MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 2000, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: 3M SPECIALTY MATERIALS
TRADE NAME:
FX-8A FLUORAD (TM) BRAND PERFLUOROOCTANE SULFONYL FLUORIDE
ID NUMBER/U.P.C.:
ZF-0002-1129-0 - - -
ISSUED: January 04, 2000
SUPERSEDES: February 22, 1999
DOCUMENT: 07-2643-0
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1. INGREDIENT C.A.S. NO. PERCENT
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C8F17SO2F (PERFLUOROOCTANE
SULFONYLFLUORIDE)..................... 307-35-7 > 95.5
PERFLUOROALKYL(C4-C7)SULFONYLFLUORIDES
+++................................... 335-71-7 < 4.5
The components of this product are in compliance with the chemical
notification requirements of TSCA. All applicable chemical
ingredients in this material are listed on the European Inventory of
Existing Chemical Substances (EINECS), or are exempt polymers whose
monomers are listed on EINECS.
+++ CONTAINS SMALL AMOUNTS OF CAS 375-72-4 + CAS 375-81-5 + CAS
423-50-7.
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2. PHYSICAL DATA
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BOILING POINT:................. 154 C
VAPOR PRESSURE:................ < 10 mmHg
Calc. at 20C
VAPOR DENSITY:................. > 1.0 Air=1
Calc. @ 20C
EVAPORATION RATE:.............. < 1.0 BuOAc=1
SOLUBILITY IN WATER:........... neglig.
SPECIFIC GRAVITY:.............. ca. 1.8 Water=1
PERCENT VOLATILE:.............. nil
pH:............................ N/A
VISCOSITY:..................... N/D
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: FX-8A FLUORAD (TM) BRAND PERFLUOROOCTANE SULFONYL FLUORIDE
January 04, 2000 PAGE 2
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2. PHYSICAL DATA (continued)
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MELTING POINT:................. N/A
APPEARANCE AND ODOR:
Clear liquid.
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... > 100 C Setaflash
FLAMMABLE LIMITS - LEL:........ N/A
FLAMMABLE LIMITS - UEL:........ N/A
AUTOIGNITION TEMPERATURE:...... N/A
EXTINGUISHING MEDIA:
Water, Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
See Hazardous Decomposition section for products of combustion.
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4. REACTIVITY DATA
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STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Strong Bases, Amines.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Oxides of Sulfur, Hydrogen
Fluoride, Toxic Vapors, Gases or Particulates.
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Observe precautions from other sections. Ventilate area. Contain
spill. Cover with absorbent material. Collect spilled material.
Clean up residue with an appropriate organic solvent. Read and follow
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: FX-8A FLUORAD (TM) BRAND PERFLUOROOCTANE SULFONYL FLUORIDE
January 04, 2000 PAGE 3
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5. ENVIRONMENTAL INFORMATION (continued)
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safety precautions on the solvent label and MSDS. Place in a closed
container.
RECOMMENDED DISPOSAL:
Incinerate in an industrial or commercial facility in the presence of
a combustible material. Combustion products will include HF.
Disposal alternative: Dispose of completely absorbed waste product
in a facility permitted to accept chemical wastes.
ENVIRONMENTAL DATA:
COD=500-720 mg/kg; BOD20=Nil; 96-Hr. LC50 Fathead minnow (Pimephales
promelas) - >1000 mg/L. No acute inhibition of microbial oxygen
uptake at 1000 mg/L.
REGULATORY INFORMATION:
Volatile Organic Compounds: N/A.
VOC Less H2O & Exempt Solvents: N/A.
Since regulations vary, consult applicable regulations or authorities
before disposal. U.S. EPA Hazardous Waste Number = None (Not U.S.
EPA Hazardous).
OTHER ENVIRONMENTAL INFORMATION:
This product contains one or more organic fluorochemicals that have
the potential to resist degradation and persist in the environment.
EPCRA HAZARD CLASS:
FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: No CHRONIC: No
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
INHALATION:
If signs/symptoms occur, remove person to fresh air. If
signs/symptoms continue, call a physician.
