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MSDS Material Safety Data Sheet
CAS

108-80-5

File Name: horizonpoolsupply_com---MSDS_Cyanuric_Acid.asp
                                                Univar USA Inc.
6100 Carillon Point
Kirkland, WA 98033
(425) 889-3400




For Emergency Assistance involving chemicals call - CHEMTREC (800) 424-9300
===========================================================================


The Version Date for this MSDS is : 09/27/2004

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PRODUCT IDENTIFICATION
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PRODUCT NAME: ISOCYANURIC ACID, CYANURIC ACID

MSDS#: P21534VS

DATE ISSUED: 09/16/2003

SUPERSEDES: 07/28/1997

ISSUED BY: 006768

MATERIAL SAFETY DATA SHEET

Material Name: Isocanuric Acid Canuric Acid ID: CI-205

* * * Section 1 - Chemical Product and Company Identification

Chemical Name: Isocyanuric Acid, Technical Granular and Powder
Product Use: For Commercial Use
Synonyms: Cyanuric acid; Tricarbimide; Triacyanic acid

Supplier Information
Chem One Ltd. (Importer of record) Phone: (713) 896-9966
8017 Pinemont Drive, Suite 100 Fax: (713) 896-7540
Houston, Texas 77040-6519 Emergency # (800) 424-9300 or (703) 527-3887

General Comments: FOR COMMERCIAL USE ONLY; NOT TO BE USED AS A PESTICIDE.

NOTE: Emergency telephone numbers are to be used only in the event of
chemical emergencies involving a spill, leak, fire, exposure, or accident
involving chemicals. All non-emergency questions should be directed to
customer service.

* * * Section 2 - Composition / Information on Ingredients

CAS # Component Percent
108-80-5 Isocyanuric Acid > 98

Component Information/Information on Non-Hazardous Components
This product is considered hazardous under 29 CFR 1910.1200 (Hazard
Communication).

* * * Section 3 - Hazards Identification

Emergency Overview
Isocyanuric Acid is a white granular powder. Exposure to dusts may irritate
eyes, skin, and respiratory tract. As a finely-divided organic compound, the
accumulation of dusts of this product can create a serious hazard of air/dust
explosion. When heated to decomposition, this product may emit very toxic
fumes of carbon monoxide, carbon dioxide and nitrogen oxides. Use
extinguishing media suitable for surrounding fire.

Hazard Statements
CAUTION! MAY BE HARMFUL IF INHALED OR INGESTED. MAY CAUSE EYE, SKIN AND
RESPIRATORY IRRITATION. Avoid breathing dusts or fumes. Avoid contact with
eyes, skin and clothing. Keep container closed. Use only with adequate
ventilation. Do not take internally. Wash thoroughly after handling.

Potential Health Effects: Eyes
Exposure to particulates of this Isocyanuric Acid may cause mild irritation
of the eyes with symptoms such as stinging, tearing and redness.

Potential Health Effects: Skin
May cause mild skin irritation and redness. Repeated or prolonged contact may
cause dermatitis (red, dry, itchy skin).

Potential Health Effects: Ingestion
Ingestion of this Isocyanuric Acid (especially in large volumes) can irritate
the tissues of the mouth, esophagus, and other tissues of the digestive
system. Symptoms of exposure can include vomiting, diarrhea, and nausea.

Potential Health Effects: Inhalation
Breathing dusts or particulates generated by this Isocyanuric Acid can lead
to irritation of the nose, throat or respiratory system. Symptoms of severe
inhalation overexposures may include burning sensation, coughing, wheezing,
shortness of breath, headache, nausea and vomiting.

HMIS Ratings: Health Hazard: 2* Fire Hazard: I Physical Hazard: 0
Hazard Scale: 0 = Minimal I = Slight 2 = Moderate 3 = Serious 4 = Severe
* = Chronic hazard

* * * Section 4 - First Aid Measures * * *

First Aid: Eyes
In case of eye contact, flush with plenty of water for 15 minutes. If
irritation persists, seek medical attention.

First Aid: Skin
Remove all contaminated clothing. For skin contact, wash thoroughly with
soap and water for at least 20 minutes. Seek immediate medical attention if
irritation develops or persists.

