ESL3-BK
August 11 , 2005
Material Safety Data Sheet
1. Article and Corporate Identification
1.1. Product:
ECO-SOL MAX, ESL3-BK
1.2. Manufacturer/Distributor:
Manufacture's name: Roland DG Corporation
Address: 1-6-4 Shinmiyakoda Hamamatsu-shi
Shizuoka 431-2103
JAPAN
Phone: + 81-53-484-1224
Fax: + 81-53-484-1221
1.3. Medical Emergency Number
Not Available
2. Composition Information
This is a solvent ink formulation
Ink Composition CAS No. % By Weight
Carbon black 1333-86-4 1-5
- 1-5
Synthetic polymer
112-36-7 55-65
Diethylene glycol diethyl ether
96-48-0 10-20
Gamma-butyrolactone
143-24-8 10-20
Tetraethylene glycol, dimethyl ether
1559-34-8 1-5
Tetraethylene glycol, monobutyl ether
- 1-5
Additives
3. Hazard Identification
3.1 Emergency Overview:
Ink component is a black liquid that causes eye, nose or throat irritation, and that effects anesthesia, if inhales. Ink
may flash, when under high temperature. Avoid contact with eyes or clothing. In the case of skin contact, wash
with soap and water. Keep out of reach of children.
3.2 Potential Health Effects:
Eyes: Ink contact with eye will be irritating. See Section 11 for Toxicology.
Skin: Ink contact with skin may cause minimally irritation. See Section 11 for Toxicology.
Inhalation: Intentional exposure to ink vapors (mist) will cause respiratory irritation and anesthesia. See
Section 11 for Toxicology.
Ingestion: May cause upset stomach. See Section 11 for Toxicology.
1/4
ESL3-BK
August 11 , 2005
4. First Aid Measures
4.1 Eyes: Immediately flush with room temperature, low pressure, clean water for at least 15 minutes.
Seek medical attention if eye irritation continues.
4.2 Skin: Wash surface areas with soap and water. Wash soiled clothing before rewearing. Consult a
physician if irritation continues.
4.3 Inhalation: Remove subject to ventilated fresh air. If not breathing, give artificial respiration right away.
If breathing is difficult, give oxygen. Seek immediate medical attention.
4.4 Ingestion: Seek medical advice; and attention if stomach continues to be upset.
5. Fire Fighting Measures
5.1 Flammability: Combustible liquid under Hazard Communication Standard (HCS, U.S.A)
See Section 9 for Flash Point.
5.2 Extinguishing Media: Water spray, dry chemical, carbon dioxide or alcohol foam
5.3 Fire Fighting Instructions: Extinguish to use fire fighting media or plentiful fog water. Put protection
wear without fail in case of fire fighting work; do not work in the leeward.
6. Accidental Release Measures
Remove the person of the leeward. Keep away the person from periphery of
6.1 Personal protections:
the place of the leakage. Ventilate sufficiently during clean-up in case of
inside of a house.
If a spill occurs, use sponges to wipe-up ink, then rinse area with damp cloth.
6.2 Methods for cleaning up:
Place waste in closed container for disposal. Do not dispose of waste to the
sewer. Wash hands with soap and water.
7. Precautions for Safe Handling and Use
Use proper ventilation and no fire in work place. Put protection wear that has
7.1 Handling:
electrical conductivity in case of work. Keep out of reach of children and do
not drink ink. Do not dismantle cartridge. Make sure cartridge is dry before
insertion into printer housing.
7.2 Storage: Do not store the cartridges in high or freezing temperatures. Keep cartridge
out of direct sunlight. Do not store cartridges with oxidizing agents or
explosives.
7.3 Specific use(s): Not specified
8. Exposure Controls and Personal Protection
8.1 Engineering controls: Proper ventilation
8.2 Exposure controls:
8.2.1 Occupational exposure control Not established
8.2.1.1 Respiratory protection Not required under suitable use as setting the cartridge on the printer.
8.2.1.2. Hand protection Not required under suitable use as setting the cartridge on the printer.
8.2.1.3 Eye protection Not required under suitable use as setting the cartridge on the printer.
Not required under suitable use as setting the cartridge on the printer.
8.2.1.4 Skin protection
Not established
8.2.2 Environmental exposure control
2/4
ESL3-BK
August 11 , 2005
9. Physical and Chemical Properties of Ink Formulation
9.1 General information
Appearance Black Liquid
Odor: Slightly
9.2 Important health, safety and environmental information
pH: Not applicable
Boiling point: No data available
Melting point: No data available
Flash point: about 71 deg.C (closed cup)
Autoflammability: None
Explosive properties: 1.4-6.9v/v% as Gamma-butyrolactone
Oxidizing properties: None
Vapor density: Greater than 1 (air=1)
Relative density: No data available
Solubility in water: Soluble
Solubility in fat: No data available
Partition coefficient: No data available
Viscosity: No data available
9.3 Other information Not specified
10. Stability and Reactivity
Stability: Stable under normal temperature
Hazardous polymerization: No data available
10.1 Conditions to avoid: High and freezing temperatures
10.2 Materials to avoid: Oxidizers and explosives
10.3 Hazardous decomposition products: No data available
11. Toxicology and Health Hazards
*Based on toxicology data of chemically similar material
Routes Of Overexposure: Eye, skin, inhalation, and oral
Acute Health Hazards:
- Overexposure of eye surface to ink may be mildly irritating
- Overexposure of skin to ink contact may cause irritation and in some people swelling and redness
- Intentional inhalation overexposure to ink vapors may result in respiratory tract irritation and anesthesia
- Intentional or accidental oral ingestion may cause an upset stomach
Chronic Health Hazards: None Known
Mugtagenicity: Negative (by Ames Test)*
Carcinogenicity: With excessive exposure, carbon black has been listed as a possible human
carcinogen. However, as engineered within this ink cartridges, emissions to
air of carbon black during normal printing use have not been found. IARC,
the International Agency for Research on Cancer, has found printing inks to be
not classifiable as human carcinogens as group 3.
