HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 242 Vicinale Diketone/ Vicinale Dicetones; LCK 242 A; 1/2
Print date : 02.05.2008 Product code : LCK242-1 Page 1 of 5
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation
LCK 242 Vicinale Diketone/ Vicinale Dicetones; LCK 242 A; 1/2
Use of the substance/preparation
Water analysis
Company/undertaking identification
HACH LANGE GmbH
Company name :
Willst盲tterstr. 11
Street :
Place : D-40549 D眉sseldorf
+49 (0)211 5288-383
Telephone :
marion.ives@hach-lange.de
e-mail :
www.hach-lange.com
Internet :
Inquiry office : HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - United Kingdom
Tel. +44 (0) 161 872 1487
e-Mail: martin.butterfield@hach-lange.co.uk
HACH LANGE Ltd.
Unit 1, Chestnut Road Western Industrial Estate
Dublin 12 - Ireland
Tel. +353 (0)1 4602522
e-Mail: joseph.diver@hach-lange.ie
2. Hazards identification
Classification
Indications of danger : Irritant
R-phrases :
Irritating to eyes, respiratory system and skin.
3. Composition/information on ingredients
Chemical characterization ( preparation )
Hazardous components
CAS-No. Chemical name Quantity Classification
EC-No.
231-791-2 7732-18-5 Water > 85 %
231-595-7 hydrochloric acid ... % < 15 % C, Xi R34-37
Full text of each relevant R phrase can be found in heading 16.
4. First aid measures
General information
Take off all contaminated clothing immediately.
After inhalation
Move to fresh air.
After contact with skin
Wash off immediately with plenty of water.
If skin irritation persists, call a physician.
Revision no. : 1.00 GB - EN Revision date : 03.12.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 242 Vicinale Diketone/ Vicinale Dicetones; LCK 242 A; 1/2
Print date : 02.05.2008 Product code : LCK242-1 Page 2 of 5
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
After ingestion
Clean mouth with water and drink afterwards plenty of water.
Consult a physician.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. The product itself does not burn.
Special exposure hazards arising from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
7. Handling and storage
Handling
Advice on safe handling
Use only in well-ventilated areas.
Storage
Requirements for storage rooms and vessels
Keep in a dry, cool place.
8. Exposure controls/personal protection
Exposure limit values
Exposure limits (EH40)
CAS-No. Chemical name ml/m鲁 mg/m鲁 F/ml Category Origin
7647-01-0 Hydrogen chloride (gas and aerosol mists) 1 2 TWA (8 h) WEL
5 8 STEL (15 min) WEL
Exposure controls
Revision no. : 1.00 GB - EN Revision date : 03.12.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 242 Vicinale Diketone/ Vicinale Dicetones; LCK 242 A; 1/2
Print date : 02.05.2008 Product code : LCK242-1 Page 3 of 5
Protective and hygiene measures
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Wash hands before breaks and after work.
Hand protection
Use barrier skin cream.
Chemical resistant gloves made of butyl rubber or nitrile rubber category III according to EN 374. In
full contact: Gloves material: Viton, Layer thickness: 0.70 mm, Breakthrough time: >480 min. In
splash contact: Glove material: nitrile rubber, Layer thickness 0,20 mm, Breakthrough time: > 30 min
Eye protection
Safety glasses with side-shields
Skin protection
Remove and wash contaminated clothing before re-use.
9. Physical and chemical properties
General information
liquid
Physical state :
colourless
Colour :
odourless
Odour :
Important health, safety and environmental information
Test method
<1
pH-Value (at 20 掳C) :
Changes in the physical state
Flammability
not applicable
Solid :
not applicable
Gas :
not applicable
Lower explosion limits :
not applicable
Upper explosion limits :
Density (at 20 掳C) : 1,06 g/cm鲁
completely soluble
Water solubility :
(at 20 掳C)
10. Stability and reactivity
Conditions to avoid
No dangerous reaction known under conditions of normal use.
Materials to avoid
alkali metals
bases
Gives off hydrogen by reaction with metals.
Hazardous decomposition products
Hydrogen chloride gas
11. Toxicological information
Acute toxicity
No data is available on the product itself.
Specific effects in experiment on an animal
No data is available on the product itself.
Revision no. : 1.00 GB - EN Revision date : 03.12.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 242 Vicinale Diketone/ Vicinale Dicetones; LCK 242 A; 1/2
Print date : 02.05.2008 Product code : LCK242-1 Page 4 of 5
Corrosive and irritant effects
Inhalation of mist causes irritation of respiratory system.
Irritating to eyes.
Irritating to skin.
12. Ecological information
Ecotoxicity
No data is available on the product itself.
Do not flush into surface water or sanitary sewer system.