First Aid: Ingestion

DO NOT INDUCE VOMITING. Have victim rinse mouth, if person is conscious.
Never give anything by mouth to a victim who is unconscious or having
convulsions. Contact a physician or poison control center if adverse affect
occurs.
First Aid: Inhalation
Remove source of contamination or move victim to fresh air. Apply artificial
respiration if victim is not breathing. Do not use mouth-to-mouth method if
victim ingested or inhaled the substance; induce artificial respiration with
the aid of a pocket mask equipped with a one-way valve or other proper
respiratory medical device. Administer oxygen if breathing is difficult.
Get immediate medical attention.

First Aid: Notes to Physician
Treatment is symptomatic and supportive. There is no specific antidote.

* * * Section 5 - Fire Fighting Measures * *

Flash Point: Not combustible. Method Used: Not applicable.
Upper Flammable Limit (UEL): Not applicable.
Lower Flammable Limit (LEL): Not applicable.

Auto Ignition: Not applicable.
Flammability Classification: Not applicable.

Rate of Burning: Not applicable.

General Fire Hazards
It is important to note that as with all organic solids, large dust clouds
of this product have the potential to ignite explosively. When involved in a
fire, this material may decompose and produce irritating vapors, acrid smoke
and toxic gases.

Hazardous Combustion Products
When heated to decomposition product emits toxic fumes of Isocyanuric Acid
gas, carbon monoxide, carbon dioxide and nitrogen oxides.

Extinguishing Media
Use any method suitable for the surrounding fire and other materials involved
in the fire.

Fire Fighting Equipment/Instructions
Firefighters should wear full protective clothing including self-contained
breathing apparatus.

NFPA Ratings: Health: 2 Fire: I Reactivity: 0 Other:
Hazard Scale: 0 = Minimal I = Slight 2 = Moderate 3 = Serious 4 = Severe

* * * Section 6 - Accidental Release Measures * *

Containment Procedures
Stop the flow of material, if this can be done without risk. Contain the
discharged material. . If sweeping of a contaminated area is necessary use a
dust suppressant agent, which does not react with product (see Section 10 for
incompatibility information).

Clean-Up Procedures
Small releases can be cleaned-up in gloves, goggles and suitable body
protection. Shovel the material into waste container. Thoroughly wash the
area after a spill or leak clean-up. In case of a large spill (in which
excessive dusts can be generated), clear the affected area, protect people,
and respond with trained personnel. Place all spill residues in an appropriate
container and seal. Thoroughly wash the area after a spill or leak clean-up.

Evacuation Procedures
Evacuate the area promptly and keep upwind of the spilled material. Isolate
the spill area to prevent people from entering. Keep materials which burn
away from spilled material. In case of large spills, follow all facility
emergency response procedures.

Special Procedures
Remove soiled clothing and launder before reuse. Avoid all skin contact with
the spilled material. Have emergency equipment readily available.

* * * Section 7 - Handling and Storage

Handling Procedures
Do not breathe dust. Avoid all contact with skin and eyes. Wherever dust
clouds may be generated, eliminate sparks, flames and other ignition sources.
Use this product only with adequate ventilation. Wash thoroughly after
handling. Care should be taken to avoid the accumulation of dusts, which can
create a serious dust-explosion hazard. All equipment used in the handling
of this material should be electrically grounded.

Storage Procedures
Keep container tightly closed when not in use. Store containers in a cool,
dry location, away from direct sunlight, sources of intense heat, or where
freezing is possible. Material should be stored in secondary containers or
in a diked area, as appropriate. Keep this product in an air-tight
container.

Storage Procedures
Store containers away from incompatible chemicals (see Section 10, Stability
and Reactivity). Storage areas should be made of fire-resistant materials.
Post warning and "NO SMOKING" signs in storage and use areas, as appropriate.
Use corrosion-resistant structural materials, lighting, and ventilation
systems in the storage area. Floors should be sealed to prevent absorption
of this material. Inspect all incoming containers before storage, to ensure
containers are properly labeled and not damaged. Have appropriate
extinguishing equipment in the storage area (i.e., sprinkler system,
portable fire extinguishers). Empty containers may contain residual
particulates; therefore, empty containers should be handled with care. Never
store food, feed, or drinking water in containers that held this product.
Keep this material away from food, drink and animal feed. Do not store this
material in open or unlabeled containers. Limit quantity of material stored.

