Conforms to 2001/58/EC and ISO 11014-1
SAFETY DATA SHEET
URANUS
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
: URANUS
Product name
Chemical name of active : Trifluralin (ISO):
伪,伪,伪-trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine.
ingredient(s)
Linuron (ISO) : 3-(3,4-Dichlorophenyl)-1-methoxy-1-methylurea.
: Agan Chemical Manufacturers Ltd.
Manufacturer
Northern Industrial Zone,
P.O.Box 262, Ashdod, Israel.
: Makhteshim-Agan (UK) Ltd.
Supplier
Unit 16, Thatcham Business Village
Colthrop Way, Thatcham
Berkshire RG19 4LW, U.K.
: National Chemical Emergency Centre, Tel : 0870 1906621.
Emergency telephone
number
2. COMPOSITION/INFORMATION ON INGREDIENTS
: Preparation
Substance/preparation
Information on hazardous ingredients *
Common name CAS No. % EC Number Symbol R-Phrases
Trifluralin (ISO) 1582-09-8 22 - 24 216-428-8 Xi,N R36-43-50/53
Linuron (ISO) 330-55-2 11 - 12 206-356-5 Xn,N R22-40-48/22-50/-
53
Isophorone 78-59-1 16 - 18 201-126-0 Xn R21/22-36/37-40
Xylene 1330-20-7 35 - 38 215-535-7 Xn R10-20/21-38
* Occupational Exposure Limit(s), if available, are listed in section 8
3. HAZARDS IDENTIFICATION
: Flammable. Irritating to eyes. Limited evidence of a carcinogenic effect.
Most important hazards
May cause sensitization by skin contact. Harmful: danger of serious
damage to health by prolonged exposure if swallowed. Very toxic to
aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
4. FIRST-AID MEASURES
Effects and symptoms
: Vapours - headache, dizziness, collapse.
Inhalation
: nausea, headache, cramps, vomiting.
Ingestion
: May cause sensitization by skin contact.
Skin contact
: Irritating to eyes.
Eye contact
: Remove victim from area of exposure. Wash off remaining material with
First-aid measures
plenty of water.
: Remove victim to fresh air. If breathing is difficult: artificial respiration.
Inhalation
Get medical attention.
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Conforms to 2001/58/EC and ISO 11014-1
SAFETY DATA SHEET
URANUS
: Wash out mouth with plenty of water. Get medical attention. Never give
Ingestion
anything by mouth to an unconscious person.
: Remove contaminated clothing.Wash away remainder with water and
Skin contact
soap.
: Wash out with plenty of water with the eyelid held wide open for at least
Eye contact
15 minutes. Get medical attention.
: There is no specific antidote. Treat symptomatically and give supportive
Notes to a physician
therapy.
: Use appropriate protection (see section 8).
Protection of first-aiders
5. FIRE-FIGHTING MEASURES
Extinguishing media
: Dry chemical, water spray, foam, carbon dioxide.
Suitable
: Flashback may occur along vapour trail.
Unusual fire/explosion
hazards
: Chloride compounds, Fluoride compounds and nitrogen oxides.
Hazardous thermal
(de)composition products
: Self-contained breathing apparatus and total protection required in
Protection of fire-fighters
enclosed areas.
6. ACCIDENTAL RELEASE MEASURES
: Wear suitable protective clothing.
Personal precautions
: Do not discharge into drains or the environment.
Environmental precautions
: Keep away from: open flame, sparks and heat. Absorb remainder in
Methods for cleaning up
sand or other inert material. Dispose of in an authorized waste collecting
point.
7. HANDLING AND STORAGE
: Avoid contact with skin and eyes. Ventilation required. Keep away from:
Handling
sparks, open flame and direct sunlight.
: Keep only in the original container. Keep in a cool, dry, well ventilated
Storage
place away from direct sunlight.
Packaging materials
: Plastic containers.
Suitable
Resin-lined metal drums.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
: Ventilation required.
Engineering measures
: When handling do not eat, drink or smoke. Wash hands thoroughly after
Hygiene measures
handling. Wash clothing separately before re-use.
Occupational Exposure
Limits
Common name : Trifluralin (ISO)
: Not established
Common name : Linuron (ISO)
: Not established
Common name : Isophorone
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Conforms to 2001/58/EC and ISO 11014-1
SAFETY DATA SHEET
URANUS
: 2 ppm or 11 mg/m3
TLV (USA)
: 2 ppm
"MAK" (Germany)
Common name : Xylene
: 100 ppm
TLV (USA)
: 100 ppm
"MAK" (Germany)
: 100 ppm
OEL (United Kingdom)
Personal protective
equipment
: Respiratory protection is not required if good ventilation is maintained.
Respiratory system
: Wear suitable protective clothing. Chemical resistant boots.
