SAFETY DATA SHEET
REG_EUADD0
Product: DUPONT MARINE FINISHES IMRON TOPGLOSS
Print Date: 28.09.2005 Version: 1.0 Revision Date: 28/09/2005 Page: 1/6
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of the substance or preparation
- Commercial Product Name: DUPONT MARINE FINISHES IMRON TOPGLOSS
- Intended use of the substance/preparation: Coating for professional use
Manufacturer, importer, supplier
- Producer/Supplier: Du Pont de Nemours (Belgium)
- Street/Box: A. Spinoystraat 6
- Nat.-Code/Postal code/City: B-2800 MECHELEN
- Telephone: +32-(0)15-44.10.11
- Responsible Department: Regulatory Affairs
- Telephone: ++49 (0)202 529 2571
- Emergency telephone: ++44 (0)8456 06640
__________________________________________________________________________________________
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical characterization of the product
- Hazardous components:
Substances presenting a health or environmental hazard within the meaning of the DSD 67/548/EEC incl.
29. ATP
EINECS-No. CAS-No. Chemical Name Concentration Classification
215-535-7 1330-20-7 xylene 20,00 - < 25,00 % R10
Xn; R20/21
Xi; R38
259-370-1 54839-24-6 ethoxypropyl acetate 7,00 - < 10,00 % R10
R67
203-603-9 108-65-6 2-methoxy-1-methylethyl acetate 5,00 - < 7,00 % R10
Xi; R36
202-849-4 100-41-4 ethylbenzene 5,00 - < 7,00 % F; R11
Xn; R20
204-658-1 123-86-4 n-butyl acetate 3,00 - < 5,00 % R10
R66
R67
265-199-0 64742-95-6 solvent naphtha (petroleum), light arom. 1,00 - < 2,00 % R10
Xi; R37
Xn; R65
R66
R67
N; R51/53
; Nota H, Nota P
202-436-9 95-63-6 1,2,4-trimethylbenzene 1,00 - < 2,00 % R10
Xn; R20
Xi; R36/37/38
N; R51/53
203-604-4 108-67-8 mesitylene 0,20 - < 0,25 % R10
Xi; R37
N; R51/53
212-454-9 818-61-1 2-hydroxyethyl acrylate 0,10 - < 0,20 % T; R24
C; R34
R43
N; R50
; Nota D
203-132-9 103-65-1 n-propylbenzene 0,10 - < 0,20 % R10
Xn; R65
Xi; R37
N; R51/53
SBV: SDS_EU_2003_V14.0
SAFETY DATA SHEET
REG_EUADD0
Product: DUPONT MARINE FINISHES IMRON TOPGLOSS
Print Date: 28.09.2005 Version: 1.0 Revision Date: 28/09/2005 Page: 2/6
- Additional advice:
See full text of R-phrases in chapter 16.
__________________________________________________________________________________________
3. HAZARDS IDENTIFICATION
The product is classified as dangerous in accordance with Directive 1999/45/EC.
- Human health hazards:
Classification : - flammable - harmful - irritant - dangerous for the environment
Flammable. Harmful by inhalation and in contact with skin. Irritating to skin. Harmful to aquatic
organisms, may cause long-term adverse effects in the aquatic environment.
__________________________________________________________________________________________
4. FIRST AID MEASURES
- General advice:
When symptoms persist or in all cases of doubt seek medical advice. Never give anything by mouth to an
unconscious person.
- Inhalation:
Remove to fresh air. Keep patient warm and at rest. If breathing is irregular or stopped, administer
artificial respiration. If unconscious place in recovery position and seek medical advice.
- Skin contact:
Do NOT use solvents or thinners. Take off all contaminated clothing immediately. Wash skin thoroughly
with soap and water or use recognized skin cleanser.
- Eye contact:
Remove contact lenses. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the
eyelids apart. Seek medical advice.
- Ingestion:
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do not induce vomiting.