Toxicity Data: Oral LD50 Dermal LD50 Inhalant LC50
>2500mg/kg(Rat)* >2000mg/kg(Rat)* No data available
3/4
ESL3-BK
August 11 , 2005
Eye irritating: Moderate irritant (Rabbit, OECD405)*
Skin irritating: Mild irritant (Rabbit, OECD404)*
Skin sensitizing: Non-sensitizer (LLNA, OECD429)*
12. Ecological Information
12.1 Ecotoxicity: No data available on the adverse effects of this ink on the environment
12.2 Mobility: No data available on the adverse effects of this ink on the environment
12.3 Persistence and degradability: No data available on the adverse effects of this ink on the environment
12.4 Bioaccumulative potential: No data available on the adverse effects of this ink on the environment
12.5 Other adverse effects: No data available
13. Disposal Considerations
Disposal should be in accordance with federal, state, and local requirement.
14. Transportation Information
UN Class/UN Number: Not applicable
15. Regulatory Considerations
US Regulation:
TSCA Section 4(a) Final Test Rules Regulated Not regulated
TSCA Section 8(a) Preliminary Assessment Information Rule (PAIR) Not regulated
TSCA Section 8(a) Inventory Update Rule Not regulated
TSCA Section 12(b) One-Time Export Notification Regulated Not regulated
California Proposition 65 Not regulated
EU Information
Symbols and indication according to 1999/45/EC: This ink does not meet the criteria for classification
as dangerous.
16. Other Information
This "Material Safety Data Sheet" contains health, safety, and environmental information. It does not replace any
precautionary language or use and disposal information which accompanies the product. The information contained
herein is believed to be accurate at the time of precaution, but should only be used as a guide. It is subject to
revision from time to time. Roland DG does not warrant the completeness or accuracy of the information contained
herein.
4/4
ESL3-CY
August 11 , 2005
Material Safety Data Sheet
1. Article and Corporate Identification
1.1. Product:
ECO-SOL MAX, ESL3-CY
1.2. Manufacturer/Distributor:
Manufacture's name: Roland DG Corporation
Address: 1-6-4 Shinmiyakoda Hamamatsu-shi
Shizuoka 431-2103
JAPAN
Phone: + 81-53-484-1224
Fax: + 81-53-484-1221
1.3. Medical Emergency Number
Not Available
2. Composition Information
This is a solvent ink formulation
Ink Composition CAS No. % By Weight
Proprietary pigment - 1-5
- 1-5
Synthetic polymer
112-36-7 55-65
Diethylene glycol diethyl ether
96-48-0 10-20
Gamma-butyrolactone
143-24-8 10-20
Tetraethylene glycol, dimethyl ether
1559-34-8 1-5
Tetraethylene glycol, monobutyl ether
- 1-5
Additives
3. Hazard Identification
3.1 Emergency Overview:
Ink component is a cyan liquid that causes eye, nose or throat irritation, and that effects anesthesia, if inhales. Ink
may flash, when under high temperature. Avoid contact with eyes or clothing. In the case of skin contact, wash
with soap and water. Keep out of reach of children.
3.2 Potential Health Effects:
Eyes: Ink contact with eye will be irritating. See Section 11 for Toxicology.
Skin: Ink contact with skin may cause minimally irritation. See Section 11 for Toxicology.
Inhalation: Intentional exposure to ink vapors (mist) will cause respiratory irritation and anesthesia. See
Section 11 for Toxicology.
Ingestion: May cause upset stomach. See Section 11 for Toxicology.
4. First Aid Measures
4.1 Eyes: Immediately flush with room temperature, low pressure, clean water for at least 15 minutes.
Seek medical attention if eye irritation continues.
4.2 Skin: Wash surface areas with soap and water. Wash soiled clothing before rewearing. Consult a
physician if irritation continues.
1/4
ESL3-CY
August 11 , 2005
4.3 Inhalation: Remove subject to ventilated fresh air. If not breathing, give artificial respiration right away.
If breathing is difficult, give oxygen. Seek immediate medical attention.
4.4 Ingestion: Seek medical advice; and attention if stomach continues to be upset.
5. Fire Fighting Measures
5.1 Flammability: Combustible liquid under Hazard Communication Standard (HCS, U.S.A)
See Section 9 for Flash Point.
5.2 Extinguishing Media: Water spray, dry chemical, carbon dioxide or alcohol foam
5.3 Fire Fighting Instructions: Extinguish to use fire fighting media or plentiful fog water. Put protection
wear without fail in case of fire fighting work; do not work in the leeward.
6. Accidental Release Measures
Remove the person of the leeward. Keep away the person from periphery of
6.1 Personal protections:
the place of the leakage. Ventilate sufficiently during clean-up in case of
inside of a house.
If a spill occurs, use sponges to wipe-up ink, then rinse area with damp cloth.
6.2 Methods for cleaning up:
Place waste in closed container for disposal. Do not dispose of waste to the
sewer. Wash hands with soap and water.
7. Precautions for Safe Handling and Use
Use proper ventilation and no fire in work place. Put protection wear that has
7.1 Handling:
electrical conductivity in case of work. Keep out of reach of children and do
not drink ink. Do not dismantle cartridge. Make sure cartridge is dry before
insertion into printer housing.
7.2 Storage: Do not store the cartridges in high or freezing temperatures. Keep cartridge
out of direct sunlight. Do not store cartridges with oxidizing agents or
explosives.
