MATERIAL SAFETY DATA SHEET
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CHS Inc. Transportation Emergency (CHEMTREC): 1-800-424-9300
P.O. Box 64089 Technical Information: 1-651-355-8443
Mail station 525 MSDS Information: 1-651-355-8438
St. Paul, MN 55164-0089
PRODUCT NAME: No. 1 DIESEL FUEL MSDS: 0143-M2A0 - Rev. D (02/08/07)
COMMON NAME: No. 1 Distillate Fuel, No. 1 High Sulfur Diesel (Dyed) CHEMICAL FORMULA: Mixture
No. 1 Low Sulfur Diesel (Dyed), No. 1 Ultra Low Sulfur Diesel (Dyed/Undyed)
CHEMICAL NAME: Petroleum Distillate CHEMICAL FAMILY: A mixture of Paraffinic,
Olefinic, Naphthenic, and Aromatic Hydrocarbon.
Section 2 - COMPOSITION AND INFORMATION ON INGREDIENTS
INGREDIENTS PERCENTAGES PEL (OSHA) TLV (ACGIH) CAS #
(by weight) TWA TWA
Petroleum
Distillates 0-100 N/D 200 ppm 8008-20-6
Biphenyl 0.5-1.5 0.2 ppm 92-52-4
Naphthalene 0-3 10 ppm 91-20-3
Xylene 0-2.5 100 ppm 1330-20-7
1,2,4-Trimethylbenzene 0-2 25 ppm 95-63-6
Note: The National Institute for Occupational Safety and Health has published a Recommended Exposure Limit (REL) of 100 mg/m3 TWA or 禄 14 ppm based on an average
molecular weight of 170 for kerosene like factions.
(TWA) - Time Weighted Average is the employee's average airborne exposure in any 8-hour work shift of a 40-hour work week which shall not be exceeded.
(STEL) - Short Term Exposure Limit is the employee's 15-minute time weighted average exposure which shall not be exceeded at any time during a work day unless another time
limit is specified.
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
A clear to light yellow liquid with a hydrocarbon odor. May contain dye.
OSHA HAZARD CLASSES
Based on OSHA definitions, the following ingredients in this product are hazardous. The OSHA physical and health hazard
categories are shown below.
Petroleum Hydrocarbon - Combustible, toxic (moderate), target organ (skin).
1,2,4-Trimethylbenzene - Flammable, toxic, irritant, target organ (Central Nervous System, blood).
POTENTIAL HEALTH EFFECTS
ROUTES OF ENTRY: Eye Contact, Dermal, Inhalation, Ingestion.
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No. 1 Diesel Fuel
ACUTE EFFECTS OF OVEREXPOSURE:
Eyes - Minor irritation
Skin - Slight irritation
Inhalation - Vapors may cause dizziness or asphyxiation
Ingestion - Central nervous system depression, peripheral nervous system depression, narcosis, asphyxiation, gastrointestinal
disturbances. Aspiration of vomitus can cause serious pneumonitis, particularly in young children.
CHRONIC EFFECTS OF OVEREXPOSURE: Dermatitis from chronic exposure. Products of similar composition were tested on
laboratory animals, and weak to moderately positive results were found in mouse skin cancer studies, mixed and inconsistent results were
found in mutagenicity studies, and negative results were found in rat teratology studies. There is no direct evidence that this material
causes skin cancer in humans. This material is not listed as a carcinogen by NTP, IARC, or OSHA.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: May aggravate pre-existing dermatitis or respiratory illness.
CARCINOGENICITY: Petroleum Hydrocarbon NTP: No IARC: No OSHA: No
1,2,4-Trimethylbenzene NTP: No IARC: No OSHA: No
Section 4 - FIRST AID MEASURES
EMERGENCY AND FIRST AID PROCEDURES:
Eye Contact: If material contacts the eye, flush thoroughly with water for at least 15 minutes, occasionally lifting upper and
lower lids, until no evidence of chemical remains. Get medical attention.