__________________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
- Suitable extinguishing media:
alcohol-resistant foam, carbon dioxide (CO2), dry powder, water spray
- Extinguishing media which must not be used for safety reasons:
high volume water jet
- Special exposure hazards from the product itself, combustion products, resulting arising gases:
Fire will produce dense black smoke containing hazardous combustion products (see heading 10).
Exposure to decomposition products may be a hazard to health.
- Special protective equipment for fire-fighters:
Respiratory protective device may be required.
- Additional advice:
Cool closed containers exposed to fire with water spray.
__________________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
- Personal precautions:
Keep away from sources of ignition. Comply with safety directives (see chapters 7 and 8). Air out the
room. Do not inhale vapours.
- Environmental precautions:
Do not let product enter drains. Notify the respective authorities in accordance with local law in the case
of contamination of rivers, lakes or waste water systems.
- Methods for cleaning up:
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations. Clean preferably
with a detergent; avoid use of solvents.
__________________________________________________________________________________________
7. HANDLING AND STORAGE
Handling
- Safe handling advice:
Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour
concentration higher than the occupational exposure limits. The product should only be used in areas from
which all naked lights and other sources of ignition have been excluded. Preparation may charge
electrostatically: always use grounded leads when transferring from one container to another. Operators
should wear antistatic footwear and clothing. No sparking tools should be used. Avoid skin and eye
contact. Do not breathe vapours or spray mist. Smoking, eating and drinking should be prohibited in the
SBV: SDS_EU_2003_V14.0
application area. For personal protection see section 8. Comply with the health and safety at work laws.
When operators, whether spraying or not, have to work inside the spraybooth, ventilation is unlikely to be
sufficient to control particulates and solvent vapour in all cases. Particularly for spray mist the sustained
certain compliance with the limitation on respirable dust is improbable. Particularly for spray mist
SAFETY DATA SHEET
REG_EUADD0
Product: DUPONT MARINE FINISHES IMRON TOPGLOSS
Print Date: 28.09.2005 Version: 1.0 Revision Date: 28/09/2005 Page: 3/6
compliance with the limitation on respirable dust is improbable.
- Advice on protection against fire and explosion:
Solvent vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures
with air.
Storage
- Requirements for storage areas and containers:
Keep containers tightly closed. Never use pressure to empty container: container is not a pressure vessel.
No smoking. Prevent unauthorized access. Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
- Advice on common storage:
Keep away from oxidising agents and strongly acid or alkaline materials.
- Additional information on storage conditions:
Always keep in containers of same material as the original one. Observe label precautions. Place away
from sources of heat and direct sunlight. Keep away from sources of ignition.
__________________________________________________________________________________________
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Additional technical information on the plant
Provide adequate ventilation. This should be achieved by a good general extraction and -if practically
feasible- by the use of a local exhaust ventilation. If these are not sufficient to maintain concentrations of
particulates and solvent vapour below the OEL, suitable respiratory protection must be worn.
Exposure limit values
1
CAS-No. Chemical Name Type Value Note
1330-20-7 xylene STEL 150,00 ml/m3
TWA 100,00 ml/m3
100-41-4 ethylbenzene STEL 125,00 ml/m3
TWA 100,00 ml/m3
123-86-4 n-butyl acetate TWA 150,00 ml/m3
STEL 200,00 ml/m3
95-63-6 1,2,4-trimethylbenzene STEL 25,00 ml/m3
108-67-8 mesitylene STEL 25,00 ml/m3
- Additional advice:
(A.C.G.I.H. Treshold Limit Values) 2003.
Exposure controls
- Respiratory protection:
When workers are facing concentrations above the exposure limit they must use appropriate certified
respirators.
