MATERIAL SAFETY DATA SHEET
95A
鈥斺?? S E C T I O N I 鈥斺??
PRODUCT IDENTIFICATION
THE SHERWIN - WILLIAMS CO. EMERGENCY TELEPHONE NO. DATE OF PREPARATION
(216) 566-2917 1 - DEC - 95
101 PROSPECT AVE. N.W.
CLEVELAND, OH 44115 INFORMATION TELEPHONE NO.
(216) 566-2902 漏1995, The Sherwin-Williams Co.
ULTRA PLUS TM Acrylic Urethane System AUP
UP- series
鈥斺?? S E C T I O N I I 鈥?-- ACGIH OSHA Vapor SSH-520 UA-101
Non-Lead Lead Urethane 4.0/4.3
CAS No. HAZARDOUS INGREDIENT TLV PEL Units Pressure
(percent by weight) Colors Colors Hardener Converter
(mm Hg)
108-88-3 搂 Toluene. 100
50 PPM (Skin) 22.0 4-10 4-10
<150 >
100-41-4 搂 Ethylbenzene 100 100 PPM 7.1 4-6 4-6 7
<125 > <125 >
1330-20-7 搂 Xylene. 100 100 PPM 5.9 25-35 25-35 40
<150 > <150 >
95-63-6 搂 1,2,4-Trimethylbenzene 25 25 PPM 2.0 0-1 0-1
108-10-1 搂 Methyl Isobutyl Ketone 50 50 PPM 16.0 0-5 0-5
<75 > <75 >
150 150
123-86-4 n-Butyl Acetate. PPM 10.0 3-5 3-5 8 10
<200 > <200 >
112-07-2 搂 2-Butoxyethyl Acetate. Not Established 1.0 2-5 2-5
0.5 Mg/M3
Proprietary Hexamethylene Diisocyanate Polymer. 45
<1.0 > Supplier Limit
822-06-0 Hexamethylene Diisocyanate (max.) 0.005 PPM 0.05 0.7
Mg/M3 as Dust
13463-67-7 Titanium Dioxide 10 10[5] 0-20 0-20
[Resp. Fraction]
Proprietary Substituted Cyclohexyldiaminoethyl Esters Not Established 90
1344-37-2 Lead Chromate. 0.05 0.05 Mg/M3 <15
12656-85-8 Molybdate Orange.
搂 Lead Compound (maximum) [% Lead] 15[9.1]
搂 Chromium Compound (maximum) [% Chromium] 15[1.7]
Weight per Gallon (lbs.) 7.5-9.5 7.5-9.5 8.07 8.67
VOC - Total Volatile Organic Compounds (lbs./gal.) 4.2-5.1 4.2-5.1 4.46 0.87
VOC - Less Water and exempt Solvents (lbs./gal.) 4.2-5.1 4.2-5.1 4.46 0.87
Photochemically Reactive Yes Yes Yes No
Flash Point (掳F) 45-60 45-60 77 125
DOL Storage Category 1B 1B 1C 2
Flammability Classification (Flammable - Combustible) Flam. Flam. Flam. Comb.
HMIS (NFPA) Rating (health - flammability - reactivity) 2* 3 0 2* 3 0 2* 3 1 220
搂 Ingredient subject to the reporting requirements of the Superfund Amendments and Reauthorization Act (SARA) Section 313, 40 CFR 372.65 C
猫猫猫 猫猫猫
MSDS Text Page Follows
I-5a
ULTRA PLUSTM Acrylic Urethane System AUP
Section III 鈥? PHYSICAL DATA Section VII 鈥? SPILL OR LEAK PROCEDURES
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?? 鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
PRODUCT WEIGHT EVAPORATION RATE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
鈥? See TABLE 鈥? Slower than Ether
SPECIFIC GRAVITY VAPOR DENSITY
鈥? 0.90-1.14 鈥? Heavier than Air Remove all sources of ignition. Ventilate and remove with inert absorbent.
BOILING RANGE MELTING POINT
鈥? 222-384 掳F 鈥? N.A. If hardener is spilled, all personnel in the area should be protected as in
VOLATILE VOLUME SOLUBILITY IN WATER
鈥? 12-62 % 鈥? N.A. Section VIII. Cover spill with absorbent material. Deactivate spilled material with a
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?? 10% ammonium hydroxide solution (household ammonia). After 10 minutes, collect in open
Section IV 鈥? FIRE AND EXPLOSION HAZARD DATA containers and add more ammonia. Cover loosely. Wash spill area with soap and water.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?? WASTE DISPOSAL METHOD
FLAMMABILITY CLASSIFICATION FLASH POINT LEL UEL
See TABLE 0.5 7.6 No material containing UA-101 4.0/4.3 Converter can be released to waterways because it
See TABLE contains a SNUR material. See Section X.