7.3 Specific use(s): Not specified
8. Exposure Controls and Personal Protection
8.1 Engineering controls: Proper ventilation
8.2 Exposure controls:
8.2.1 Occupational exposure control Not established
8.2.1.1 Respiratory protection Not required under suitable use as setting the cartridge on the printer.
8.2.1.2. Hand protection Not required under suitable use as setting the cartridge on the printer.
8.2.1.3 Eye protection Not required under suitable use as setting the cartridge on the printer.
Not required under suitable use as setting the cartridge on the printer.
8.2.1.4 Skin protection
Not established
8.2.2 Environmental exposure control
2/4
ESL3-CY
August 11 , 2005
9. Physical and Chemical Properties of Ink Formulation
9.1 General information
Appearance Cyan Liquid
Odor: Slightly
9.2 Important health, safety and environmental information
pH: Not applicable
Boiling point: No data available
Melting point: No data available
Flash point: about 71 deg.C (closed cup)
Autoflammability: None
Explosive properties: 1.4-6.9v/v% as Gamma-butyrolactone
Oxidizing properties: None
Vapor density: Greater than 1 (air=1)
Relative density: No data available
Solubility in water: Soluble
Solubility in fat: No data available
Partition coefficient: No data available
Viscosity: No data available
9.3 Other information Not specified
10. Stability and Reactivity
Stability: Stable under normal temperature
Hazardous polymerization: No data available
10.1 Conditions to avoid: High and freezing temperatures
10.2 Materials to avoid: Oxidizers and explosives
10.3 Hazardous decomposition products: No data available
11. Toxicology and Health Hazards
*Based on toxicology data of chemically similar material
Routes Of Overexposure: Eye, skin, inhalation, and oral
Acute Health Hazards:
- Overexposure of eye surface to ink may be mildly irritating
- Overexposure of skin to ink contact may cause irritation and in some people swelling and redness
- Intentional inhalation overexposure to ink vapors may result in respiratory tract irritation and anesthesia
- Intentional or accidental oral ingestion may cause an upset stomach
Chronic Health Hazards: None Known
Mugtagenicity: Negative (by Ames Test)*
Carcinogenicity: Not contain any substances listed in IARC Monogrhaphs(1,2A and 2B)
Toxicity Data: Oral LD50 Dermal LD50 Inhalant LC50
>2500mg/kg(Rat)* >2000mg/kg(Rat)* No data available
3/4
ESL3-CY
August 11 , 2005
Eye irritating: Minimal irritant (Rabbit, OECD405)*
Skin irritating: Mild irritant (Rabbit, OECD404)*
Skin sensitizing: Non-sensitizer (LLNA, OECD429)*
12. Ecological Information
12.1 Ecotoxicity: No data available on the adverse effects of this ink on the environment
12.2 Mobility: No data available on the adverse effects of this ink on the environment
12.3 Persistence and degradability: No data available on the adverse effects of this ink on the environment
12.4 Bioaccumulative potential: No data available on the adverse effects of this ink on the environment
12.5 Other adverse effects: No data available
13. Disposal Considerations
Disposal should be in accordance with federal, state, and local requirement.
14. Transportation Information
UN Class/UN Number: Not applicable
15. Regulatory Considerations
US Regulation:
TSCA Section 4(a) Final Test Rules Regulated Not regulated
TSCA Section 8(a) Preliminary Assessment Information Rule (PAIR) Not regulated
TSCA Section 8(a) Inventory Update Rule Not regulated
TSCA Section 12(b) One-Time Export Notification Regulated Not regulated
California Proposition 65 Not regulated
EU Information
Symbols and indication according to 1999/45/EC: This ink does not meet the criteria for classification
as dangerous.
16. Other Information
This "Material Safety Data Sheet" contains health, safety, and environmental information. It does not replace any
precautionary language or use and disposal information which accompanies the product. The information contained
herein is believed to be accurate at the time of precaution, but should only be used as a guide. It is subject to
revision from time to time. Roland DG does not warrant the completeness or accuracy of the information contained
herein.
4/4
ESL3-MG
August 11 , 2005
Material Safety Data Sheet
1. Article and Corporate Identification
1.1. Product:
ECO-SOL MAX, ESL3-MG
1.2. Manufacturer/Distributor:
Manufacture's name: Roland DG Corporation
Address: 1-6-4 Shinmiyakoda Hamamatsu-shi
Shizuoka 431-2103
JAPAN
Phone: + 81-53-484-1224
Fax: + 81-53-484-1221
1.3. Medical Emergency Number
Not Available
2. Composition Information
This is a solvent ink formulation
Ink Composition CAS No. % By Weight
Proprietary pigment - 1-5
- 1-5
Synthetic polymer
112-36-7 55-65
Diethylene glycol diethyl ether
96-48-0 10-20
Gamma-butyrolactone
143-24-8 10-20
Tetraethylene glycol, dimethyl ether
1559-34-8 1-5
Tetraethylene glycol, monobutyl ether
- 1-5
Additives
3. Hazard Identification
3.1 Emergency Overview:
Ink component is a magenta liquid that causes eye, nose or throat irritation, and that effects anesthesia, if inhales.
Ink may flash, when under high temperature. Avoid contact with eyes or clothing. In the case of skin contact, wash
with soap and water. Keep out of reach of children.
3.2 Potential Health Effects:
Eyes: Ink contact with eye will be irritating. See Section 11 for Toxicology.
Skin: Ink contact with skin may cause minimally irritation. See Section 11 for Toxicology.
Inhalation: Intentional exposure to ink vapors (mist) will cause respiratory irritation and anesthesia. See
Section 11 for Toxicology.
Ingestion: May cause upset stomach. See Section 11 for Toxicology.
1/4
ESL3-MG
August 11 , 2005
4. First Aid Measures
4.1 Eyes: Immediately flush with room temperature, low pressure, clean water for at least 15 minutes.
Seek medical attention if eye irritation continues.
4.2 Skin: Wash surface areas with soap and water. Wash soiled clothing before rewearing. Consult a
physician if irritation continues.