- Hand :
Glove material Glove thickness Break through time
xylene nitrile rubber 0,33 mm 30 minute
Viton 0,7 mm 480 minute
n-butyl acetate nitrile rubber 0,33 mm 30 minute
Viton 0,7 mm 10 minute
solvent naphtha (petroleum), light arom. Viton 0,7 mm 30 minute
The protective glove should be checked in each case for its workstation-specific suitability (e.g.
mechanical stability, product compatibility, anti-statics). When the intended use is for spray application a
nitrile glove of the chemical resistance group 3 (e.g. Dermatril庐 glove) is to be used. After contamination,
the glove has to be changed. If immersing the hands into the product is not avoidable (e.g. maintenance
work) a butyl or fluorocarbon rubber glove should be used. When skin exposure may occur to materials
specified in chapter 2 of this SDS, advice should be sought from the glove supplier as to appropriate type
to use with this product and the permeation breakthrough times. Cleaning solvents or viscosity adjustment
thinners require special hand protection, a fluorocarbon rubber glove should be used. Solvents are to be
used only for adjusting the viscosity. Care should be taken when working with sharp edged articles as
SBV: SDS_EU_2003_V14.0
1
Note:
H: Skin resorbtive
Y: There is no need to fear risk of fetal damage if complying with the MWC and the BWST values.
SAFETY DATA SHEET
REG_EUADD0
Product: DUPONT MARINE FINISHES IMRON TOPGLOSS
Print Date: 28.09.2005 Version: 1.0 Revision Date: 28/09/2005 Page: 4/6
these can easily damage the gloves and make them ineffective. The instructions and information provided
by the glove supplier on use, storage, maintenance and replacement must be followed. Damaged gloves or
those showing signs of wear should be replaced immediately. Preventive skin protection such as skin
protective cream is recommended. Work tasks should be arranged in such a way that gloves do not have to
be worn continuously.
- Eye protection:
Wear protective eyewear for protection against solvent spatter.
- Skin protection:
Personnel should wear antistatic clothings made of natural fiber or of high temperature resistant synthetic
fiber.
- Protective measures / Hygiene measures:
Wash skin thoroughly with soap and water or use recognized skin cleanser. Do not use organic solvents!
Environmental exposure controls
Do not let product enter drains.
For ecological information refer to chapter 12.
__________________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
General information (appearance)
Physical state: liquid Colour: Various
Important health, safety and environmental information
Value Method
- Flash point: 23 掳C DIN 53213/ISO 1523
- Ignition temperature: 272 掳C DIN 51794
- Lower explosion limit (Vol.): 1,0 %(V)
- Upper explosion limit (Vol.): 8,2 %(V)
- Vapour pressure (20 掳C): 3,4 hPa
- Relative density (20 掳C): 0,95 - 1 g/cm3
- Water solubility: partly miscible
- Viscosity (23 掳C): < 40 s ISO 2431-1993 6,0 mm
- Solvent separation test: <3% ADR/RID
__________________________________________________________________________________________
10. STABILITY AND REACTIVITY
- Conditions to avoid:
Stable under recommended storage and handling conditions (see section 7).
- Materials to avoid:
Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid
exothermic reactions.
- Hazardous decomposition products:
When exposed to high temperatures may produce hazardous decomposition products such as carbon
monoxide and dioxide, smoke, oxides of nitrogen.
__________________________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Practical experience
- Further observations:
Exposure to component solvents vapours concentration in excess of the stated occupational exposure limit
may result in adverse health effect such as mucous membrane and respiratory system irritation and adverse
effect on kidney, liver and central nervous system.
Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme
cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in non-allergic contact dermatitis and absorption through the skin.
The liquid splashed in the eyes may cause irritation and reversible damage.
Through skin resorbtion, solvents can cause some of the effects described here.
General observations
There are no data available on the product itself. See sections 2 and 15 for details.
__________________________________________________________________________________________
12. ECOLOGICAL INFORMATION
- Acute toxicity aquatic invertebrates :
Daphnia 24 hour 72,8 mg/l EC50
SBV: SDS_EU_2003_V14.0
- Acute and extended toxicity of fishes :
Golden orfe 48 hour 71 mg/l LC50 DIN
38412
- Toxicity with aquatic plants :
SAFETY DATA SHEET
REG_EUADD0
Product: DUPONT MARINE FINISHES IMRON TOPGLOSS
Print Date: 28.09.2005 Version: 1.0 Revision Date: 28/09/2005 Page: 5/6
scenedesmus quadricauda 192 hour 21 mg/l EC50
- Toxicity with micro organisms :
Daphnia magna 18 hour 959 mg/l EC50 DIN
38412
Mobility
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Other adverse effects
The product contains an organic linked halogen. It may contribute to the AOX-value. The preparation was
evaluated in accordance with the conventional method of the preparation directive 1999/45/EG and not
classified as environmentally dangerous, but contains environmentally dangerous materials. For details see
sections 2 and 15.