Skin Contact: Remove contaminated clothing. Wash affected areas with soap and water.
Inhalation: Move person to fresh air. If a large amount has been inhaled, keep victim warm and get medical attention. Begin
rescue breathing procedures if not breathing.
Ingestion: Do NOT induce vomiting. Get medical attention immediately. If spontaneous vomiting occurs, lower victim's head in
an effort to prevent vomits from entering the lungs. Never give anything by mouth to an unconscious person.
Section 5 - FIRE - FIGHTING MEASURES
FLASH POINT: 100-150掳F (38-66掳C) TCC AUTO IGNITION TEMP: 410掳 F
FLAMMABLE LIMITS IN AIR LOWER UPPER
% BY VOLUME 0.7 5.0
EXTINGUISHING MEDIA: Dry Chemical, Foam, Carbon Dioxide (CO2), Water (fog pattern)
SPECIAL FIRE FIGHTING PROCEDURES: Water may be ineffective on flames, but should be used to keep fire-exposed containers
cool. Water or foam sprayed into container of hot burning product could cause frothing and endanger fire fighters. Large fires, such as
tank fires, should be fought with caution. If possible, pump the contents from the tank and keep adjoining structures cool with water.
Avoid spreading burning liquid with water used for cooling purposes. Do not flush down public sewers. Avoid inhalation of vapors. Fire
fighters should wear self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors are heavier than air and may travel along the ground to a source of ignition
(pilot light, heater, electric motor) some distance away. Containers, drums (even empty) can explode when heat (welding, cutting, etc.) is
applied.
HAZARD RATINGS: NFPA 704: Health 1 Fire 2 Reactivity 0
HMIS: Health 1 Fire 2 Reactivity 0
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Section 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO TAKE IF MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition. Notify emergency response
personnel as appropriate. If facility or operation has an "Oil or Hazardous Substance Contingency Plan", "Spill Prevention Control &
Countermeasures (SPCC) Plan" or equivalent, activate its procedures. Prohibit persons not wearing protective equipment from entering
the area. Stop leak at source, contain spill to prevent spreading. Small spills can be removed with inert absorbent. Dike areas of large spill
to prevent runoff to sewers, streams, etc. Ventilate area. Avoid breathing vapors.
Section 7 - HANDLING AND STORAGE
HANDLING AND STORAGE: Transport, handle and store in accordance with OSHA Regulation 29 CFR 1910.106, and applicable
D.O.T. Regulation. Caution: Misuse of empty containers can be hazardous. Empty containers can be hazardous since emptied containers
retain product residue (vapor, liquid, and/or solid). Cutting or welding empty containers might cause fire, explosion or toxic fumes from
residues.
Section 8 - EXPOSURE CONTROL - PERSONAL PROTECTION
ENGINEERING CONTROLS: Provide adequate local or dilution ventilation to keep vapors below permissible concentrations.
RESPIRATORY EQUIPMENT: Personnel should never enter areas of high concentrations without proper respiratory protection. If
exposure limits for product or components are exceeded, NIOSH-approved respiratory protection equipment should be worn. Proper
selection of respirators should be determined by adequately trained personnel, based on the contaminants, the degree of potential exposure
and published respiratory protection factors. Self-contained breathing apparatus or supplied air respiratory protection required for entry
into tanks, vessels, or other confined spaces containing kerosene.
EYE PROTECTION: Chemical type goggles or face shield where contact with liquid or mist may occur.
PROTECTIVE CLOTHING: Wear impervious clothing and gloves when contact with skin may occur.
OTHER (SAFETY SHOWERS, EYE WASH STATIONS, ETC.): Water should be available for flushing and washing when
exposure exists.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: A clear to light yellow liquid, may ODOR: Hydrocarbon odor.
contain red dye.