* * * Section 8 - Exposure Controls / Personal Protection * * *

Exposure Guidelines
A: General Product Information
No ACGIH, NIOSH or OSHA guidelines listed for this product.
B: Component Exposure Limits
There are no ACGIH, NIOSH or OSHA guidelines listed for this product's
components. The exposure limits given are for Particulates Not Otherwise
Classified (PNOC).

OSHA: 15 mg/m3 TWA (Total dust)
5 mg/m3 TWA (Respirable fraction)
DFG MAKs 4 mg/m3 TWA (Inhalable fraction)
1.5 mg/m3 TWA (Respirable fraction)

Engineering Controls
Use mechanical ventilation such as dilution and local exhaust. Use a
corrosion-resistant ventilation system and exhaust directly to the outside.
Supply ample air replacement. Provide dust collectors with explosion vents.
PERSONAL PROTECTIVE EQUIPMENT
The following information on appropriate Personal Protective Equipment is
provided to assist employers in complying with OSHA regulations found in
29 CFR Subpart I (beginning at 1910.132). Please reference applicable
regulations and standards for relevant details.

Personal Protective Equipment: Eyes/Face
Wear safety glasses with side shields or chemical goggles. If necessary,
refer to U.S. OSHA 29 CFR 1910.133.

Personal Protective Equipment: Skin
Wear appropriate work gloves for type of operation. Gloves should be tested
to determine their suitability for prolonged contact with this material. If
necessary, refer to U.S. OSHA 29 CFR 1910.138.

Personal Protective Equipment: Respiratory
None required where adequate ventilation conditions exist. No specific
guidelines are available. If airborne concentrations are above the applicable
exposure limits, use NIOSH-approved respiratory protection. An approved dust
and mist air-purifying respirator may be adequate. If respiratory protection
is needed, use only protection authorized in the U.S. Federal OSHA Standard
(29 CFR 1910.134), applicable U.S. State regulations. Oxygen levels below
19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-
facepiece pressure/demand SCBA or a full facepiece, supplied air respirator
with auxiliary self-contained air supply is required under OSHA's Respiratory
Protection Standard (1910.134-1998). Personal Protective Equipment: General
Have an eyewash fountain and safety shower available in the work area. Use
good hygiene practices when handling this material including changing and
laundering work clothing after use.

* * * Section 9 - Physical & Chemical Properties * * *

Physical Properties: Additional Information
The data provided in this section are to be used for product safety handling
purposes. Please refer to Product Data Sheets, Certificates of Conformity
or Certificates of Analysis for chemical and physical data for determinations
of quality and for formulation purposes.

Appearance: White granular powder
Odor: Odorless
Physical State: Solid
pH: 4.8 (saturated aqueous solutions)
Vapor Pressure: Negligible.
Vapor Density: Not applicable
Boiling Point: Sublimes at > 329.12 deg C (625 deg F)
Melting Point: 360 deg C (680 deg F)
Solubility (H2O): 0.3 g/100 mL at 25 deg C
Specific Gravity: 1.768 (water = 1)
Freezing Point: Not applicable
Particle Size: Not available
Softening Point: Not applicable
Evaporation Rate: Not applicable
Bulk Density: 0.73-0.83 g/cc
Molecular Weight: 129.09
Percent Volatile: Not available
Chemical Formula: C3H3N303

* * * Section 10 - Chemical Stability & Reactivity Information *
Chemical Stability
Isocyanuric Acid is normally stable. Isocyanuric Acid is hygroscopic; it
absorbs moisture from air.

Chemical Stability: Conditions to Avoid
Moisture, heat and incompatible materials.

