===================== Product Identification =====================
MSDS NAME:REGULAR UNLEADED GASOLINE.
NIIN:00-148-7013
MSDS Number: BGWLG
=== Responsible Party ===
Company:DIAMOND SHAMROCK REFINING & MARKETING CO.
Address:9830 COLONNADE BLVD.
Box:696000
City:SAN ANTONIO
State:TX
ZIP:78269-6000
Info Phone Num:512-641-8800
Emergency Phone Num:512-641-8800
CAGE:3P045
=== Contractor Identification ===
Company:DIAMOND SHAMROCK REFINING AND MARKETING CO
Address:9830 COLONNADE BLVD
Box:696000
City:SAN ANTONIO
State:TX
ZIP:78269-6000
Country:US
Phone:210-641-8601
CAGE:3P045
============= Composition/Information on Ingredients =============
Name:GASOLINE
CAS:8006-61-9
RTECS #:LX3300000
Fraction by Wt: TO 100%
OSHA PEL:300 PPM/500 STEL
ACGIH TLV:300 PPM/500STEL;9192
Name:BENZENE (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: 5%
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9192
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:1,2,4-TRIMETHYLBENZENE (SARA III)
CAS:95-63-6
RTECS #:DC3325000
Fraction by Wt: 2%
OSHA PEL:25 PPM
ACGIH TLV:25 PPM; 9192
Name:MESITYLENE
CAS:108-67-8
RTECS #:OX6825000
Fraction by Wt: 1%
Name:METHYL TERT-BUTYL ETHER (SARA III)
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: PROPRIE
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL RAT LD50 18,800 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:PRODUCT IS IRRITATING TO
EYES,SKIN,RESPIRATORY TRACT AND DEPRESSES THE CENTRAL NERVOUS
SYSTEM. CHRONIC OVER EXPOSURE MAY CAUSE LIVER,KIDNEY, OR CENTRAL
NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:CONTAINS BENZENE;LISTED BY ALL THREE.
ALSO,AN API STUDY FOUND LIVER CANCER IN MICE EXPOSED TO GASOLINE
VAPORS.
Effects of Overexposure:EYE/SKIN CONTACT:TRANSITORY IRRITATION.
INHALED:RESPIRATORY IRRITATION,CENTRAL NERVOUS SYSTEM DEPRESSION
INCLUDING,EUPHORIA,HEADACHE,DIZZINESS,DROWINESS,FATIGUE,TREMORS,CON
VULSIONS,NAUSEA,VOMITING,DIA RRHEA,LOSS OF CONSCIOUSNESS.AND
FINALLYDEATH. INGESTED:G/I IRRITATION,PLUS SYMPTOMS SIMILAR TO
THOSE UNDER "INHALED".
Medical Cond Aggravated by Exposure:PRE-ESISTING EYE,SKIN CONDITIONS OR
IMPAIRED LIVER,KIDNEY FUNCTION MAY BE AGGRAVATED BY THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH WITH WATER 15 MIN. SKIN:WASH WITH SOAP &
WATER.REMOVE CONTAMINATED CLOTHING;LAUNDER BEFORE REUSE.
INHALED:REMOVE TO FRESH AIR.RESUSCITATE OR GIVE OXYGEN AS NEEDED.
GET MEDICAL ATTENTION. DO NOT INDUCE VOMITING. IF VOMITING
OCCURS,MINIMIZE ASPIRATION HAZARD.
===================== Fire Fighting Measures =====================
Flash Point:BELOW AMBIENT
Lower Limits:1.3
Upper Limits:7.6
Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,FOAM,WATER FOG. WATER
MAY BE INEFFECTIVE,AS PRODUCT WILL FLOAT AND MAY SPREAD FIRE.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS IN
ENCLOSED AREAS. WATER SPRAY MAY BE USED TO COOL FIRE EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR,ACCUMULATING
IN LOW AREAS,TRAVELS ALONG GROUND AND MAY FLASH BACK FROM DISTIANT
IGNITION SOURCE.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE IGNITION SOURCES, ISOLATE AREA. USE
PROTECTIVE EQUIPMENT AS NECESSARY. STOP LEAK AND CONTAIN SPILL.DIKE
AS NEEDED TO KEEP SPILL FROM DRAINS.WATER WAYS ETC. WATER FOG MAY
BE USED TO REDUCE VA PORS & PERSONAL HAZARD. REPORT SPILL PERLAW.
Neutralizing Agent:NONE
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL,DRY,ISOLATED,WELL
VENTILATED AREA. KEEP IGNITION SOURCES AWAY, GROUND CONTAINERS TO
PREVENT STATIC DISCHARGE DURING TRANSFERS.
Other Precautions:FIRE AND EXPLOSION ARE THE ACUTE HAZARDS OF THIS
PRODUCT. TAKE EXTRAORDINARY STEPS TO PREVENT THEM.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF NEEDED,USE NIOSH/MSHA RESPIRATOR WITH ORGANIC
VAPOR CARTRIDGE OR PREFERRABLY, A POSITIVE PRESSURE AIR SUPPLIED
RESPIRATOR OR SELFCONTAINED BREATHING APPARATUS.
Ventilation:USE EXPLOSION PROOF VENTILATION EQUIPMENT TO MAINTAIN
EXPOSURE BELOW PEL/TLV.
Protective Gloves:IMPERVIOUS OR POLYMER.
Eye Protection:SAFETY GLASSES,OR SPLASH GOGGLES.
Other Protective Equipment:SAFETY SHOWER/EYE WASH, WORK CLOTHING AS
NEEDED TO PROTECT FROM PROLONGED/REPEATED CONTACT.
Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID
UNNECESSARY CONTACT. MINIMIZE ALL CONTAXT.
Supplemental Safety and Health
MSDS NO M4044.
================== Physical/Chemical Properties ==================
HCC:F1
Boiling Pt:=26.7C, 80.F
B.P. Text:80-437F
Vapor Pres:9-15-PSI
Vapor Density:3.5 (AIR)
Spec Gravity:0.72 - 0.76
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR,COLORED LIQUID;GASOLINE ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:HEAT,SPARKS AND OTHER IGNITION
SOURCES,VAPOR ACCUMULATIONS.
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATION.
PRODUCT QUALIFYS AS IGNITABLE WAS AND CANNOT BE LANDFILLED. IF
RECOVERY OR RECYCLE ARE UNACCEPTABLE, INCINERATED MAY BE ACCEPTABLE
DISPOSAL METHOD.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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