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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/08/2003 Reviewed on 07/08/2003
1 Identification of substance
路 Product details
路 Trade name: Concrete Film Remover
路 Article number: 10810, 10811
路 Application of the substance / the
preparation Cleaning agent/ Cleaner
路 Manufacturer/Supplier: AKEMI Erich H枚ntsch GmbH Tel. +49(0)911-642960
Lechstrasse 28 Fax. +49(0)911-644456
D 90451 N眉rnberg e-mail info@akemi.de
路 Information department: Laboratory
2 Composition/Data on components
路 Chemical characterization
路 Description: Mixture of the substances listed below with nonhazardous additions.
路 Dangerous components:
CAS: 7647-01-0 hydrogen chloride 25-50%
EINECS: 231-595-7
EU Number: 017-002-01-X
CAS: 7664-38-2 phosphoric acid 10-25%
EINECS: 231-633-2
EU Number: 015-011-00-6
Aliphatic alkohols, C13-C15, largely linear, ethoxylated 2.5-10%
CAS: 110-65-6 but-2-yne-1,4-diol 鈮? 2.5%
EINECS: 203-788-6
EU Number: 603-076-00-9
路 Additional information: For the wording of the listed risk phrases refer to section 16.
3 Hazards identification
路 Hazard description: Corrosive
路 Information pertaining to particular
dangers for man and environment: The product has to be labelled due to the calculation procedure of the "General
Classification guideline for preparations of the EU" in the latest valid version.
Causes burns.
Irritating to respiratory system.
路 Classification system: The classification was made according to the latest editions of international
substances lists, and expanded upon from company and literature data.
路 NFPA ratings (scale 0 - 4) Health = 3
Fire = 0
Reactivity = 0
路 HMIS-ratings (scale 0 - 4) Health = 3
Fire =0
Reactivity = 0
4 First aid measures
路 General information: Immediately remove any clothing soiled by the product.
路 After inhalation: Supply fresh air; consult doctor in case of complaints.
In case of unconsciousness place patient stably in side position for
transportation.
路 After skin contact: Immediately wash with water and soap and rinse thoroughly.
路 After eye contact: Rinse opened eye for several minutes under running water. Then consult a
doctor.
路 After swallowing: Drink copious amounts of water and provide fresh air. Immediately call a doctor.
(Contd. on page 2)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/08/2003 Reviewed on 07/08/2003
Trade name: Concrete Film Remover
(Contd. of page 1)
5 Fire fighting measures
路 Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or
alcohol resistant foam.
路 Special hazards caused by the
material, its products of
combustion or resulting gases: Hydrogen chloride (HCl)
路 Protective equipment: Wear self-contained respiatory protective device.
Wear fully protective suit.
6 Accidental release measures
路 Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
Particular danger of slipping on leaked/spilled product.
路 Measures for environmental
protection: Inform respective authorities in case of seepage into water course or sewage
system.
Do not allow to enter sewers/ surface or ground water.
路 Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal
binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7 Handling and storage
路 Handling:
路 Information for safe handling: Keep receptacles tightly sealed.
Ensure good ventilation/exhaustion at the workplace.
路 Information about protection
against explosions and fires: No special measures required.
路 Storage:
路 Requirements to be met by
storerooms and receptacles: No special requirements.
路 Information about storage in one
common storage facility: Do not store together with alkalis (caustic solutions).
路 Further information about storage
conditions: Protect from heat and direct sunlight.
Keep receptacle tightly sealed.
Protect from frost.
8 Exposure controls and personal protection
路 Additional information about
design of technical systems: No further data; see item 7.
路 Components with limit values that require monitoring at the workplace:
7647-01-0 hydrogen chloride
PEL Short-term value: C 7 mg/m鲁, C 5 ppm
REL Short-term value: C 7 mg/m鲁, C 5 ppm
TLV Short-term value: C 7.5 mg/m鲁, C 5 ppm
NIC-C 2; C 2.98; NIC-A4
7664-38-2 phosphoric acid
PEL 1 mg/m鲁
REL Short-term value: 3 mg/m鲁
Long-term value: 1 mg/m鲁
TLV Short-term value: 3 mg/m鲁
Long-term value: 1 mg/m鲁
路 Additional information: The lists that were valid during the creation were used as basis.
(Contd. on page 3)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/08/2003 Reviewed on 07/08/2003
Trade name: Concrete Film Remover
(Contd. of page 2)
路 Personal protective equipment:
路 General protective and hygienic
measures: Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
路 Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of
intensive or longer exposure use respiratory protective device that is
independent of circulating air.
路 Protection of hands: Protective gloves
路 Material of gloves Butyl rubber, BR
Fluorocarbon rubber (Viton)
Nitrile rubber, NBR
Chloroprene rubber, CR
PVC gloves
The selection of the suitable gloves does not only depend on the material, but
also on further marks of quality and varies from manufacturer to manufacturer.