Incompatibility:
Incompatible with strong oxidizing agents. Isocyanuric Acid, Ammonia-chlorine
mixtures are explosive if warmed or if chlorine is in excess, owing to
formation of nitrogen trichloride. Hydrazine, hydoxylamine and calcium
nitride ignite in chlorines such as Isocyanuric Acid, and nitrogen triiodide
may explode on contact with chlorines. During chlorination of impure biuret
in water at 20 degrees C, a violent explosion occurred. This was attributed
to conversion of the cyanuric acid impurity (3%) to nitrogen trichloride
and spontaneous explosion of the latter. During chlorination of
2,4,6-triketo-hexahydro-1,3,5-triazine (cyanuric acid), presence of the
diaminoketo and aminodiketo analogues as impurities, or of an unusually low
pH value, may lead to formation of nitrogen trichloride.

Hazardous Decomposition
When heated to decomposition, product emits toxic fumes of Isocyanuric acid
gas, nitrogen oxides, carbon oxides.

Hazardous Polymerization
Will not occur.

* * * Section 11 - Toxicological Information *

Acute and Chronic Toxicity
A: General Product Information
Standard Draize Test (Skin-Rabbit) 500 mg/24 hours: Mild; Rinsed with Water
(Eye-Rabbit) 20 mg/24 hours: Mild May cause eye, skin, nose, throat and
respiratory tract irritation.

Chronic: Long term skin overexposure to this product may lead to
dermatitis (red, itchy skin).
B: Component Analysis - LD50/LC50
Isocyanuric Acid (108-80-5):
LD50 (Oral-Rat) 7700 mg/kg; LD50 (Oral-Mouse) 3400 mg/kg; LD50
(Oral-Mammal-species unspecified) > 5 gm/kg; LD50
(Intravenous-Rat) > 100 mg/kg; LD50 (Intravenous-Mouse) > 500 mg/kg;
LD50 (Skin-Rabbit) > 5 gm/kg
B: Component Analysis - TDLo/TCLo/LD/LDLo
Isocyanuric Acid (108-80-5):
TDLo (oral, rat) = 55 g/kg/ 82 weeks/ intermittent; equivocal tumorigenic
agent; TDLo (subcutaneous, rat) = 27 g/kg/ 2 years/
intermittent; equivocal tumorigenic agent; TDLo (oral, mouse) = 130 g/kg/
2 years/ intermittent; equivocal tumorigenic agent; TDLo (skin, mouse)
= 2400 mg/kg; equivocal tumorigenic agent; TDLo (skin, mouse) = 138 g/kg/
2 years/ intermittent; equivocal tumorigenic agent; TD (oral, rat)
= 60,750 mg/kg/ 81 weeks/ intermittent; equivocal tumorigenic agent; TD
(subcutaneous, rat) = 36 g/kg/ 2 years/ intermittent; equivocal tumorigenic
agent.

Carcinogenicity
A: General Product Information
150-300 mg/kg Isocyanuric Acid was fed to rats, cysticerian sarcomas were
observed between 19-25 months. Fibroadenoma of mammary glands noted in 2
females. In mice fed 280-310 mg/kg, myeloid leukosis observed in 2/14 mice
that had survived 23 months. Feeding studies in rats and mice suggest lower
tumorigenic potential. Studies of subcutaneous application in mice at an
application rate of 550 to 620 mg/kg show no tumor induction. Dermal
application of two drops of 20% Isocyanuric Acid inbenzene 3 times/week to
mice is reported in which two animals developed liver tumors after 22 months.

B: Component Carcinogenicity
No information available.
Epidemiology
No information available.
Neurotoxicity
No information available.
Mutagenicity
No information available.

Teratogenicity
Studies of the teratogenic and reproductive effects of Isocyanuric Acid in
mice and rats examined show no dominant lethal response nor any significant
difference in reproductive parameters between the experimental and control
groups.

Other Toxicological Information
No information available.

* * * Section 12 - Ecological Information

Ecotoxicity
A: General Product Information
No information available.
B: Ecotoxicity
No ecotoxicity data are currently available for Isocyanuric Acid.