Acute Fish toxicity HCl > 25 mg/l
13. Disposal considerations
Advice on disposal
In accordance with local and national regulations.
Our local agencies will accept used cuvettes to ensure their proper disposal.
Waste disposal number of waste from residues/unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of contaminated packaging
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
3316
UN number :
9
ADR/RID class :
Warning plate
ADR/RID packing group : II
Description of the goods
Chemical kit
Inland waterways transport
Other applicable information (inland waterways transport)
Not tested
Marine transport
3316
UN number :
9
IMDG code :
--
Marine pollutant :
II
IMDG packing group :
F-A,S-P
EmS :
Revision no. : 1.00 GB - EN Revision date : 03.12.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 242 Vicinale Diketone/ Vicinale Dicetones; LCK 242 A; 1/2
Print date : 02.05.2008 Product code : LCK242-1 Page 5 of 5
Description of the goods
Chemical kit
Air transport
3316
UN/ID number :
9
ICAO/IATA-DGR :
II
ICAO packing group :
Description of the goods
Chemical kit
Further Information
This product forms part of a kit. Information in this section relates to the kit as a whole.
15. Regulatory information
Labelling
Xi - Irritant
Danger symbols :
Xi - Irritant
Hazardous component(s) to be indicated on label
hydrochloric acid ... %
R phrases
36/37/38 Irritating to eyes, respiratory system and skin.
S phrases
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
37/39 Wear suitable gloves and eye/face protection.
Additional advice on labelling
Classification according to European directive on classification of hazardous preparations
1999/45/EC.
National regulatory information
Water contaminating class (D) : 1 - slightly water contaminating
16. Other information
Full text of R-phrases referred to under sections 2 and 3
34 Causes burns.
36/37/38 Irritating to eyes, respiratory system and skin.
37 Irritating to respiratory system.
Further Information
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)
Revision no. : 1.00 GB - EN Revision date : 03.12.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 242 Vicinale Diketone/ Vicinale Dicetones; LCK 242 B; 2/2
Print date : 02.05.2008 Product code : LCK242-2 Page 1 of 6
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation
LCK 242 Vicinale Diketone/ Vicinale Dicetones; LCK 242 B; 2/2
Use of the substance/preparation
Water analysis
Company/undertaking identification
HACH LANGE GmbH
Company name :
Willst盲tterstr. 11
Street :
Place : D-40549 D眉sseldorf
+49 (0)211 5288-383
Telephone :
marion.ives@hach-lange.de
e-mail :
www.hach-lange.com
Internet :
Inquiry office : HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - United Kingdom
Tel. +44 (0) 161 872 1487
e-Mail: martin.butterfield@hach-lange.co.uk
HACH LANGE Ltd.
Unit 1, Chestnut Road Western Industrial Estate
Dublin 12 - Ireland
Tel. +353 (0)1 4602522
e-Mail: joseph.diver@hach-lange.ie
2. Hazards identification
Classification
Indications of danger : Toxic, Harmful, Irritant, Dangerous for the environment
R-phrases :
Toxic if swallowed.
Irritating to eyes.
Limited evidence of a carcinogenic effect.
May cause sensitization by skin contact.
Possible risks of irreversible effects.
Harmful by inhalation and in contact with skin.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
3. Composition/information on ingredients
Chemical characterization ( preparation )
Hazardous components
CAS-No. Chemical name Quantity Classification
EC-No.
210-418-7 615-28-1 o-phenylenediamine dihydrochloride < 80 % Carc. Cat. 3, Muta. Cat. 3, T, Xn, Xi,
N R40-68-25-20/21-36-43-50-53
Full text of each relevant R phrase can be found in heading 16.
4. First aid measures
General information
Take off all contaminated clothing immediately.
Revision no. : 1.00 GB - EN Revision date : 03.12.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 242 Vicinale Diketone/ Vicinale Dicetones; LCK 242 B; 2/2
Print date : 02.05.2008 Product code : LCK242-2 Page 2 of 6
After inhalation
Move to fresh air.
After contact with skin
Wash off immediately with plenty of water.
If skin irritation persists, call a physician.
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
After ingestion
Clean mouth with water and drink afterwards plenty of water.
Call a physician immediately.
Show this safety data sheet to the doctor in attendance.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. The product itself does not burn.
Special exposure hazards arising from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Sweep up or vacuum up spillage and collect in suitable container for disposal.
7. Handling and storage
Handling
Advice on safe handling
Use only in well-ventilated areas.
Storage
Requirements for storage rooms and vessels
Keep in a dry, cool place.
Further information on storage conditions
Keep locked up or in an area accessible only to qualified or authorised persons.
