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| MATERIAL SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : BUEHLER SILICONE MOLD RELEASE
IDENTIFICATION NUMBER: 20-3046
PRODUCT USE/CLASS : Mold release
SUPPLIER:
Buehler, Ltd.
41 Waukegan Road
Lake Bluff, IL 60044
EMERGENCY: 800-424-9300
INFORMATION: 847-295-6500
PREPARER: Technical Department, PHONE: 847-295-6500
PREPARE DATE: 05/2/06; 22 MAY 06
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER WT/WT%
---------------------------------------------------------------------------
01 Dichloromethane 75-09-2 60.0-100.0
02 1,1,1,2-tetrafluoroethane 811-97-2 10.0-30.0
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
01 50 ppm N.E. 50 ppm 200 ppm 50 ppm NO
02 1000 ppm N.E. 1000 ppm N.E. N.E. NO
(See Section 16 for abbreviation legend)
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| SECTION 3 - HAZARDS IDENTIFICATION |
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EMERGENCY OVERVIEW: Harmful if inhaled or swallowed. High vapor
concentrations may cause drowsiness. Contents under pressure. Respiratory
irritant. May cause skin and eye irritation.
ACUTE EFFECTS - EYE CONTACT: Irritating, but will not permanently injure
eye tissue.
ACUTE EFFECTS - SKIN CONTACT: Contact causes severe skin irritation and
possible burns.
ACUTE EFFECTS - INHALATION: Harmful if inhaled. Liquid aspirated into
lungs may cause serious injury or death. Can cause severe central nervous
system depression, including unconsciousness. High vapor concentrations
are irritating to the eyes, nose, throat and lungs. *Extreme overexposure
to 1,1,1,2-tetrafluoroethane may cause cardiac arrhythmia. Effects are
worsened by activity following overexposure.
ACUTE EFFECTS - INGESTION: Moderately toxic. May cause nausea and
vomiting.
CHRONIC OVEREXPOSURE EFFECTS: *Preexisting pulmonary and dermatological
disorders may be aggravated by exposure to hazardous components. *Studies
suggest that solvent chronic overexposure effects are targeted at the liver
and central nervous system. Deliberate and repeated inhalation of
concentrated solvent vapors may cause permanent neural injury. Consumption
of alcohol in conjunction with repeated solvent exposure may cause color
vision defects. *Component(s) in this material are considered to have
caused cancer in laboratory animal studies. (Methylene chloride)
Continued on Page 2)
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9100895
Product: 20-3046
Preparation Date: 05/22/06 Page 2
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| SECTION 3 - HAZARDS IDENTIFICATION |
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OTHER INFORMATION: Not Applicable.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT, SKIN ABSORPTION, INHALATION, EYE
CONTACT,
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| SECTION 4 - FIRST AID MEASURES |
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EYE CONTACT: Immediately flush eyes with plenty of water. Get medical
attention.
SKIN CONTACT: Wash with soap and water. Get medical attention if
irritation persists.
INHALATION: Remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical
attention.
INGESTION: If swallowed, do NOT induce vomiting. Give victim a glass of
water or milk. Call a physician or poison control center immediately.
Never give anything by mouth to an unconscious person.
NOTES TO PHYSICIAN: In case of poisoning, do not give epinephrin. Treat
ventricular arrhymias with beta-blocking agents. Keep patient calm.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: N.A. LOWER EXPLOSIVE LIMIT: N.A.
UPPER EXPLOSIVE LIMIT: N.A.
AUTOIGNITION TEMPERATURE: No data
EXTINGUISHING MEDIA:CO2,DRY CHEMICAL,FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may rupture or
explode (due to pressure build-up) when exposed to extreme heat. "Empty"
containers may retain dangerous product residues or explosive vapors. DO
NOT pressurize, cut, weld, braze, solder, drill or grind on or near empty
containers. Store full and empty containers away from heat, sparks, flame,
and other sources of ignition. Observe all labeled precautions.
Irritating and/or toxic gases or fumes may be generated by thermal
decomposition or combustion.
SPECIAL FIREFIGHTING PROCEDURES: Use NIOSH-approved self-contained
breathing apparatus and full protective clothing. Use water to cool
exposed containers. Water stream directed into fire may cause frothing
with subsequent spread of flame.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Wipe up excess
material. Dispose of damaged aerosol container in accordance with state
and local regulations regarding "empty" chemical containers.
Continued on Page 3)
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9100895
Product: 20-3046
Preparation Date: 05/22/06 Page 3
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: Use with adequate ventilation. Follow all MSDS/label
precautions even after container is emptied because it may retain product
residues. Avoid contact with skin and eyes. FOR INDUSTRIAL USE ONLY.
STORAGE: Keep away from heat, sparks and flame. Do not store in direct
sunlight. KEEP OUT OF THE REACH OF CHILDREN.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: Local exhaust as needed to control vapor or dust
levels to below lowest component TLV.