Skin and body
: Chemical resistant gloves.
Hands
: Safety goggles or face shield.
Eyes
9. PHYSICAL AND CHEMICAL PROPERTIES
: Liquid
Physical state
: Reddish
Colour
: Characteristic odour
Odour
: 137-143oC (Xylene)
Boiling point
: 1.04 卤 0.015 g/mL @ 20oC
Density
: 13.7 mPa @ 25oC (Trifluralin (ISO))
Vapour pressure
0.04 mPa @ 25oC (Linuron (ISO))
: 0.2 ppm @ 25oC (Trifluralin (ISO))
Solubility in water
58.8 mg/L @ 20oC (Linuron (ISO))
: log = 5.14 (Trifluralin (ISO))
Octanol/water partition
log = 3.07 (Linuron (ISO))
coefficient
:5-7
pH
: 37oC
Flash point
: Flammable
Flammability
: 450oC (Xylene)
Autoignition temperature
: Xylene (vapours) - May form explosive mixture with air.
Explosion properties
: 1 volume %
Lower explosion limit
: 7 volume %
Upper explosion limit
10. STABILITY AND REACTIVITY
: Not subject to polymerization.
Stability
: Oxidizing agents, acids and alkali.
Materials to avoid
: Flashback may occur along vapour trail.
Hazardous reactions
: Chloride compounds, Fluoride compounds and nitrogen oxides.
Hazardous decomposition
products
11. TOXICOLOGICAL INFORMATION
Preparation
: LD50 (rat) > 2,000 mg/kg
Acute toxicity - Oral
: LD50 (rat) > 2,000 mg/kg
Acute toxicity - Dermal
: LC50 > 5.13 mg/L
Acute toxicity - Inhalation
: Not irritating (rabbit)
Skin irritation
: Moderately irritating (rabbit)
Eye irritation
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Conforms to 2001/58/EC and ISO 11014-1
SAFETY DATA SHEET
URANUS
: Extreme sensitizer (guinea-pig)
Sensitization
Common name : Trifluralin (ISO)
: NOEL (rat) = 2.5 mg/kg/day (2 years).
Chronic toxicity
NOEL (mice) = 73 mg/kg/day (2 years).
: EPA : Group C
Carcinogenicity
EU : Not classified
IARC : Group 3
: Not mutagenic
Mutagenicity
: NOEL (rat) = 50 ppm (2 generation).
Reproduction toxicity
: Teratogenicity - NOAEL (rabbit): 20 mg/kg/day (Maternal) ; 50
Other information
mg/kg/day (Fetal).
Common name : Linuron (ISO)
: NOAEL (rat) = 25 ppm or 1.3 mg/kg/day (2 years)
Chronic toxicity
NOAEL (mouse) = 50 ppm or 6.5 mg/kg/day (2 years)
: EPA : Group C
Carcinogenicity
EU : Category 3
IARC : Not classified
: Not mutagenic
Mutagenicity
: NOAEL (rat) = 125 ppm (3 generation)
Reproduction toxicity
: Teratogenicity - NOAEL (rat) = 20 mg/kg/day (Maternal and Fetal)
Other information
NOAEL (rabbit) = 10 mg/kg/day (Maternal) ; 25 mg/kg/day (Fetal)
12. ECOLOGICAL INFORMATION
Preparation
Ecotoxicity : Fish
LC50 (96 hours) Trout = 0.24 mg/L
Daphnia magna
EC50 (48 hours) = 0.85 mg/L
Algae (scenedesmus subspicatus)
EC50 (72 hours) = 0.29 mg/L
Birds
Bobwhite quail (colinus virginianus) LD50 = 1,230 mg/kg
Mallard duck (anas platyrhynchos) LD50 > 1,650 mg/kg
Toxic to fish. Low toxicity: birds.
Common name : Trifluralin (ISO)
Mobility : Soil
Not mobile.
Adsorbed on soils with high organic content.
Koc = 6,414 - 13,414 mL/g
Persistence/degradability : Soil
Moderately persistent.
Half-life time (t陆): ~ 45 days.
Degradation is primarily via: microorganisms.
Water
The product is not biodegradable.
Dissipates rapidly in aquatic systems with DT50 4.9-5.8 days.
Low risk of underground water contamination.
: Low bioaccumulation potential.