4.3 Inhalation: Remove subject to ventilated fresh air. If not breathing, give artificial respiration right away.
If breathing is difficult, give oxygen. Seek immediate medical attention.
4.4 Ingestion: Seek medical advice; and attention if stomach continues to be upset.
5. Fire Fighting Measures
5.1 Flammability: Combustible liquid under Hazard Communication Standard (HCS, U.S.A)
See Section 9 for Flash Point.
5.2 Extinguishing Media: Water spray, dry chemical, carbon dioxide or alcohol foam
5.3 Fire Fighting Instructions: Extinguish to use fire fighting media or plentiful fog water. Put protection
wear without fail in case of fire fighting work; do not work in the leeward.
6. Accidental Release Measures
Remove the person of the leeward. Keep away the person from periphery of
6.1 Personal protections:
the place of the leakage. Ventilate sufficiently during clean-up in case of
inside of a house.
If a spill occurs, use sponges to wipe-up ink, then rinse area with damp cloth.
6.2 Methods for cleaning up:
Place waste in closed container for disposal. Do not dispose of waste to the
sewer. Wash hands with soap and water.
7. Precautions for Safe Handling and Use
Use proper ventilation and no fire in work place. Put protection wear that has
7.1 Handling:
electrical conductivity in case of work. Keep out of reach of children and do
not drink ink. Do not dismantle cartridge. Make sure cartridge is dry before
insertion into printer housing.
7.2 Storage: Do not store the cartridges in high or freezing temperatures. Keep cartridge
out of direct sunlight. Do not store cartridges with oxidizing agents or
explosives.
7.3 Specific use(s): Not specified
8. Exposure Controls and Personal Protection
8.1 Engineering controls: Proper ventilation
8.2 Exposure controls:
8.2.1 Occupational exposure control Not established
8.2.1.1 Respiratory protection Not required under suitable use as setting the cartridge on the printer.
8.2.1.2. Hand protection Not required under suitable use as setting the cartridge on the printer.
8.2.1.3 Eye protection Not required under suitable use as setting the cartridge on the printer.
Not required under suitable use as setting the cartridge on the printer.
8.2.1.4 Skin protection
Not established
8.2.2 Environmental exposure control
2/4
ESL3-MG
August 11 , 2005
9. Physical and Chemical Properties of Ink Formulation
9.1 General information
Appearance Magenta Liquid
Odor: Slightly
9.2 Important health, safety and environmental information
pH: Not applicable
Boiling point: No data available
Melting point: No data available
Flash point: about 71 deg.C (closed cup)
Autoflammability: None
Explosive properties: 1.4-6.9v/v% as Gamma-butyrolactone
Oxidizing properties: None
Vapor density: Greater than 1 (air=1)
Relative density: No data available
Solubility in water: Soluble
Solubility in fat: No data available
Partition coefficient: No data available
Viscosity: No data available
9.3 Other information Not specified
10. Stability and Reactivity
Stability: Stable under normal temperature
Hazardous polymerization: No data available
10.1 Conditions to avoid: High and freezing temperatures
10.2 Materials to avoid: Oxidizers and explosives
10.3 Hazardous decomposition products: No data available
11. Toxicology and Health Hazards
*Based on toxicology data of chemically similar material
Routes Of Overexposure: Eye, skin, inhalation, and oral
Acute Health Hazards:
- Overexposure of eye surface to ink may be mildly irritating
- Overexposure of skin to ink contact may cause irritation and in some people swelling and redness
- Intentional inhalation overexposure to ink vapors may result in respiratory tract irritation and anesthesia
- Intentional or accidental oral ingestion may cause an upset stomach
Chronic Health Hazards: None Known
Mugtagenicity: Negative (by Ames Test)*
Carcinogenicity: Not contain any substances listed in IARC Monogrhaphs(1,2A and 2B)
Toxicity Data: Oral LD50 Dermal LD50 Inhalant LC50
>2500mg/kg(Rat)* >2000mg/kg(Rat)* No data available
3/4
ESL3-MG
August 11 , 2005
Eye irritating: Moderate irritant (Rabbit, OECD405)*
Skin irritating: Mild irritant (Rabbit, OECD404)*
Skin sensitizing: Non-sensitizer (LLNA, OECD429)*
12. Ecological Information
12.1 Ecotoxicity: No data available on the adverse effects of this ink on the environment
12.2 Mobility: No data available on the adverse effects of this ink on the environment
12.3 Persistence and degradability: No data available on the adverse effects of this ink on the environment
12.4 Bioaccumulative potential: No data available on the adverse effects of this ink on the environment
12.5 Other adverse effects: No data available
13. Disposal Considerations
Disposal should be in accordance with federal, state, and local requirement.
14. Transportation Information
UN Class/UN Number: Not applicable
15. Regulatory Considerations
US Regulation:
TSCA Section 4(a) Final Test Rules Regulated Not regulated
TSCA Section 8(a) Preliminary Assessment Information Rule (PAIR) Not regulated
TSCA Section 8(a) Inventory Update Rule Not regulated
TSCA Section 12(b) One-Time Export Notification Regulated Not regulated
California Proposition 65 Not regulated
EU Information
Symbols and indication according to 1999/45/EC: This ink does not meet the criteria for classification
as dangerous.
16. Other Information
This "Material Safety Data Sheet" contains health, safety, and environmental information. It does not replace any
precautionary language or use and disposal information which accompanies the product. The information contained
herein is believed to be accurate at the time of precaution, but should only be used as a guide. It is subject to
revision from time to time. Roland DG does not warrant the completeness or accuracy of the information contained
herein.