BOILING POINT: 340掳F - 570掳 F SPECIFIC GRAVITY (water=1): 0.82
VAPOR PRESSURE: < 50 mmHg @ 100掳F VAPOR DENSITY (air=1): >1
SOLUBLE IN WATER: Insoluble EVAPORATION RATE (ether=1): >1
pH: N/D
Section 10 - STABILITY AND REACTIVITY
STABILITY:
STABLE X
UNSTABLE
INCOMPATIBILITY:
CONDITIONS TO AVOID: Heat, flame, all ignition sources and static electricity.
MATERIALS TO AVOID: Strong oxidizing agents.
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No. 1 Diesel Fuel
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, and other petroleum decomposition products
(hydrocarbons).
HAZARDOUS POLYMERIZATION: Has not been reported to occur under normal temperatures and pressures.
Section 11 - TOXICOLOGY INFORMATION
Note: CHS has not conducted specific toxicity tests on this product. Our hazard evaluation is based from similar
ingredients, technical literature, and/or professional experience.
Section 12 - ECOLOGICAL INFORMATION
Note: CHS has not conducted specific ecological tests on this product.
Section 13 - DISPOSAL CONSIDERATION
WASTE DISPOSAL PROCEDURES: Recycle as much of the recoverable product as possible. Do not flush to drain or storm sewer or
otherwise release to the environment. Dispose of non-recyclable material according to federal, state and local regulations.
Section 14 - TRANSPORTATION
DOT PROPER SHIPPING NAME: Fuel 0il #1 DOT HAZARD CLASS: Flammable Liquid
DOT IDENTIFICATION NUMBER: NA 1993 DOT EMER. RESPONSE GUIDE NO.: 128
(Formerly #27)
Proper Shipping Name-Fuel Oil #1; Hazard Class- 3; UN/NA Identification #- NA 1993; Packing Group III; Placard- FLAMMABLE LIQUID.
Section 15 - REGULATORY INFORMATION
This product contains the following toxic chemicals subject to the reporting requirements of SARA Section 313 of the Emergency
Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372:
CAS Number Chemical Name Percent by Weight
95-63-6 1,2,4-Trimethylbenzene 0-2%
91-20-3 Naphthalene 0-3%
SARA SECTION 311-312 HAZARD CATEGORIES (40 CFR 370.2):
FIRE: Yes SUDDEN RELEASE OF PRESSURE: No REACTIVE: No ACUTE: Yes CHRONIC: Yes
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Section 16 - OTHER INFORMATION
Prepared By: Hue Lam Date: February 08, 2007
Title: EHS Compliance Specialist Supersedes: December 24, 2003
Reason for Issue: Periodic review and update
THE INFORMATION CONTAINED IN THIS MSDS RELATES ONLY TO THE SPECIFIC MATERIAL IDENTIFIED. IT DOES NOT COVER USE OF THAT
MATERIAL IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PARTICULAR PROCESS. IN COMPLIANCE WITH 29 C.F.R. 1910.1200(g),
CHS HAS PREPARED THIS MSDS IN SEGMENTS, WITH THE INTENT THAT THOSE SEGMENTS BE READ TOGETHER AS A WHOLE WITHOUT
TEXTUAL OMISSIONS OR ALTERATIONS. CHS BELIEVES THE INFORMATION CONTAINED HEREIN TO BE ACCURATE, BUT MAKES NO
REPRESENTATION, GUARANTEE, OR WARRANTY, EXPRESS OR IMPLIED, ABOUT THE ACCURACY, RELIABILITY, OR COMPLETENESS OF THE
INFORMATION OR ABOUT THE FITNESS OF CONTENTS HEREIN FOR EITHER GENERAL OR PARTICULAR PURPOSES. PERSONS REVIEWING
THIS MSDS SHOULD MAKE THEIR OWN DETERMINATION AS TO THE MATERIAL鈥橲 SUITABILITY AND COMPLETENESS FOR USE IN THEIR
PARTICULAR APPLICATIONS.
Cenex庐 is a registered trademark of CHS Inc.
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