Bioaccumulative potential
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Conforms to 2001/58/EC and ISO 11014-1
SAFETY DATA SHEET
URANUS
Ecotoxicity : Fish
LC50 (96 hours) rainbow trout (oncorhynchus mykiss) = 0.088 mg/L
bluegill sunfish (lepomis macrochirus) = 0.089 mg/L
NOEC (35 days) fat head minnow = 0.3 碌g/L
Daphnia magna
EC50 (48 hours) = 0.245 mg/L
NOEC (21 days) = 0.051 mg/L
Algae (selenastrum capricornutun)
EC50 (72 hours) = 12.2 mg/L
Birds
Mallard duck (anas platyrhynchos) LD50 > 2,000 mg/kg
Bobwhite quail (colinus virginianus) LD50 > 2,250 mg/kg
Mallard duck (anas platyrhynchos) and Bobwhite quail (colinus
virginianus) LC50 > 5,000 ppm (5 day feeding)
Bees
Oral and Contact LD50 (48 hours) > 100 碌g/bee
Toxic to aquatic organisms Low toxicity: birds and bees.
Common name : Linuron (ISO)
Mobility : Soil
Not mobile.
Adsorbed on organic matter and clay.
Kd = 2.2 - 18 mL/g
Koc = 362 - 877 mL/g
Water
Low risk of underground water contamination.
Persistence/degradability : Soil
Lab. - Half-life time (t陆): 38-135 days (15-25o)
Field - DT50: 13-82 days.
Degradation is primarily via: microorganisms.
Water
DT50: 48 days.
: BCF : 38-49.
Bioaccumulative potential
Ecotoxicity : Fish
LC50 (96 hours) rainbow trout (oncorhynchus mykiss) = 3.15 mg/L
NOEC (21 days) rainbow trout (oncorhynchus mykiss) = 0.1 mg/L
Daphnia magna
EC50 (24 hours) = 0.31 mg/L
NOEC (21 days) = 0.18 mg/L
Algae (scenedesmus subspicatus)
EC50 (72 hours) = 0.016 mg/L
Birds
Bobwhite quail (colinus virginianus) LD50 = 314 mg/kg
Bobwhite quail (colinus virginianus) LC50 = 1,250 ppm (8-day feeding)
Bees
LD50 > 160 碌g/bee
Oral
Contact LD50 > 1,600 碌g/bee
Very toxic to aquatic organisms. Low toxicity: birds. Non toxic: bees.
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Conforms to 2001/58/EC and ISO 11014-1
SAFETY DATA SHEET
URANUS
13. DISPOSAL CONSIDERATIONS
: Dispose of in a pesticide approved landfill, or in a chemical incinerator
Methods of disposal
equipped with scrubbers, In accordance with national and regional
regulations.
14. TRANSPORT INFORMATION
International transport regulations
: 1993
UN number
Land - Road/Railway
: Flammable Liquid, N.O.S., Xylene
Proper shipping name
: 3, F1, PG III
ADR/RID Class
: 30
Hazard Identification
Number
Inland waterways
: Flammable Liquid, N.O.S., Xylene
Proper shipping name
: 3, F1, PG III
ADNR Class
Sea
: Flammable Liquid, N.O.S., Xylene
Proper shipping name
: 3, Label 3
IMDG Class
: III
Packing group
: F-E, S-E
Emergency Schedules
(EmS)
Air
: Flammable Liquid, N.O.S., Xylene
Proper shipping name
: 1993
UN/ID Number
:3
IATA-DGR Class
National transport regulations
No additional national transport regulations are known to the supplier
15. REGULATORY INFORMATION
: This product is provisionally labelled by the supplier in accordance with the
Classification
suppliers understanding of the EU regulations (Directives 67/548/EEC,
1999/45/EC).
: Xn, N
Hazard symbol(s)
HARMFUL DANGEROUS FOR THE
ENVIRONMENT
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Conforms to 2001/58/EC and ISO 11014-1
SAFETY DATA SHEET
URANUS
: R10: Flammable.
Risk phrases
R36: Irritating to eyes.
R40: Limited evidence of a carcinogenic effect.
R43: May cause sensitization by skin contact.
R48/22: Harmful: danger of serious damage to health by prolonged
exposure if swallowed.
R50/53: Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
: S02: Keep out of the reach of children.
Safety phrases
S13: Keep away from food, drink and animal feedingstuffs.
S20/21: When using do not eat, drink or smoke.
S26: In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face
protection.
S46: If swallowed, seek medical advice immediately and show this
container or label.
S60: This material and its container must be disposed of as hazardous
waste.
S61: Avoid release to the environment. Refer to special instructions/Safety
data sheets.
16. OTHER INFORMATION
The information contained in the Safety Data sheet is correct to the best of our knowledge at the date of
issue. It is intended as a guide for the safe use, handling, disposal, storage and transportation and is not
intended as a warranty or as a specification. The information relates only to the product specified and may
not be suitable for combinations with other materials or in processes other than those specifically described
herein.
HISTORY
: 12/01/2004
Date of printing
: 12/01/2004
Date previous issue
: 12/01/2004
Date of issue
: 001
Version
The version-number is made up of three parts; part 1 is a general information code, part 2 a
country-specific code and part 3 a language-specific code
Date of issue: 12/01/2004 Version: 001.00.00 Page 7 of 7
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