloves:IMPERVIOUS RUBBER OR POLYMER.
Eye Protection:SAFETY GLASSES,OR SPLASH GOGGLES.
Other Protective Equipment:SAFETY SHOWER/EYE WASH. WORK CLOTHING AS
NEEDED TO PROTECT FROM PROLONGED/REPEATED CONTACT.
Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID
UNNECESSARY CONTACT. MINIMIZE ALL CONTACT.
Supplemental Safety and Health
MSDS NO. 1365 CPS 201153 REVISION 9
================== Physical/Chemical Properties ==================
HCC:F1
Boiling Pt:=25.C, 77.F
B.P. Text:25-225C
Vapor Pres:5-15 PSI
Vapor Density:3.5 (AIR)
Spec Gravity:0.72 - 0.76
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR,COLORLESS TO STRAW YELLOW LIQUID;GASOLINE
ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:HEAT,SPARKS AND OTHER IGNITION
SOURCES,VAPOR ACCUMULATIONS.
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS.
PRODUCT QUALIFYS AS IGNITABLE WASTE AND CANNOT BE LANDFILLED. IF
RECOVERY OR RECYCLE ARE UNACCEPTABLE, INCINERATION MAY BE
ACCEPTABLE DISPOSAL METHOD.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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