EXTINGUISHING MEDIA Waste from these products may be hazardous as defined under the Resource Conservation and
Carbon Dioxide, Dry Chemical, Foam Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the
UNUSUAL FIRE AND EXPLOSION HAZARDS applicable EPA hazardous waste numbers. Waste from products containing Lead or Chromium must
Keep containers tightly closed. Isolate from heat, electrical equipment, sparks, and open also be tested for extractability.
flame. Closed containers may explode when exposed to extreme heat. Application to hot Incinerate in approved facility. Do not incinerate closed container. Dispose of in
surfaces requires special precautions. During emergency conditions overexposure to accordance with Federal, State, and Local regulations regarding pollution.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
decomposition products may cause a health hazard. Symptoms may not be immediately apparent.
Section VIII 鈥? PROTECTION INFORMATION
Obtain medical attention.
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SPECIAL FIRE FIGHTING PROCEDURES
PRECAUTIONS TO BE TAKEN IN USE
Full protective equipment including self-contained breathing apparatus should be used.
Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be NO PERSON SHOULD USE THESE PRODUCTS, OR BE IN THE AREA WHERE THEY ARE BEING USED, IF THEY
used to cool closed containers to prevent pressure build-up and possible autoignition or HAVE CHRONIC (LONG-TERM) LUNG OR BREATHING PROBLEMS OR IF THEY EVER HAD A REACTION TO
explosion when exposed to extreme heat. ISOCYANATES.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?? Certain topcoat colors contain Lead. (See TABLE and PRODUCT LABEL). Before initial use of
Section V 鈥? HEALTH HAZARD DATA Lead-containing colors, consult OSHA's Standard for Occupational Exposure to Lead(29 CFR1910.1025).
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?? Use only with adequate ventilation. Avoid breathing vapor and spray mist. Avoid contact
ROUTES OF EXPOSURE with skin and eyes. Wash hands after using.
Exposure may be by INHALATION and/or SKIN or EYE contact, depending on conditions of use. These coatings may contain materials classified as nuisance particulates (listed 鈥渁s Dust鈥? in
To minimize exposure, follow recommendations for proper use, ventilation, and personal Section II) which may be present at hazardous levels only during sanding or abrading of the
protective equipment. dried film. If no specific dusts are listed in Section II, the applicable limits for nuisance
ACUTE Health Hazards dusts are ACGIH TLV 10 mg./m3 (total dust), OSHA PEL 15 mg./m3 (total dust), 5 mg./m3
(respirable fraction).
EFFECTS OF OVEREXPOSURE
VENTILATION
Irritation of eyes, skin and respiratory system. May cause nervous system depression.
Local exhaust preferable. General exhaust acceptable if the exposure to materials in
Extreme overexposure may result in unconsciousness and possibly death.
Section II is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94,
Certain colors contain Lead (See TABLE and PRODUCT LABEL). Acute occupational exposure to
1910.107, 1910.108.
Lead is uncommon, but results in symptoms similar to chronic overexposure described below.
RESPIRATORY PROTECTION
4.0/4.3 Converter may cause allergic respiratory and/or skin reaction in susceptible persons
Where overspray is present, a positive pressure air supplied respirator (TC19C NIOSH/MSHA
or sensitization. This effect may be delayed several hours after exposure.
approved) should be worn. If unavailable, a properly fitted organic vapor/particulate
SIGNS AND SYMPTOMS OF OVEREXPOSURE
respirator approved by NIOSH/MSHA for protection against materials in Section II may be
Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure
effective. Follow respirator manufacturer鈥檚 directions for use. Wear the respirator for the
to vapors or spray mists.
whole time of spraying and until all vapors and mists are gone. NO PERSONS SHOULD BE ALLOWED
Redness and itching or burning sensation may indicate eye or excessive skin exposure.
IN THE AREA WHERE THESE PRODUCTS ARE BEING USED UNLESS EQUIPPED WITH THE SAME RESPIRATOR
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
PROTECTION RECOMMENDED FOR THE PAINTERS.