Additional ecological information
There are no data available on the product itself. The product should not be allowed to enter drains or
watercourses. Do not let product enter drains.
__________________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Product
- Recommendation:
The conversion into energy disposal process is recommended. To the extent not possible only the
hazardous waste incineration is suitable.
Uncleaned packaging
- Recommendation:
Properly emptied containers are to be scrap processed or reconditioned. Improperly emptied containers are
considered hazardous waste (waste key number 150110).
__________________________________________________________________________________________
14. TRANSPORT INFORMATION
Transport only in accordance with the requirements of the Carriage of Dangerous Goods by Road and Rail
(Classification, Packaging and Labeling), ADR for road, RID for rail, IMDG for sea and ICAO/IATA for
air transport.
Land transport
ADR/RID :
- Class: 3
- UN-No: 1263
- Description of the goods: PAINT
- Packing group: III
- Release of danger:
Sea transport
IMDG:
- Class: 3
- UN-No: 1263
- Marine pollutant: NO
- Proper technical name: PAINT
- Packing group: III
- Release of danger:
Air transport
ICAO/IATA:
- Class: 3
- UN/ID No.: 1263
- Proper technical name: PAINT
- Packing group: III
- Release of danger:
__________________________________________________________________________________________
SBV: SDS_EU_2003_V14.0
15. REGULATORY INFORMATION
The product is labelled according to the Chemicals (Hazard Information and Packaging for Supply)
Regulations 2002 as amended (CHIP Regulations). The risk associated with the use of this product
must be assessed in accordance with the Control of Substances Hazardous to Health (COSHH)
SAFETY DATA SHEET
REG_EUADD0
Product: DUPONT MARINE FINISHES IMRON TOPGLOSS
Print Date: 28.09.2005 Version: 1.0 Revision Date: 28/09/2005 Page: 6/6
Regulations and the Dangerous Substances and Explosive Atmospheres Regulations.
- Symbol and indicating of hazard:
Xn Harmful
Contains: xylene
Contains 2-hydroxyethyl acrylate. May produce an allergic reaction.
- R-phrase(s):
R10 Flammable.
R20/21 Harmful by inhalation and in contact with skin.
R38 Irritating to skin.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
- S-phrase(s):
S23 Do not breathe vapour.
S24 Avoid contact with skin.
S36/37 Wear suitable protective clothing and gloves.
S46 If swallowed, seek medical advice immediately and show this container or label.
S51 Use only in well-ventilated areas.
S57 Use appropriate container to avoid environmental contamination.
S61 Avoid release to the environment. Refer to special instructions/safety data sheets.
- Other directives, limitations and prohibitory regulations:
Restricted to professional users.
________________________________________________________________________________________
16. OTHER INFORMATION
Full text of R phrases with no. appearing in section 2:
R10 Flammable.
R11 Highly flammable.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R24 Toxic in contact with skin.
R34 Causes burns.
R36 Irritating to eyes.
R36/37/38 Irritating to eyes, respiratory system and skin.
R37 Irritating to respiratory system.
R38 Irritating to skin.
R43 May cause sensitization by skin contact.
R50 Very toxic to aquatic organisms.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
Further information
The information of this SDS is based on the present state of our knowledge and meets the requirements of
EU and national laws. The user's working conditions however, are beyond our knowledge and control. The
product is not to be used for purposes other than those specified under section 1 without a written
permission. It remains the responsibility of the user to ensure that the necessary steps are taken to meet the
laws and regulations. The information given in this SDS is to describe the product only in terms of health
and safety requirements and should not, therefore, be construed as guaranteeing specific properties.
SBV: SDS_EU_2003_V14.0
|