4/4
ESL3-YE
August 11 , 2005
Material Safety Data Sheet
1. Article and Corporate Identification
1.1. Product:
ECO-SOL MAX, ESL3-YE
1.2. Manufacturer/Distributor:
Manufacture's name: Roland DG Corporation
Address: 1-6-4 Shinmiyakoda Hamamatsu-shi
Shizuoka 431-2103
JAPAN
Phone: + 81-53-484-1224
Fax: + 81-53-484-1221
1.3. Medical Emergency Number
Not Available
2. Composition Information
This is a solvent ink formulation
Ink Composition CAS No. % By Weight
Proprietary pigment - 1-5
- 1-5
Synthetic polymer
112-36-7 55-65
Diethylene glycol diethyl ether
96-48-0 10-20
Gamma-butyrolactone
143-24-8 10-20
Tetraethylene glycol, dimethyl ether
1559-34-8 1-5
Tetraethylene glycol, monobutyl ether
- 1-5
Additives
3. Hazard Identification
3.1 Emergency Overview:
Ink component is a yellow liquid that causes eye, nose or throat irritation, and that effects anesthesia, if inhales. Ink
may flash, when under high temperature. Avoid contact with eyes or clothing. In the case of skin contact, wash
with soap and water. Keep out of reach of children.
3.2 Potential Health Effects:
Eyes: Ink contact with eye will be the risk of serious damage. See Section 11 for Toxicology.
Skin: Ink contact with skin may cause minimally irritation. See Section 11 for Toxicology.
Inhalation: Intentional exposure to ink vapors (mist) will cause respiratory irritation and anesthesia. See
Section 11 for Toxicology.
Ingestion: May cause upset stomach. See Section 11 for Toxicology.
1/4
ESL3-YE
August 11 , 2005
4. First Aid Measures
4.1 Eyes: Immediately flush with room temperature, low pressure, clean water for at least 15 minutes.
Seek medical attention if eye irritation continues.
4.2 Skin: Wash surface areas with soap and water. Wash soiled clothing before rewearing. Consult a
physician if irritation continues.
4.3 Inhalation: Remove subject to ventilated fresh air. If not breathing, give artificial respiration right away.
If breathing is difficult, give oxygen. Seek immediate medical attention.
4.4 Ingestion: Seek medical advice; and attention if stomach continues to be upset.
5. Fire Fighting Measures
5.1 Flammability: Combustible liquid under Hazard Communication Standard (HCS, U.S.A)
See Section 9 for Flash Point.
5.2 Extinguishing Media: Water spray, dry chemical, carbon dioxide or alcohol foam
5.3 Fire Fighting Instructions: Extinguish to use fire fighting media or plentiful fog water. Put protection
wear without fail in case of fire fighting work; do not work in the leeward.
6. Accidental Release Measures
Remove the person of the leeward. Keep away the person from periphery of
6.1 Personal protections:
the place of the leakage. Ventilate sufficiently during clean-up in case of
inside of a house.
If a spill occurs, use sponges to wipe-up ink, then rinse area with damp cloth.
6.2 Methods for cleaning up:
Place waste in closed container for disposal. Do not dispose of waste to the
sewer. Wash hands with soap and water.
7. Precautions for Safe Handling and Use
Use proper ventilation and no fire in work place. Put protection wear that has
7.1 Handling:
electrical conductivity in case of work. Keep out of reach of children and do
not drink ink. Do not dismantle cartridge. Make sure cartridge is dry before
insertion into printer housing.
7.2 Storage: Do not store the cartridges in high or freezing temperatures. Keep cartridge
out of direct sunlight. Do not store cartridges with oxidizing agents or
explosives.
7.3 Specific use(s): Not specified
8. Exposure Controls and Personal Protection
8.1 Engineering controls: Proper ventilation
8.2 Exposure controls:
8.2.1 Occupational exposure control Not established
8.2.1.1 Respiratory protection Not required under suitable use as setting the cartridge on the printer.
8.2.1.2. Hand protection Not required under suitable use as setting the cartridge on the printer.
8.2.1.3 Eye protection Not required under suitable use as setting the cartridge on the printer.
Not required under suitable use as setting the cartridge on the printer.
8.2.1.4 Skin protection
Not established
8.2.2 Environmental exposure control
2/4
ESL3-YE
August 11 , 2005
9. Physical and Chemical Properties of Ink Formulation
9.1 General information
Appearance Yellow Liquid
Odor: Slightly
9.2 Important health, safety and environmental information
pH: Not applicable
Boiling point: No data available
Melting point: No data available
Flash point: about 71 deg.C (closed cup)
Autoflammability: None
Explosive properties: 1.4-6.9v/v% as Gamma-butyrolactone
Oxidizing properties: None
Vapor density: Greater than 1 (air=1)
Relative density: No data available
Solubility in water: Soluble
Solubility in fat: No data available
Partition coefficient: No data available
Viscosity: No data available
9.3 Other information Not specified
10. Stability and Reactivity
Stability: Stable under normal temperature
Hazardous polymerization: No data available
10.1 Conditions to avoid: High and freezing temperatures
10.2 Materials to avoid: Oxidizers and explosives
10.3 Hazardous decomposition products: No data available
11. Toxicology and Health Hazards
*Based on toxicology data of chemically similar material
Routes Of Overexposure: Eye, skin, inhalation, and oral
Acute Health Hazards:
- Overexposure of eye surface to ink may be mildly irritating
- Overexposure of skin to ink contact may cause irritation and in some people swelling and redness
- Intentional inhalation overexposure to ink vapors may result in respiratory tract irritation and anesthesia
- Intentional or accidental oral ingestion may cause an upset stomach
Chronic Health Hazards: None Known
Mugtagenicity: Negative (by Ames Test)*
Carcinogenicity: Contains Nickel compounds
IARC: Group 1
NTP: Known to be human carcinogen
Pro.65: Known to cause cancer
Toxicity Data: Oral LD50 Dermal LD50 Inhalant LC50
>2500mg/kg(Rat)* >2000mg/kg(Rat)* No data available
3/4
ESL3-YE
August 11 , 2005
Eye irritating: Moderate irritant (Rabbit, OECD405)*
However, risk of serious damage to eyes
Skin irritating: Mild irritant (Rabbit, OECD404)*
Skin sensitizing: Non-sensitizer (LLNA, OECD429)*
12. Ecological Information
12.1 Ecotoxicity: No data available on the adverse effects of this ink on the environment
12.2 Mobility: No data available on the adverse effects of this ink on the environment
12.3 Persistence and degradability: No data available on the adverse effects of this ink on the environment
12.4 Bioaccumulative potential: No data available on the adverse effects of this ink on the environment
12.5 Other adverse effects: No data available
13. Disposal Considerations
Disposal should be in accordance with federal, state, and local requirement.