IF SWALLOWED:
Drink two glasses of water. Call a physician.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: FX-8A FLUORAD (TM) BRAND PERFLUOROOCTANE SULFONYL FLUORIDE
January 04, 2000 PAGE 4
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact with vapor, spray, or mist. Wear vented goggles.
SKIN PROTECTION:
Avoid skin contact. Wear appropriate gloves when handling this
material. A pair of gloves made from the following material(s) are
recommended: butyl rubber. Use one or more of the following
personal protection items as necessary to prevent skin contact:
coveralls.
RECOMMENDED VENTILATION:
If exhaust ventilation is not adequate, use appropriate respiratory
protection. Provide ventilation adequate to control vapor
concentrations below recommended exposure limits and/or control spray
or mist.
RESPIRATORY PROTECTION:
Avoid breathing of airborne material. Select one of the following
NIOSH approved respirators based on airborne concentration of
contaminants and in accordance with OSHA regulations: Half-mask
organic vapor respirator with dust/mist prefilter.
PREVENTION OF ACCIDENTAL INGESTION:
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water. Wash hands after handling and
before eating.
RECOMMENDED STORAGE:
Store away from areas where product may come into contact with food
or pharmaceuticals. Do not store containers on their sides. Store
away from heat. Allow material to return to room temperature before
use. Keep container closed when not in use. Keep container in well-
ventilated area.
FIRE AND EXPLOSION AVOIDANCE:
Nonflammable.
OTHER PRECAUTIONARY INFORMATION:
No smoking: Smoking while using this product can result in
contamination of the tobacco and/or smoke and lead to the formation
of the hazardous decomposition products mentioned in the Reactivity
Data section of this MSDS.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: FX-8A FLUORAD (TM) BRAND PERFLUOROOCTANE SULFONYL FLUORIDE
January 04, 2000 PAGE 5
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7. PRECAUTIONARY INFORMATION (continued)
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EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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C8F17SO2F (PERFLUOROOCTANE
SULFONYLFLUORIDE).................. 0.1 MG/M3 TWA 3M Y
PERFLUOROALKYL(C4-
C7)SULFONYLFLUORIDES +++........... 0.1 MG/M3 TWA 3M Y
* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- 3M: 3M Recommended Exposure Guidelines
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Mild Eye Irritation: signs/symptoms can include redness, swelling,
pain, and tearing.
SKIN CONTACT:
Product is not expected to be irritating to the skin.
May be absorbed through the skin and produce effects similiar to
those caused by inhalation and/or ingestion.
INHALATION:
Single overexposure, above recommended guidelines, may cause:
Irritation (upper respiratory): signs/symptoms can include
soreness of the nose and throat, coughing and sneezing.
IF SWALLOWED:
Animal studies conducted on organic fluorochemicals which are present
in this product indicate effects including liver disturbances, weight
loss, loss of appetite, lethargy, and neurological, pancreatic,
adrenal and hematologic effects. There are no known human health
effects from anticipated exposure to these organic fluorochemicals
when used as intended and instructed.
OTHER HEALTH HAZARD INFORMATION:
This product contains one or more organic fluorochemicals that have
the potential to be absorbed and remain in the body for long periods
of time, either as the parent molecule or as metabolites, and may
accumulate with repeated exposures. There are no known human health
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: FX-8A FLUORAD (TM) BRAND PERFLUOROOCTANE SULFONYL FLUORIDE
January 04, 2000 PAGE 6
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8. HEALTH HAZARD DATA (continued)
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effects from anticipated exposure to these organic fluorochemicals
when used as intended and instructed.
The presence of organic fluorochemicals in the blood of the general
population and subpopulations, such as workers, has been published
dating back to the 1970's. 3M's epidemiological study of its own
workers indicates no adverse effects.
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SECTION CHANGE DATES
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INGREDIENTS SECTION CHANGED SINCE February 22, 1999 ISSUE
ENVIRONMENTAL INFO. SECTION CHANGED SINCE February 22, 1999 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
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