路 Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the
protective gloves and has to be observed.
路 Eye protection: Tightly sealed goggles
路 Body protection: Protective work clothing
9 Physical and chemical properties
路 General Information
Form: Fluid
Color: Yellow-brown
Odor: Pungent
路 Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Undetermined.
路 Flash point: Not applicable.
路 Auto igniting: Product is not selfigniting.
路 Danger of explosion: Product does not present an explosion hazard.
路 Vapor pressure at 20掳C (68掳F): 20.0 hPa (15 mm Hg)
路 Density at 20掳C (68掳F): 1.150 g/cm鲁
路 Solubility in / Miscibility with
Water: Fully miscible.
路 pH-value at 20掳C (68掳F): <1
10 Stability and reactivity
路 Thermal decomposition /
conditions to be avoided: No decomposition if used according to specifications.
路 Dangerous reactions Reacts with strong oxidizing agents.
Reacts with metals forming hydrogen.
路 Dangerous products of
decomposition: Hydrogen chloride (HCl)
11 Toxicological information
路 Acute toxicity:
路 Primary irritant effect:
路 on the skin: Caustic effect on skin and mucous membranes.
路 on the eye: Strong caustic effect.
(Contd. on page 4)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/08/2003 Reviewed on 07/08/2003
Trade name: Concrete Film Remover
(Contd. of page 3)
路 Sensitization: No sensitizing effects known.
路 Additional toxicological
information: The product shows the following dangers according to internally approved
calculation methods for preparations:
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the
danger of perforation of esophagus and stomach.
12 Ecological information
路 General notes: Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Also poisonous for fish and plankton in water bodies.
13 Disposal considerations
路 Product:
路 Recommendation: Must not be disposed of together with household garbage. Do not allow product
to reach sewage system.
路 Uncleaned packagings:
路 Recommendation: Disposal must be made according to official regulations.
Empty contaminated packagings thoroughly. They can be recycled after
thorough and proper cleaning.
14 Transport information
路 DOT regulations:
路 Hazard class: 8
路 Identification number: UN3264
路 Packing group: II
路 Proper shipping name (technical name): CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROCHLORIC
ACID)
路 Label 8
路 Land transport ADR/RID (cross-border):
路 ADR/RID class: 8 (C1) Corrosive substances
路 Danger code (Kemler): 80
路 UN-Number: 3264
路 Packaging group: II
路 Description of goods: 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
(HYDROCHLORIC ACID)
路 Maritime transport IMDG:
路 IMDG Class: 8
路 UN Number: 3264
路 Label 8
路 Packaging group: II
路 EMS Number: F-A,S-B
路 Marine pollutant: No
路 Propper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROCHLORIC
ACID)
路 Air transport ICAO-TI and IATA-DGR:
路 ICAO/IATA Class: 8
路 UN/ID Number: 3264
路 Label 8
(Contd. on page 5)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/08/2003 Reviewed on 07/08/2003
Trade name: Concrete Film Remover
(Contd. of page 4)
路 Packaging group: II
路 Propper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROCHLORIC
ACID)
15 Regulations
路 Sara
路 Section 355 (extremely hazardous substances):
7647-01-0 hydrogen chloride
路 Section 313 (Specific toxic chemical listings):
7647-01-0 hydrogen chloride
7664-38-2 phosphoric acid
路 TSCA (Toxic Substances Control Act):
7647-01-0 hydrogen chloride
7664-38-2 phosphoric acid
110-65-6 but-2-yne-1,4-diol
路 Proposition 65
路 Chemicals known to cause cancer:
None of the ingredients is listed.
路 Chemicals known to cause reproductive toxicity:
None of the ingredients is listed.
路 Cancerogenity categories
路 EPA (Environmental Protection Agency)
None of the ingredients is listed.
路 IARC (International Agency for Research on Cancer)
7647-01-0 hydrogen chloride 3
路 NTP (National Toxicology Program)
None of the ingredients is listed.
路 TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
路 MAK (German Maximum Workplace Concentration)
None of the ingredients is listed.
路 NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
路 OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
路 Product related hazard
informations: The product has been classified and marked in accordance with directives on
hazardous materials.
路 Hazard symbols: Corrosive
路 Hazard-determining components
of labelling: hydrogen chloride
phosphoric acid
路 Risk phrases: Causes burns.
Irritating to respiratory system.
路 Safety phrases: Keep locked up and out of the reach of children.
Avoid contact with skin and eyes.
In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell, seek medical advice immediately.
Dispose of this material and its container at hazardous or special waste
collection point
(Contd. on page 6)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/08/2003 Reviewed on 07/08/2003
Trade name: Concrete Film Remover
(Contd. of page 5)
路 National regulations:
路 Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific
product features and shall not establish a legally valid contractual relationship.
路 Contact: Dieter Zimmermann
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