14. Transportation Information
UN Class/UN Number: Not applicable
15. Regulatory Considerations
US Regulation:
TSCA Section 4(a) Final Test Rules Regulated Not regulated
TSCA Section 8(a) Preliminary Assessment Information Rule (PAIR) Not regulated
TSCA Section 8(a) Inventory Update Rule Not regulated
TSCA Section 12(b) One-Time Export Notification Regulated Not regulated
California Proposition 65 Regulated as follows
"WARNING: This product contains a chemical known to the State of
Wording of Risk and Safety Phrase:
California to cause cancer"
EU Information
Symbols and indication according to 1999/45/EC:
Wording of Risk and Safety Phrase: Xi Irritant
R41: Risk of serious damage to eyes.
S25: Avoid contact to eyes.
S26: In case of contact with eyes, rinse immediately with plenty water and seek medical advice.
R39: Ware eye/face protection
16. Other Information
This "Material Safety Data Sheet" contains health, safety, and environmental information. It does not replace any
precautionary language or use and disposal information which accompanies the product. The information contained
herein is believed to be accurate at the time of precaution, but should only be used as a guide. It is subject to
revision from time to time. Roland DG does not warrant the completeness or accuracy of the information contained
herein.
4/4
ESL3-LC
August 11 , 2005
Material Safety Data Sheet
1. Article and Corporate Identification
1.1. Product:
ECO-SOL MAX, ESL3-LC
1.2. Manufacturer/Distributor:
Manufacture's name: Roland DG Corporation
Address: 1-6-4 Shinmiyakoda Hamamatsu-shi
Shizuoka 431-2103
JAPAN
Phone: + 81-53-484-1224
Fax: + 81-53-484-1221
1.3. Medical Emergency Number
Not Available
2. Composition Information
This is a solvent ink formulation
Ink Composition CAS No. % By Weight
Proprietary pigment - <1
- 1-5
Synthetic polymer
112-36-7 55-70
Diethylene glycol diethyl ether
96-48-0 10-20
Gamma-butyrolactone
143-24-8 10-20
Tetraethylene glycol, dimethyl ether
1559-34-8 1-5
Tetraethylene glycol, monobutyl ether
- <1
Additives
3. Hazard Identification
3.1 Emergency Overview:
Ink component is a cyan liquid that causes eye, nose or throat irritation, and that effects anesthesia, if inhales. Ink
may flash, when under high temperature. Avoid contact with eyes or clothing. In the case of skin contact, wash
with soap and water. Keep out of reach of children.
3.2 Potential Health Effects:
Eyes: Ink contact with eye will be irritating. See Section 11 for Toxicology.
Skin: Ink contact with skin may cause minimally irritation. See Section 11 for Toxicology.
Inhalation: Intentional exposure to ink vapors (mist) will cause respiratory irritation and anesthesia. See
Section 11 for Toxicology.
Ingestion: May cause upset stomach. See Section 11 for Toxicology.
4. First Aid Measures
4.1 Eyes: Immediately flush with room temperature, low pressure, clean water for at least 15 minutes.
Seek medical attention if eye irritation continues.
4.2 Skin: Wash surface areas with soap and water. Wash soiled clothing before rewearing. Consult a
physician if irritation continues.
1/4
ESL3-LC
August 11 , 2005
4.3 Inhalation: Remove subject to ventilated fresh air. If not breathing, give artificial respiration right away.
If breathing is difficult, give oxygen. Seek immediate medical attention.
4.4 Ingestion: Seek medical advice; and attention if stomach continues to be upset.
5. Fire Fighting Measures
5.1 Flammability: Combustible liquid under Hazard Communication Standard (HCS, U.S.A)
See Section 9 for Flash Point.
5.2 Extinguishing Media: Water spray, dry chemical, carbon dioxide or alcohol foam
5.3 Fire Fighting Instructions: Extinguish to use fire fighting media or plentiful fog water. Put protection
wear without fail in case of fire fighting work; do not work in the leeward.
6. Accidental Release Measures
Remove the person of the leeward. Keep away the person from periphery of
6.1 Personal protections:
the place of the leakage. Ventilate sufficiently during clean-up in case of
inside of a house.
If a spill occurs, use sponges to wipe-up ink, then rinse area with damp cloth.
6.2 Methods for cleaning up:
Place waste in closed container for disposal. Do not dispose of waste to the
sewer. Wash hands with soap and water.
7. Precautions for Safe Handling and Use
Use proper ventilation and no fire in work place. Put protection wear that has
7.1 Handling:
electrical conductivity in case of work. Keep out of reach of children and do
not drink ink. Do not dismantle cartridge. Make sure cartridge is dry before
insertion into printer housing.
7.2 Storage: Do not store the cartridges in high or freezing temperatures. Keep cartridge
out of direct sunlight. Do not store cartridges with oxidizing agents or
explosives.
