Version No: 04
Date of issue: Date of printing:
08/06/07 08.06.2007
1. Identification of the substance and the company
Product name: Chlorophacinone 0.29% [w/w] oil concentrate
CAS-No:
EU-No:
REANAL Product Number: 27594
Reanal Finechemical Co.
Company identification:
Address: HUNGARY, H-1147 Budapest, Telepes u. 53.
Tel.: (36-1) 467-7500
Fax.: (36-1) 252-1339
2. Composition / Information on ingredients
Molecular formula: N/A
Relative molecular weight: N/A
Active ingredient: Chlorophacinone 0.29 w/w %
Composition:
White oil 98.6 (w/w) %
Sudan red solution < 0.75 (w/w) %
Tridodecylamine 102-87-4 < 0.45 (w/w) %
3. Hazard statements
Hazard symbols and-signs:
N Xn
Dangerous for the environment Harmful
Risk phrases:
21/22 Harmful in contact with skin and if swallowed.
33 Danger of cumulative effects.
48/21/22 Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if
swallowed.
55 Toxic to fauna.
4. First aid measures
General:
Remove the person from the exposed area immediately, if necessary lay him/her comfortable and loosen tight
clothing. Remove contaminated clothing and shoes immediately. Cover up injured person, do not allow to cool.
Wash contaminated clothing before reuse. Call a physician!
Antidote of the active agent (chlorophacinone) is K1 vitamine (available as intravenous injection or chewing
tablets with phytomenadionum active agent).
Keep patient strictly in rest as continued movement enhances the effect of cholinesterase inhibition.
After swallowing:
If swallowed, wash out the mouth with water provided person is conscious. Let the patient drink 0.3-0.6 liter water
and activated carbon. Induce vomiting, repeat it 2-3 times. Finally give activated carbon with salted water and
laxative. Never give anything by mouth to an unconscious person.
Do not give milk, fat, oil, alcoholic beverage! Antidote: vitamin K1.
After inhalation:
Remove the person to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
After eye contact:
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Chlorophacinone 0.29% [w/w] oil concentrate
In case of contact immediately flush eyes with copious amount of water for at least 15 minutes. Assure adequate
flushing by separeting the eyelid with fingers. Drop 8-10 drops of 1% Lidocain solution into the eye. Get medical
attention if irritation persists.
After skin contact:
In case of skin contact, immediately wash skin with soap and copious amount of water.
Notes to the physician:
Antidote: vitamin K1. If the acute toxic effect is survived, the chances of complete recovery are very good
provided that subdural haemorrhages or vascular lesions in other tissues do not produce secondary effects.
5. Fire fighting measures
Combustible. Use water spray, carbon dioxide, dry chemical powder, or polymer foam extinguisher. Emits toxic
fumes under fire conditions. Wear self-contained breathing apparatus and protective clothing to prevent contact
with skin and eyes. Use water spray to cool containers under fire conditions. Use extinguishing media appropriate
to surrounding fire conditions.
6. Accidental release measures
Close and evacuate contaminated area. Do not allow contamination to get to drain. Only authorised person can
order the decontamination. Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves.
Absorb on sand or vermiculite and place in closed container for disposal. Ventilate area and wash spill site after
material pickup is complete.
7. Handling and storage
Containers out of use keep closed. Store in labelled container, in a cool, dry place. Light sensitive.
Storage temperature: 15-25 脟C
8. Exposure controls / Personal protection
Exposure controls:
Avoid contact with eyes, skin and clothing. Do not breathe vapour. When working do not eat or smoke. Take
care of bathing facilities with warm water after work. Safety shower and eye bath are required. Wash thoroughly
after handling.
Personal protective equipment:
Protective clothing.
Eye protect:
Chemical safety goggles.
Hand protect:
Chemical-resistant rubber gloves.
Respiration protection:
Gas-mask or respirator.
Specific control parameters
MAK (mg/m艂): -
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Chlorophacinone 0.29% [w/w] oil concentrate
9. Physical and chemical properties
clear oily liquid
Appearance:
dark, deep red
Colour:
nonmiscible
Solubility in water [脟C]:
>160
Flash point [脟C]:
>240
Ignition temperature [脟C]:
10. Stability and reactivity
Decomposition products:
Carbon monoxide, carbon dioxide, toxic fumes of chlorine.
11. Toxicological information
Acute toxicity:
Harmful if swallowed, inhaled or absorbed through skin. Internal bleedeing can occur in the organism, the level of
prothrombine is decreasing, resulting in abnormal clotting. Material is extremly destructive to tissue of the
mucous membranes and upper respiratory tract, eyes and skin. Inhalation may result in spasm, inflammation and
edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Symptoms of exposure may
include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting,
abnormal clotting, bruising or bleeding.
Target organ(s): blood.
Chronic effects: possible risk of congenital malformation in the foetus.
Toxicity data:
ORL-male rats LD50: 4385 碌l/kg
DERM-rabbits LD50: > 2000 mg/kg
12. Ecological information
WGK (German Water Hazard Classification): 0
Futher ecological data:
Ecotoxicity data:
ORL-female pheasants LD50: 177 mg/kg
ORL-male/female ducks LD50: 147 mg/kg
Toxicity on water life:
EC50 (Brachidanio rerio): > 100 mg/L
EC50 (Daphnia magna): >100 mg/L
13. Disposal information
Chemicals must be disposed of in compliance with the respective national regulations.
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Chlorophacinone 0.29% [w/w] oil concentrate
14. Transport information
ADR/RID: 9. III.
IMDG: 9/III.
IATA: 9/III.
CAO: 914
PAX: 914
UN: 3082
15. Regulatory information
Hazard signs:
Dangerous for the environment
N
Harmful
Xn
Risk phrases:
21/22 Harmful in contact with skin and if swallowed.
33 Danger of cumulative effects.
48/21/22 Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if
swallowed.
55 Toxic to fauna.
Safety phrases:
1 Keep locked up.
13 Keep away from food, drink and animal feeding stuffs.
36/37 Wear suitable protective clothing and gloves.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
Labelling according to EC Directives.
16. Other information
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as
a guide. Reanal shall not be held liable for any damage resulting from handling or from contact.
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Chlorophacinone 0.29% [w/w] oil concentrate
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