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MSDS Material Safety Data Sheet
CAS

98-59-9

File Name: nanomechanics_pratt_duke_edu---p_Toluenesulfonyl_chloride.asp
 
Material Safety Data Sheet

p-Toluenesulfonyl chloride



                  Section 1 - Chemical Product and Company Identification

MSDS Name:      p-Toluenesulfonyl chloride

Catalog         13903-0000, 13903-0020, 13903-0250, 13903-5000, 22054-0000,

Numbers:        22054-0100, 22054-1000, 22054-5000

Synonyms:       Tosyl chloride

                                                    Acros Organics BVBA

Company Identification:                             Janssen Pharmaceuticalaan 3a

                                                    2440 Geel, Belgium

                                                    Acros Organics

Company Identification: (USA)                       One Reagent Lane

                                                    Fair Lawn, NJ 07410

For information in the US, call:                    800-ACROS-01

For information in Europe, call:                    +32 14 57 52 11

Emergency Number, Europe:                           +32 14 57 52 99

Emergency Number US:                                201-796-7100

CHEMTREC Phone Number, US:                          800-424-9300

CHEMTREC Phone Number, Europe:                      703-527-3887

                     Section 2 - Composition, Information on Ingredients

                     CAS#       Chemical Name:          % EINECS#

                    98-59-9 p-Toluenesulfonyl chloride >99% 202-684-8

        Hazard Symbols:          C









        Risk Phrases:            29 34

                              Section 3 - Hazards Identification

                                EMERGENCY OVERVIEW

            Contact with water liberates toxic gas. Causes burns.Moisture sensitive.

Potential Health Effects

Eye:             Causes eye burns.

Skin:            Causes skin burns.

Ingestion:       Causes gastrointestinal tract burns.

Inhalation:      Causes chemical burns to the respiratory tract.

Chronic:

                                Section 4 - First Aid Measures

              Immediately flush eyes with plenty of water for at least 15 minutes, occasionally

Eyes:

              lifting the upper and lower eyelids. Get medical aid immediately.

              Get medical aid immediately. Immediately flush skin with plenty of water for at

Skin:

              least 15 minutes while removing contaminated clothing and shoes.

Ingestion:    Do not induce vomiting. Get medical aid immediately.

                Get medical aid immediately. Remove from exposure and move to fresh air

Inhalation:     immediately. If not breathing, give artificial respiration. If breathing is difficult,

                give oxygen.

Notes to

                Treat symptomatically and supportively.

Physician:

                                 Section 5 - Fire Fighting Measures

General           As in any fire, wear a self-contained breathing apparatus in pressure-demand,

Information:      MSHA/NIOSH (approved or equivalent), and full protective gear.

Extinguishing

                  Use foam, dry chemical, or carbon dioxide.

Media:

                             Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.

Spills/Leaks:        Vacuum or sweep up material and place into a suitable disposal container.

                                 Section 7 - Handling and Storage

         Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.

Handling:

         Use only in a chemical fume hood.

Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area.

                       Section 8 - Exposure Controls, Personal Protection

Engineering Controls:

         Facilities storing or utilizing this material should be equipped with an eyewash facility

         and a safety shower. Use adequate ventilation to keep airborne concentrations low.

Exposure Limits

         CAS# 98-59-9:

                    United Kingdom, WEL - STEL: 5 mg/m3 STEL





Personal Protective Equipment

Eyes:        Wear chemical splash goggles.

Skin:        Wear appropriate protective gloves to prevent skin exposure.

Clothing: Wear appropriate protective clothing to prevent skin exposure.

             Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European

             Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149

Respirators:

             approved respirator if exposure limits are exceeded or if irritation or other

             symptoms are experienced.

                           Section 9 - Physical and Chemical Properties

                                Physical State: Crystalline powder

                                         Color: white

                                          Odor: Not available

                                            pH: Not available

                               Vapor Pressure: 1mmHg @88 deg C

                                     Viscosity: Not available

                                  Boiling Point: 134 deg C @10mmHg ( 273.20掳F)

                       Freezing/Melting Point: 67 - 69 deg C

                     Autoignition Temperature: Not available

                                   Flash Point: 128 deg C ( 262.40 deg F)

                      Explosion Limits: Lower: Not available

                      Explosion Limits: Upper: Not available

                   Decomposition Temperature: Not available

                            Solubility in water: hydrolyses

                      Specific Gravity/Density:

                           Molecular Formula: C7H7ClO2S

                            Molecular Weight: 190.64

                                Section 10 - Stability and Reactivity

Chemical Stability:                  Moisture sensitive.

Conditions to Avoid:                 Incompatible materials, exposure to moist air or water.

Incompatibilities with Other

                                     Strong oxidizing agents, strong bases.

Materials

Hazardous Decomposition              Hydrogen chloride, carbon monoxide, oxides of sulfur,

Products                             carbon dioxide.

Hazardous Polymerization             Has not been reported.

                               Section 11 - Toxicological Information
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