7.3 Specific use(s): Not specified
8. Exposure Controls and Personal Protection
8.1 Engineering controls: Proper ventilation
8.2 Exposure controls:
8.2.1 Occupational exposure control Not established
8.2.1.1 Respiratory protection Not required under suitable use as setting the cartridge on the printer.
8.2.1.2. Hand protection Not required under suitable use as setting the cartridge on the printer.
8.2.1.3 Eye protection Not required under suitable use as setting the cartridge on the printer.
Not required under suitable use as setting the cartridge on the printer.
8.2.1.4 Skin protection
Not established
8.2.2 Environmental exposure control
2/4
ESL3-LC
August 11 , 2005
9. Physical and Chemical Properties of Ink Formulation
9.1 General information
Appearance Cyan Liquid
Odor: Slightly
9.2 Important health, safety and environmental information
pH: Not applicable
Boiling point: No data available
Melting point: No data available
Flash point: about 71 deg.C (closed cup)
Autoflammability: None
Explosive properties: 1.4-6.9v/v% as Gamma-butyrolactone
Oxidizing properties: None
Vapor density: Greater than 1 (air=1)
Relative density: No data available
Solubility in water: Soluble
Solubility in fat: No data available
Partition coefficient: No data available
Viscosity: No data available
9.3 Other information Not specified
10. Stability and Reactivity
Stability: Stable under normal temperature
Hazardous polymerization: No data available
10.1 Conditions to avoid: High and freezing temperatures
10.2 Materials to avoid: Oxidizers and explosives
10.3 Hazardous decomposition products: No data available
11. Toxicology and Health Hazards
*Based on toxicology data of chemically similar material
Routes Of Overexposure: Eye, skin, inhalation, and oral
Acute Health Hazards:
- Overexposure of eye surface to ink may be mildly irritating
- Overexposure of skin to ink contact may cause irritation and in some people swelling and redness
- Intentional inhalation overexposure to ink vapors may result in respiratory tract irritation and anesthesia
- Intentional or accidental oral ingestion may cause an upset stomach
Chronic Health Hazards: None Known
Mugtagenicity: Negative (by Ames Test)*
Carcinogenicity: Not contain any substances listed in IARC Monogrhaphs(1,2A and 2B)
Toxicity Data: Oral LD50 Dermal LD50 Inhalant LC50
>2500mg/kg(Rat)* >2000mg/kg(Rat)* No data available
3/4
ESL3-LC
August 11 , 2005
Eye irritating: Moderate irritant (Rabbit, OECD405)*
Skin irritating: Mild irritant (Rabbit, OECD404)*
Skin sensitizing: Non-sensitizer (LLNA, OECD429)*
12. Ecological Information
12.1 Ecotoxicity: No data available on the adverse effects of this ink on the environment
12.2 Mobility: No data available on the adverse effects of this ink on the environment
12.3 Persistence and degradability: No data available on the adverse effects of this ink on the environment
12.4 Bioaccumulative potential: No data available on the adverse effects of this ink on the environment
12.5 Other adverse effects: No data available
13. Disposal Considerations
Disposal should be in accordance with federal, state, and local requirement.
14. Transportation Information
UN Class/UN Number: Not applicable
15. Regulatory Considerations
US Regulation:
TSCA Section 4(a) Final Test Rules Regulated Not regulated
TSCA Section 8(a) Preliminary Assessment Information Rule (PAIR) Not regulated
TSCA Section 8(a) Inventory Update Rule Not regulated
TSCA Section 12(b) One-Time Export Notification Regulated Not regulated
California Proposition 65 Not regulated
EU Information
Symbols and indication according to 1999/45/EC:
Wording of Risk and Safety Phrase: Xi Irritant
R36: Irritant to eyes
S25: Avoid contact to eyes.
S26: In case of contact with eyes, rinse immediately with plenty water and seek medical advice.
16. Other Information
This "Material Safety Data Sheet" contains health, safety, and environmental information. It does not replace any
precautionary language or use and disposal information which accompanies the product. The information contained
herein is believed to be accurate at the time of precaution, but should only be used as a guide. It is subject to
revision from time to time. Roland DG does not warrant the completeness or accuracy of the information contained
herein.
4/4
ESL3-LM
August 11 , 2005
Material Safety Data Sheet
1. Article and Corporate Identification
1.1. Product:
ECO-SOL MAX, ESL3-LM
1.2. Manufacturer/Distributor:
Manufacture's name: Roland DG Corporation
Address: 1-6-4 Shinmiyakoda Hamamatsu-shi
Shizuoka 431-2103
JAPAN
Phone: + 81-53-484-1224
Fax: + 81-53-484-1221
1.3. Medical Emergency Number
Not Available
2. Composition Information
This is a solvent ink formulation
Ink Composition CAS No. % By Weight
Proprietary pigment - <1
- 1-5
Synthetic polymer
112-36-7 55-70
Diethylene glycol diethyl ether
96-48-0 10-20
Gamma-butyrolactone
143-24-8 10-20
Tetraethylene glycol, dimethyl ether
1559-34-8 1-5
Tetraethylene glycol, monobutyl ether
- <1
Additives
3. Hazard Identification
3.1 Emergency Overview:
Ink component is a magenta liquid that causes eye, nose or throat irritation, and that effects anesthesia, if inhales.
Ink may flash, when under high temperature. Avoid contact with eyes or clothing. In the case of skin contact, wash
with soap and water. Keep out of reach of children.
3.2 Potential Health Effects:
Eyes: Ink contact with eye will be irritating. See Section 11 for Toxicology.
Skin: Ink contact with skin may cause minimally irritation. See Section 11 for Toxicology.
Inhalation: Intentional exposure to ink vapors (mist) will cause respiratory irritation and anesthesia. See
Section 11 for Toxicology.
Ingestion: May cause upset stomach. See Section 11 for Toxicology.
1/4
ESL3-LM
August 11 , 2005
4. First Aid Measures
4.1 Eyes: Immediately flush with room temperature, low pressure, clean water for at least 15 minutes.
Seek medical attention if eye irritation continues.