Hardener CONTAINS ISOCYANATES. Isocyanates may cause allergic respiratory and/or skin
When sanding, wirebrushing, abrading, burning, or welding the dried film, wear a particulate
reaction in susceptible persons or sensitization. This effect may be delayed several hours
respirator approved by NIOSH/MSHA for protection against non-volatile materials in Section II.
after exposure.
PROTECTIVE GLOVES
EMERGENCY AND FIRST AID PROCEDURES
Wear gloves which are recommended by glove supplier for protection against materials in
If INHALED: If any breathing problems occur during use, LEAVE THE AREA and get fresh air.
Section II.
If problems remain or occur later, IMMEDIATELY get medical attention.
EYE PROTECTION -- Wear safety spectacles with unperforated sideshields.
If on SKIN: Wash affected area thoroughly with soap and water.
OTHER PROTECTIVE EQUIPMENT -- Use barrier cream on exposed skin.
Remove contaminated clothing and launder before re-use.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
If in EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention.
Section IX 鈥? PRECAUTIONS
If SWALLOWED: Get medical attention.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
CHRONIC Health Hazards
DOL STORAGE CATEGORY 鈥? See TABLE
Certain Colors contain Lead and/or Chromate (See TABLE and PRODUCT LABEL).
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Chronic overexposure to Lead may result in damage to the blood-forming, nervous, urinary,
Keep away from heat, sparks, and open flame. During use and until all vapors are gone: Keep
and reproductive systems (including embryotoxic effects). Symptoms include abdominal discomfort
area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off
or pain, constipation, loss of appetite, metallic taste, nausea, insomnia, nervous irritability,
stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code.
weakness, muscle and joint pains, headache and dizziness.
Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer
Chromates are listed by IARC and NTP. Although studies have associated exposure to
only to approved containers with complete and appropriate labeling. Do not take internally.
Chromium VI compounds with an increased risk of respiratory cancer, available evidence
Keep out of the reach of children.
indicates that Lead Chromate (Chrome Yellow, Molybdate Orange) DOES NOT present this hazard.
OTHER PRECAUTIONS
Prolonged overexposure to solvent ingredients in Section II may cause adverse effects to
Certain colors contain Lead (See PRODUCT LABEL). Do not apply Lead-containing colors on toys
the liver, urinary, blood forming, cardio-vascular, and reproductive systems.
or other children's articles, furniture, or any interior surface of a dwelling or facility which
Hardener CONTAINS ISOCYANATES. Persons sensitive to isocyanates will experience increased
may be occupied or used by children. Do not apply on any exterior surface of dwelling units,
allergic reaction on repeated exposure.
such as window sills, porches, stairs, or railings to which children may be commonly exposed.
Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such
These products must be mixed with other components before use. Before opening the packages,
exposure levels are not attainable in the workplace.
READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
Reports have associated repeated and prolonged overexposure to solvents with permanent brain
Intentional misuse by deliberately concentrating and inhaling the contents can be harmful
and nervous system damage.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?? or fatal.
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
Section VI 鈥? REACTIVITY DATA
Section X 鈥? OTHER REGULATORY INFORMATION
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
鈥斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺?斺??
STABILITY 鈥? Stable
CALIFORNIA PROPOSITION 65
CONDITIONS TO AVOID
WARNING: These products, except for UA-101, contain chemicals known to the State of
None known.
California to cause cancer and birth defects or other reproductive harm.
INCOMPATIBILITY
The substituted Cyclohexyldiaminoethyl Ester in UA-101 4.0/4.3 Converter is subject to a
Metallics contain Aluminum. Contamination with Water, Acids, or Alkalis can cause evolution
Significant New Use Rule (SNUR) under TSCA (40 CFR 721.2980) and may not be released to water.
of hydrogen, which may result in dangerously increased pressures in closed containers.
Processors of this chemical are subject to certain record keeping requirements.
Contamination of hardeners with Water, Alcohols, Amines, and other compounds which react with
The above information pertains to this product as currently formulated, and is based on the
isocyanates, may result in dangerous pressure in, and possible bursting of closed containers.
information available at this time. Addition of reducers or other additives to this product may
HAZARDOUS DECOMPOSITION PRODUCTS
substantially alter the composition and hazards of the product. Since conditions
By fire: Carbon Dioxide, Carbon Monoxide, Oxides of Metals in Section II
I-5a
of use are outside our control, we make no warranties, express or implied, and
HAZARDOUS POLYMERIZATION 鈥? Will Not Occur
assume no liability in connection with any use of this information.
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