Environmental Fate
If released to the soil, Isocyanuric Acid is expected to be highly mobile.
If released to water, it will be essentially nonvolatile. Isocyanuric acid
biodegrades readily under a wide variety of natural conditions. If released
to the atmosphere, it will exist in both the vapor and particulate phases.
In the vapor phase, Isocyanuric Acid will degrade in the ambient atmosphere
by reaction with photochemically produced hydroxyl radicals with an estimated
half-life of 102 days. Physical removal of particulate Isocyanuric Acid from
air is likely to occur through wet and dry deposition. Isocyanuric Acid is
highly toxic to certain strains of barley and radishes.

* * * Section 13 - Disposal Considerations * * *

US EPA Waste Number & Descriptions
A: General Product Information
Waste, if discarded, is not expected to be a characteristic hazardous
waste under RCRA.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.

Disposal Instructions
Review federal, provincial, and local government requirements prior to
disposal. Disposal by controlled incineration or secure landfill may be
acceptable.

* * * Section 14 - Transportation Information * * *

NOTE: The shipping classification information in this section (Section 14)
is meant as a guide to the overall classification of the product. However,
transportation classifications may be subject to change with changes in
package size. Consult shipper requirements under I.M.O., I.C.A.O. (I.A.T.A.)
and 49 CFR to assure regulatory compliance.

US DOT Information
Shipping Name: Non-regulated.
Hazard Class: Not Applicable
UN/NA #: Not Applicable
Packing Group: Not Applicable
Required Label(s): None
Additional Info.: None.

International Air Transport Association (IATA)
For Shipments by Air transport: We classify this product as hazardous
(Class 9) when shipped by air because 49 CFR 173.140 (a). "For the purposes
of this subchapter, miscellaneous hazardous material (Class 9) means a
material which presents a hazard during transportation, but which does not
meet the definition of any other hazard class. This class includes: (a) Any
material which has an anesthetic, noxious, or other similar property which
could cause extreme annoyance or discomfort to a flight crew member so as to
prevent the correct performance of assigned duties."

Proper Shipping Name: Environmentally hazardous substance, solid, n.o.s.
(isocyanuric acid)
Hazard Class: 9
UN: UN 3077
Packing Group: III
Passenger & Cargo Aircraft Packing Instruction: 911
Passenger & Cargo Aircraft Maximum Net Quantity: No Limit
Limited Quantity Packing Instruction (Passenger & Cargo Aircraft): Y911
Limited Quantity Maximum Net Quantity (Passenger & Cargo Aircraft): 30 kg
Special Provisions: A97
ERG Code: 9L

International Maritime Organization (I.M.O.) Classification
Isocyanuric Acid is not regulated under I.M.O.

* * * Section 15 - Regulatory Information *

US Federal Regulations
A: General Product Information
No additional information.
B: Component Analysis
This material contains no chemical required to be identified under SARA
Section 302 (40 CFR 355 Appendix A), SARA

Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4):
Isocyanuric Acid (108-80-5)

SARA 302 (EHS TPQ) There are no specific Threshold Planning Quantities for
Isocyanuric Acid. The default Federal MSDS submission and inventory
requirement filing threshold of 10,000 lbs. (4,540 kg) therefore applies,
per 40 CFR 370.20.

C: Sara 311/312 Tier II Hazard Ratings:

Component CAS # Fire Reactivity Pressure Immediate Chronic
Hazard Hazard Hazard Health Health
Hazard Hazard
Isocyanuric Acid 108-80-5 No No No Yes Yes

State Regulations
A: General Product Information
Other state regulations may apply.
B: Component Analysis - State
The following components appear on one or more of the following state
hazardous substances lists:

Component CAS # CA FL MA MN NJ PA
Isocyanuric Acid 108-80-5 No No No No No No

* * * Section 15 - Regulatory Information (Continued) * * *

Other Regulations
A: General Product Information
Not applicable.
B: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Isocyanuric Acid 108-80-5 Yes Yes Yes
C: Component Analysis - WHMIS IDL
Isocyanuric Acid is not on the Canadian Hazardous Products Act Ingredient
Disclosure List

ANSI Labeling (Z129.1):
CAUTION! MAY CAUSE EYE IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION.
PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN IRRITATION. Avoid breathing dusts
and mists. Do not breathe dust. Do not taste or swallow. Do not get on skin or
in eyes. Keep container closed. Use only with adequate ventilation. Wash
thoroughly after handling. Wear gloves, goggles, faceshields, suitable body
protection, and NIOSH/MSHA-approved respiratory protection, as appropriate.
FIRST-AID: In case of contact, immediately flush skin or eyes with plenty of
water for at least 5 minutes while removing contaminated clothing and shoes.
If inhaled, remove to fresh air. If ingested, do not induce vomiting. Get
medical attention. IN CASE OF FIRE: Use water fog, dry chemical, CO2, or
"alcohol" foam. IN CASE OF SPILL: Absorb spill with inert material. Place
residue in suitable container. Consult Material Safety Data Sheet for
additional information.

