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Procter & Gamble
CPG TN 6
2 Procter & Gamble Plaza
Cincinnati, OH 45202
MATERIAL SAFETY DATA SHEET
Issue Date: 8/01
Supersedes: N/A Issue Date: N/A
SECTION I - CHEMICAL PRODUCT
Identity: Granular Cleaner with Bleach
Brands: SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate)
Hazard Rating: 1 Health: 1 4=EXTREME
Flammability: 0 3=HIGH
Reactivity: 0 2= MODERATE
1=SLIGHT
Emergency Telephone Number: - 1-800-332-7787 or call Local Poison Control Center
SECTION II - COMPOSITION AND INGREDIENTS
Ingredients/Chemical Name: Anionic surfactants, water softeners (sodium carbonate, complex sodium phosphates
[phosphate version]), dry chlorine bleach, processing aids (sodium sulfate), metal
protection agents (sodium silicates).
This product is a mild eye irritant within the meaning of the OSHA Hazard Communication Standard
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200.
Common CAS No. Recommended Limits Composition LD50/LC50
Chemical Name
Name Range
Sodium carbonate Soda Ash 497-19-8 N/A 15-40% (OP) LD50=1.86
10-25% (P) g/kg
LC50=N/A
Sodium 2893-78-9 AGCY OSHA 10-15% LD50=735
Sodium
DCC TLV PEL mg/kg rat
dichloroisocynanurate
10 mg/m3 15 mg/m3
dihydrate
C12.3 LAS 68081-81-2 15-30% LD50=0.65-
Linear alkyl benzene
1.26 g/kg
sulfonate N/A
LC50=N/A
SECTION III - HAZARDS IDENTIFICATION
Health Hazards & Symptoms (Acute and Chronic):
Ingestion: May cause transient gastrointestinal irritation with nausea, vomiting and/or diarrhea.
Eye Contact: May cause mild, transient irritation with stinging, tearing, itching,swelling and redness.
Inhalation: Heavy or prolonged exposure to dust may cause transient respiratory tract irritation with
coughing, sore throat, wheezing or transitiory shortness of breath.
SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate) MSDS (Continued)
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SECTION IV - FIRST AID INFORMATION
Emergency and First Aid Procedures:
Ingestion: Drink 1 or 2 large glasses of water. If large amounts are ingested, call a physician.
Eye Contact: Flush with large amounts of water for at 10-15 minutes.
Skin: Rinse skin thoroughly with water. Discontinue use.
Inhalation: Leave dusty area.
Other: Product package has a caution statement: CAUTION:. May cause eye/skin irritation. Eye irritant. Avoid eye
contact. Do not mix with other cleaning products as irritating fumes may be released. May be irritating to skin.
For sensitive skin or prolonged use, wear gloves. If eye or skin contact occurs, flush with water for 15 minutes.
If irritation persists, seek medical attention. KEEP OUT OF REACH OF CHILDREN
SECTION V - FIRE FIGHTING INFORMATION
Flash Point (Method Used): N/A Explosive Limits: LEL: N/A UEL: N/A
Extinguishing Media: CO2 , water, or dry chemical
Special Fire Fighting Procedures: None known.
Unusual Fire Hazards : N/A
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: None
Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE
AND LOCAL REGULATIONS. Solutions may be disposed of in sewer. Dry product may be landfilled if permitted by
local regulations. Discard empty container in trash.
Steps To Be Taken in Case Material is Released or Spilled: Dispose as dry scrap or flush small quantities down
acceptable sewer (contains biodegradable surfactants). Dispose of according to local regulations. Prevent heavy
exposure to dust with NIOSH approved dust mask.
SECTION VII - HANDLING AND STORAGE
Precautions To Be Taken in Handling and Storing: Store in a cool, dry place. Keep product dry to maintain free-
flowing granules.
Other Precautions: None
SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION
Respiratory Protection (Specify Type): None required with normal use.
Ventilation Local Exhaust: None required with normal use. Special: None
Mechanical (General): Acceptable. Other: None
Eye Protection: None required with normal use.
Manufacturing Setting: With dusty conditions or if a splash is likely, chemical goggles may be needed.
Protective Gloves: None required with normal use.
Manufacturing Setting: Protective gloves (rubber, neoprene) should be used for any prolonged direct contact.
Other Protective Equipment: None required with normal use.
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SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate) MSDS (Continued)
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SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point 掳 F: N/A Specific Gravity (H2 O=1): N/A
Vapor Pressure (mm Hg): N/A Percent Volatile by Volume (%): N/A
Vapor Density (Air=1): N/A Evaporation Rate (nBuOAc=1): N/A
Odor Threshold: N/A Freezing Point: N/A
Coefficient of Water/Oil Distribution: N/A pH (1% solution): ~10.9
Scooped Density: 0.4/cc (bulk density) Solubility in Water: Mostly
Appearance and Odor: White granule with green specks Reserve Alkalinity: 4.0 max
and bland odor
SECTION X - STABILITY AND REACTIVITY
Possible Hazardous Reactions/Conditions: None known
Conditions to Avoid: None
Materials to Avoid: Products which contain ammonia or are acidic
Hazardous Decomposition Products: Chlorine gas
Other Recommendations: None
Stability: Stable
Hazardous Polymerization: Will not occur
SECTION XI - TOXICOLOGICAL INFORMATION
LD50 (rats oral): 2.9g/kg
SECTION XII - ECOLOGICAL INFORMATION
None
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS. Small quantities may be disposed of in sewer. Dry product may be landfilled. Discard empty
container in trash.
SECTION XIV - TRANSPORT INFORMATION
DOT Classification: The finished product is not DOT hazardous.
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SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate) MSDS (Continued)
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SECTION XV - ADDITIONAL REGULATORY INFORMATION
All components are listed on the US TSCA Inventory. No components are affected by Significant New Use Rules
(SNURs) under TSCA 搂5.
No components of Spic and Span with Bleach are subject to California Proposition 65.
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified with
Hazard Criteria of the Canadian Control Products Regulation (CPR) and this MSDS contains all information required
by the Canadian Products Regulation.
SECTION XVI - OTHER INFORMATION
*N/A. - Not Applicable *N/K. - Not Known
The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous
when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use
only in connection with occupational safety and health.
The information contained herein has been compiled from sources considered by Procter & Gamble to be
dependable and is accurate to the best of the Company鈥檚 knowledge. The information relates to the specific material
designated herein, and does not relate to the use in combination with any other material or any other process.
Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to any
property resulting from misuse of the controlled product.
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