RESPIRATORY PROTECTION: If TLV/PEL is exceeded, if use is performed in a
poorly-ventilated space, or if inhalation effects occur, use NIOSH-approved
vapor cartridge respirator in accordance with applicable health and safety
regulations and manufacturer's recommendations.
SKIN PROTECTION: Clean clothing to cover skin. Neoprene gloves.
EYE PROTECTION: Safety goggles.
OTHER PROTECTIVE EQUIPMENT: Accessible eye wash and safety shower.
HYGIENIC PRACTICES: Follow good general industrial safety practices during
use. Do not smoke or eat during use. Follow all MSDS/label precautions
even after container is emptied.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : 103 - 104 F VAPOR DENSITY : Is heavier than air
ODOR : Strong solvent ODOR THRESHOLD : Appr 10 ppm
APPEARANCE : Clear EVAPORATION RATE: Is faster than Butyl
SOLUBILITY IN H2O : Insoluble Acetate
FREEZE POINT : No data SPECIFIC GRAVITY: 1.1679
VAPOR PRESSURE : 30 psig @ 70 F pH @ 0.0 % : N/A
PHYSICAL STATE : Gas VISCOSITY : N/A
COEFFICIENT OF WATER/OIL DISTRIBUTION: No data
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Prolonged exposure to heat.
INCOMPATIBILITY: Strong Lewis or mineral acids.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon. Chloride compounds.
Phosgene.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
Continued on Page 4)
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9100895
Product: 20-3046
Preparation Date: 05/22/06 Page 4
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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COMPONENT TOXICOLOGICAL INFORMATION:
----------- CHEMICAL NAME ----------- ------ LD50 ------ ------ LC50 ------
Dichloromethane Oral/rat-1600mg/kg rat-30m 88000mg/m3
1,1,1,2-tetrafluoroethane No information Inh-rat=1500g/m3/4
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL TEST DATA: Not Available
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD: Review all current federal, state, and local regulations
regarding health and disposal for appropriate disposal procedures.
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| TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: Aerosols, non-flammable
DOT TECHNICAL NAME: N/A
DOT HAZARD CLASS: 2.2 HAZARD SUBCLASS: N/A
DOT UN/NA NUMBER: UN1950 PACKING GROUP: N/A RESP. GUIDE PAGE: 126
INTERNATIONAL SHIPPING NAME: ICAO/IATA: Aerosols, non-flammable,
containing substances in Divion 6.1, Packing
Group III
IMO/IMDG : Aerosols
INTERNATIONAL ID NUMBER: UN1950
IMDG CLASS (1酶,2酶): 2, none PACKING GROUP: N/A
IMDG EMS: 213 IATA CLASS (1酶,2酶): 2.2, 6.1
ADR ITEM NO.: N/A ADR TREMCARD: N/A
SUPPLEMENTAL INFORMATION: Not Applicable.
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| SECTION 15 - REGULATORY INFORMATION |
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OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed, and is considered, under applicable
definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD PRESSURE HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 and 40 CFR part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
Dichloromethane 75-09-2 60.0-100.0
Continued on Page 5)
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9100895
Product: 20-3046
Preparation Date: 05/22/06 Page 5
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| SECTION 15 - REGULATORY INFORMATION |
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TOXIC SUBSTANCES CONTROL ACT:
The chemical substances in this product are on the TSCA Section 8
Inventory.
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
---------- CHEMICAL NAME ----------- CAS NUMBER
Dichloromethane 75-09-2
U.S. STATE REGULATIONS: AS FOLLOWS -
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
Polydimethylsiloxane 63148-62-9
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
Polydimethylsiloxane 63148-62-9
CALIFORNIA PROPOSITION 65:
This product contains a chemical known to the State of California to cause cancer
(Dichloromethane).
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: A, D2A
COMPONENT RCRA CLASSIFICATIONS: TOXIC
COMPONENT RCRA CODES: D003
CERCLA RQ VALUE (MINIMUM): 100
VOLATILE ORGANIC COMPOUNDS (VOCS): 0 grams/ltr
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 3* FLAMMABILITY: 0 REACTIVITY: 0
PREVIOUS MSDS REVISION DATE: 01/21/97
REASON FOR REVISION: new format
ADMINISTRATIVE REVISION: 05/20/03
REASON FOR ADMINISTRATIVE REVISION: Updates to Sections1, 16
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
ABBREVIATIONS: ACGIH = American Conference of Governmental Industrial
Hygienists; OSHA = US Occupational Safety and Health Administration; UK =
United Kingdom; TLV-TWA = Threshold Limit Value-Time Weighted Average (8
hrs); STEL = Short-Term Exposure Limit (15 min); C = Ceiling Value; PEL =
Permissible Exposure Limit
Continued on Page 6)
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9100895
Product: 20-3046
Preparation Date: 05/22/06 Page 6
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DISCLAIMER: To the best of our knowledge, the information contained in
this MSDS is accurate or is obtained from sources believed to be accurate.
However, no liability, expressed or implied, is assumed for the accuracy or
completeness of the information contained herein. Buyer assumes liability
in its use of the material.
Consult www.buehler.com periodically to assure latest revision.
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9100895
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