* * * Section 16 - Other Information *

Other Information
Chem One Ltd. ("Chem One") shall not be responsible for the use of any
information, product, method, or apparatus herein presented ("Information"),
and you must make your own determination as to its suitability and
completeness for your own use, for the protection of the environment, and for
health and safety purposes. You assume the entire risk of relying on this
Information. In no event shall Chem One be responsible for damages of any
nature whatsoever resulting from the use of this product or products, or
reliance upon this Information. By providing this Information, Chem One
neither can nor intends to control the method or manner by which you use,
handle, store, or transport Chem One products. If any materials are mentioned
that are not Chem One products, appropriate industrial hygiene and other
safety precautions recommended by their manufacturers should be observed.
Chem One makes no representations or warranties, either express or implied
of merchantability, fitness for a particular purpose or of any other nature
regarding this information, and nothing herein waives any of Chem One's
conditions of sale. This information could include technical inaccuracies or
typographical errors. Chem One may make improvements and/or changes in the
product (s) and/or the program (s) described in this information at any
time. If you have any questions, please contact us at Tel. 713-896-9966 or
E-mail us at Safety@chemone.com. Revision date: 05/30/01

Key/Legend
EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act;
ACGIH = American Conference of Governmental Industrial Hygienists;
IARC = International Agency for Research on Cancer; NIOSH = National
Institute for Occupational Safety and Health; NTP = National Toxicology
Program; OSHA = Occupational Safety and Health Administration Contact: Sue
Palmer-Koleman, PhD Contact Phone: (713)-896-9966

Revision log
08/04/00 3:50 PM SEP Changed company name, Sect 1 and 16, from Corporation
to Ltd.
05/30/01 9:31 AM HDF Checked exposure limits; made changes to Sect 9;
overall review, add SARA 311/312 Haz Ratings.
08/20/01 12:40 PM CLJ Add Shipments by Air information to Section 14, Changed
contact to Sue, non-800 Chemtrec Num.
02/15/02 11:01 AM HDF Addition of SARA Chronic Hazard Ratings.
09/16/03 9:45 AM HDF General review of entire MSDS. Up-graded Section
3 Health Hazard information, HMIS categories. Up-graded text in Section 4,
First Aid Information; Added PNOC exposure limits and references to OSHA PPE
CFRs in Section 8; Addition of currently available toxicity data to
Section 11. Addition of Atmospheric Fate data to Section 12. Up-Dated
Section 14 Transportation Information.




For Additional Information:
Contact: MSDS Coordinator - Univar USA
During business hours, Pacific Time - (425) 889-3400

NOTICE
Univar USA expressly disclaims all express or implied warranties of merchantibility and fitness
for a particular purpose with respect to the product or information provided herein, and shall
under no circumstances be liable for incidental or consequential damages.

Do not use ingredient information and/or ingredient percentages in this MSDS as a product
specification. For product specification information refer to a Product Specification Sheet and/or
a Certificate of Analysis. These can be obtained from your local Univar USA Sales Office.

All information appearing herein is based upon data obtained from the manufacturer and/or
recognized technical sources. While the information is believed to be accurate, Univar USA
makes no representations as to its accuracy or sufficiency. Conditions of use are beyond Univar
USA's control. Therefore, users are responsible to verify this data under their own operating
conditions to determine whether the product is suitable for their particular purposes, and they
assume all risks of their use, handling, and disposal of the product or from the publication or use
of, or reliance upon, information contained herein. This information relates only to the product
designated herein and does not relate to its use in combination with any other material or in any
other process.

END OF MSDS

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