4.2 Skin: Wash surface areas with soap and water. Wash soiled clothing before rewearing. Consult a
physician if irritation continues.
4.3 Inhalation: Remove subject to ventilated fresh air. If not breathing, give artificial respiration right away.
If breathing is difficult, give oxygen. Seek immediate medical attention.
4.4 Ingestion: Seek medical advice; and attention if stomach continues to be upset.
5. Fire Fighting Measures
5.1 Flammability: Combustible liquid under Hazard Communication Standard (HCS, U.S.A)
See Section 9 for Flash Point.
5.2 Extinguishing Media: Water spray, dry chemical, carbon dioxide or alcohol foam
5.3 Fire Fighting Instructions: Extinguish to use fire fighting media or plentiful fog water. Put protection
wear without fail in case of fire fighting work; do not work in the leeward.
6. Accidental Release Measures
Remove the person of the leeward. Keep away the person from periphery of
6.1 Personal protections:
the place of the leakage. Ventilate sufficiently during clean-up in case of
inside of a house.
If a spill occurs, use sponges to wipe-up ink, then rinse area with damp cloth.
6.2 Methods for cleaning up:
Place waste in closed container for disposal. Do not dispose of waste to the
sewer. Wash hands with soap and water.
7. Precautions for Safe Handling and Use
Use proper ventilation and no fire in work place. Put protection wear that has
7.1 Handling:
electrical conductivity in case of work. Keep out of reach of children and do
not drink ink. Do not dismantle cartridge. Make sure cartridge is dry before
insertion into printer housing.
7.2 Storage: Do not store the cartridges in high or freezing temperatures. Keep cartridge
out of direct sunlight. Do not store cartridges with oxidizing agents or
explosives.
7.3 Specific use(s): Not specified
8. Exposure Controls and Personal Protection
8.1 Engineering controls: Proper ventilation
8.2 Exposure controls:
8.2.1 Occupational exposure control Not established
8.2.1.1 Respiratory protection Not required under suitable use as setting the cartridge on the printer.
8.2.1.2. Hand protection Not required under suitable use as setting the cartridge on the printer.
8.2.1.3 Eye protection Not required under suitable use as setting the cartridge on the printer.
Not required under suitable use as setting the cartridge on the printer.
8.2.1.4 Skin protection
Not established
8.2.2 Environmental exposure control
2/4
ESL3-LM
August 11 , 2005
9. Physical and Chemical Properties of Ink Formulation
9.1 General information
Appearance Magenta Liquid
Odor: Slightly
9.2 Important health, safety and environmental information
pH: Not applicable
Boiling point: No data available
Melting point: No data available
Flash point: about 71 deg.C (closed cup)
Autoflammability: None
Explosive properties: 1.4-6.9v/v% as Gamma-butyrolactone
Oxidizing properties: None
Vapor density: Greater than 1 (air=1)
Relative density: No data available
Solubility in water: Soluble
Solubility in fat: No data available
Partition coefficient: No data available
Viscosity: No data available
9.3 Other information Not specified
10. Stability and Reactivity
Stability: Stable under normal temperature
Hazardous polymerization: No data available
10.1 Conditions to avoid: High and freezing temperatures
10.2 Materials to avoid: Oxidizers and explosives
10.3 Hazardous decomposition products: No data available
11. Toxicology and Health Hazards
*Based on toxicology data of chemically similar material
Routes Of Overexposure: Eye, skin, inhalation, and oral
Acute Health Hazards:
- Overexposure of eye surface to ink may be mildly irritating
- Overexposure of skin to ink contact may cause irritation and in some people swelling and redness
- Intentional inhalation overexposure to ink vapors may result in respiratory tract irritation and anesthesia
- Intentional or accidental oral ingestion may cause an upset stomach
Chronic Health Hazards: None Known
Mugtagenicity: Negative (by Ames Test)*
Carcinogenicity: Not contain any substances listed in IARC Monogrhaphs(1,2A and 2B)
Toxicity Data: Oral LD50 Dermal LD50 Inhalant LC50
>2500mg/kg(Rat)* >2000mg/kg(Rat)* No data available
3/4
ESL3-LM
August 11 , 2005
Eye irritating: Moderate irritant (Rabbit, OECD405)*
Skin irritating: Mild irritant (Rabbit, OECD404)*
Skin sensitizing: Non-sensitizer (LLNA, OECD429)*
12. Ecological Information
12.1 Ecotoxicity: No data available on the adverse effects of this ink on the environment
12.2 Mobility: No data available on the adverse effects of this ink on the environment
12.3 Persistence and degradability: No data available on the adverse effects of this ink on the environment
12.4 Bioaccumulative potential: No data available on the adverse effects of this ink on the environment
12.5 Other adverse effects: No data available
13. Disposal Considerations
Disposal should be in accordance with federal, state, and local requirement.
14. Transportation Information
UN Class/UN Number: Not applicable
15. Regulatory Considerations
US Regulation:
TSCA Section 4(a) Final Test Rules Regulated Dipropylene glycol monomethyl ether
TSCA Section 8(a) Preliminary Assessment Information Rule (PAIR) Dipropylene glycol monomethyl ether
TSCA Section 8(a) Inventory Update Rule Dipropylene glycol monomethyl ether
TSCA Section 12(b) One-Time Export Notification Regulated Dipropylene glycol monomethyl ether
California Proposition 65 Not regulated
EU Information
Symbols and indication according to 1999/45/EC: This ink does not meet the criteria for classification
as dangerous.
16. Other Information
This "Material Safety Data Sheet" contains health, safety, and environmental information. It does not replace any
precautionary language or use and disposal information which accompanies the product. The information contained
herein is believed to be accurate at the time of precaution, but should only be used as a guide. It is subject to
revision from time to time. Roland DG does not warrant the completeness or accuracy of the information contained
herein.
4/4
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