8. Exposure controls/personal protection
Exposure limit values
Revision no. : 1.00 GB - EN Revision date : 03.12.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 242 Vicinale Diketone/ Vicinale Dicetones; LCK 242 B; 2/2
Print date : 02.05.2008 Product code : LCK242-2 Page 3 of 6
Exposure controls
Protective and hygiene measures
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Wash hands before breaks and after work.
Hand protection
Use barrier skin cream.
Chemical resistant gloves made of butyl rubber or nitrile rubber category III according to EN 374. In
full contact: Gloves material: Viton, Layer thickness: 0.70 mm, Breakthrough time: >480 min. In
splash contact: Glove material: nitrile rubber, Layer thickness 0,20 mm, Breakthrough time: > 30 min
Eye protection
Safety glasses with side-shields
Skin protection
Remove and wash contaminated clothing before re-use.
9. Physical and chemical properties
General information
lyophilized cake
Physical state :
white
Colour :
odourless
Odour :
Important health, safety and environmental information
Test method
Changes in the physical state
Flammability
not applicable
Solid :
not applicable
Gas :
not applicable
Lower explosion limits :
not applicable
Upper explosion limits :
completely soluble
Water solubility :
(at 20 掳C)
10. Stability and reactivity
Conditions to avoid
No dangerous reaction known under conditions of normal use.
Materials to avoid
No dangerous reaction known under conditions of normal use.
Hazardous decomposition products
No decomposition if stored and applied as directed.
11. Toxicological information
Acute toxicity
No data is available on the product itself.
Specific effects in experiment on an animal
No data is available on the product itself.
Corrosive and irritant effects
Irritating to eyes.
Irritating to skin.
Revision no. : 1.00 GB - EN Revision date : 03.12.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 242 Vicinale Diketone/ Vicinale Dicetones; LCK 242 B; 2/2
Print date : 02.05.2008 Product code : LCK242-2 Page 4 of 6
12. Ecological information
Ecotoxicity
No data is available on the product itself.
Do not flush into surface water or sanitary sewer system.
13. Disposal considerations
Advice on disposal
In accordance with local and national regulations.
Our local agencies will accept used cuvettes to ensure their proper disposal.
Waste disposal number of waste from residues/unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of contaminated packaging
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
3316
UN number :
9
ADR/RID class :
Warning plate
ADR/RID packing group : II
Description of the goods
Chemical kit
Inland waterways transport
Other applicable information (inland waterways transport)
Not tested
Marine transport
3316
UN number :
9
IMDG code :
-
Marine pollutant :
II
IMDG packing group :
F-A, S-P
EmS :
Description of the goods
Chemical kit
Air transport
3316
UN/ID number :
9
ICAO/IATA-DGR :
II
ICAO packing group :
Revision no. : 1.00 GB - EN Revision date : 03.12.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 242 Vicinale Diketone/ Vicinale Dicetones; LCK 242 B; 2/2
Print date : 02.05.2008 Product code : LCK242-2 Page 5 of 6
Description of the goods
Chemical kit
Further Information
These transport data apply to the entire pack
15. Regulatory information
Labelling
T - Toxic; N - Dangerous for the environment
Danger symbols :
T - Toxic N - Dangerous for the
environment
Hazardous component(s) to be indicated on label
o-phenylenediamine dihydrochloride
R phrases
25 Toxic if swallowed.
36 Irritating to eyes.
40 Limited evidence of a carcinogenic effect.
43 May cause sensitization by skin contact.
68 Possible risks of irreversible effects.
20/21 Harmful by inhalation and in contact with skin.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
S phrases
28 After contact with skin, wash immediately with plenty of water .
35 This material and its container must be disposed of in a safe way.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
36/37 Wear suitable protective clothing and gloves.
Additional advice on labelling
Classification according to European directive on classification of hazardous preparations
1999/45/EC.
National regulatory information
Employment restrictions : Observe employment restrictions for young people. Observe employment
restrictions for child bearing mothers and nursing.
Water contaminating class (D) : 3 - highly water contaminating
16. Other information
Full text of R-phrases referred to under sections 2 and 3
20/21 Harmful by inhalation and in contact with skin.
25 Toxic if swallowed.
36 Irritating to eyes.
40 Limited evidence of a carcinogenic effect.
43 May cause sensitization by skin contact.
50 Very toxic to aquatic organisms.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
53 May cause long-term adverse effects in the aquatic environment.
Revision no. : 1.00 GB - EN Revision date : 03.12.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCK 242 Vicinale Diketone/ Vicinale Dicetones; LCK 242 B; 2/2
Print date : 02.05.2008 Product code : LCK242-2 Page 6 of 6
68 Possible risks of irreversible effects.
Further Information
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)
Revision no. : 1.00 GB - EN Revision date : 03.12.2007
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