03 鈥? Section 1 鈥?
Material Safety Data Sheet
Product Identification
Sherwin-Williams Automotive Finishes Corp. Emergency telephone number (216) 566-2917
101 Prospect Ave. N.W. Information telephone number (216) 566-2902
Cleveland, OH 44115 Date of preparation Januar y 22, 2003
漏2003, The Sherwin-Williams Co.
SHER-LAC 庐 Acrylic Lacquer Thinners LAC/3
R7K205 R7K214 R7K248 R7K203 R7K6248 R7K6231
鈥? Section 2 鈥? ACGIH OSHA LD50 LC50 Vapor
Non-
Hazardous Ingredients
CAS No. TLV PEL Units (Rat-Oral) (Rat) Pressure
Penetrating Fast Medium Slow Medium Very Slow
mg/kg ppm/4hr. mm
(percent by weight)
64742-89-8 Lt. Aliphatic Hydrocarbon Solvent 100 100 ppm NAv NAv 53.0 5 14 6 10
300
64742-89-8 V. M. & P. Naphtha 300 ppm NAv NAv 12.0 27 10 16 P
<400 >
搂 100 E
108-88-3 Toluene 50 ppm (skin) 5000 4000 22.0 19 51 55 18 19 12
<150 > R
搂 100 100 C
100-41-4 Ethylbenzene ppm 3500 NAv 7.1 1.0
<125 > <125 >
E
搂 100 100
1330-20-7 Xylene ppm 4300 5000 5.9 6 N
<150 > <150 >
搂 200 200 T
67-56-1 Methanol ppm (skin) 5630 64000 92.0 3 3 3 3
<250 > <250 >
400 400 B
67-63-0 2-Propanol ppm 5045 NAv 33.0 10 5 7 10 15
<500 > <500 >
Y
78-83-1 2-Methyl-1-propanol 50 50 ppm 2460 NAv 8.7 5
W
500
67-64-1 Acetone 1000 ppm 5800 NAv 180.0 65 19 19 32 12 23
<750 > E
搂 200 200 I
78-93-3 Methyl Ethyl Ketone ppm 2740 NAv 70.0 6
<300 > <300 > G
搂 50 50
108-10-1 Methyl Isobutyl Ketone ppm 2080 NAv 16.0 5 7 H
<75 > <75>
T
110-19-0 Isobutyl Acetate 150 150 ppm 13400 NAv 12.5 27
108-65-6 1-Methoxy-2-Propanol Acetate NAv NAv 8500 NAv 1.8 2 2 16 2 20
Weight per Gallon (lbs.) 6.65 6.82 6.89 6.83 6.78 6.92
VOC (Volatile Organic Compounds) Emitted - lbs./gal. 2.29 5.49 5.57 4.62 5.93 5.34
VOC Less Water & Federally Exempt Solvents - lbs./gal. 6.78 6.87 6.96 6.95 6.80 7.03
Photochemically Reactive No Yes Yes No No No
Flash Point (掳F) 1 4 4 1 4 1
HMIS (NFPA) Rating (health - flammability - reactivity) 2-3-0 3-3-0 3-3-0 3-3-0 3-3-0 2* - 3 - 0
PAINT-SAFE 庐 Personal Protection J3 J3 J3 J3 J3 J3
搂
Ingredient subject to the reporting requirements of the Superfund Amendments and Reauthorization Act (SARA) Section 313, 40 CFR 372.65 C
!!! MSDS Text Page Follows !!! I-19
SHER-LAC 庐 Acrylic Lacquer Thinners LAC/3
Section 9 鈥? Physical and Chemical Properties
Section 3 鈥? Hazards Identification
PRODUCT WEIGHT See TABLE EVAPORATION RATE Slower than ether
ROUTES OF EXPOSURE - Exposure may be by INHALATION and/or SKIN or EYE contact, depending on
SPECIFIC GRAVITY 0.80 - 0.83 VAPOR DENSITY Heavier than air
conditions of use. Alcohols and acetates can be absorbed through the skin. Follow recommendations for proper use,
BOILING POINT 132 - 419 掳F MELTING POINT Not Available
ventilation, and personal protective equipment to minimize exposure.
VOLATILE VOLUME 100 % SOLUBILITY IN WATER Not Available
EFFECTS OF OVEREXPOSURE - Irritation of eyes, skin and upper respiratory system. May cause nervous system
depression. Extreme overexposure may result in unconsciousness and possibly death.
Section 10 鈥? Stability and Reactivity
SIGNS AND SYMPTOMS OF OVEREXPOSURE - Headache, dizziness, nausea, and loss of coordination are
STABILITY - Stable
indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate
CONDITIONS TO AVOID - None known.
eye or excessive skin exposure.
INCOMPATIBILITY - None known.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE - None generally recognized.
HAZARDOUS DECOMPOSITION PRODUCTS - By fire: Carbon Dioxide, Carbon Monoxide
CANCER INFORMATION - For complete discussion of toxicology data refer to Section 11.
HAZARDOUS POLYMERIZATION - Will not occur
Section 4 鈥? First Aid Measures
Section 11 鈥? Toxicological Information
If INHALED: If affected, remove from exposure. Restore breathing. Keep warm and quiet.
CHRONIC HEALTH HAZARDS - Ethylbenzene is classified by IARC as possibly carcinogenic to humans (2B) based
If on SKIN: Wash affected area thoroughly with soap and water.
on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats
Remove contaminated clothing and launder before re-use.
and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors
If in EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention.
in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower
If SWALLOWED: Do not induce vomiting. Get medical attention immediately.
concentrations. There is no evidence that ethylbenzene causes cancer in humans.
Section 5 鈥? Fire Fighting Measures Methyl Ethyl Ketone may increase the nervous system effects of other solvents.
Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary,
LEL UEL
FLASH POINT
blood forming, cardiovascular and reproductive systems.
See TABLE 0.9 36.5
Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous
FLAMMABILITY CLASSIFICATION - RED LABEL -- Extremely Flammable, Flash below 21 掳F
system damage.
EXTINGUISHING MEDIA - Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS - Closed containers may explode when exposed to extreme heat.
Section3 12 鈥? Ecological Information
Application to hot surfaces requires special precautions. During emergency conditions overexposure to
No data available.
decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
Section 13 鈥? Disposal Considerations
SPECIAL FIRE FIGHTING PROCEDURES - Full protective equipment including self-contained breathing apparatus
WASTE DISPOSAL METHOD - Waste from these products may be hazardous as defined under the Resource
should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to
Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the
cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme
applicable EPA hazardous waste numbers. Waste from products containing Methyl Ethyl Ketone may also require
heat.
extractability testing.
Section 6 鈥? Accidental Release Measures Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal,
State/Provincial, and Local regulations regarding pollution.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED - Remove all sources of ignition.
Ventilate the area. Remove with inert absorbent.
Section 14 鈥? Transport Information
Section 7 鈥? Handling and Storage No data available.
STORAGE CATEGORY - DOL Storage Class IB
Section 15 鈥? Regulatory Information
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING - Contents are EXTREMELY FLAMMABLE. Keep
CALIFORNIA PROPOSITION 65 - WARNING: These products contain chemicals known to the State of California
away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and
to cause cancer and birth defects or other reproductive harm.
until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn
TSCA CERTIFICATION - All chemicals in these products are listed, or are exempt from listing, on the TSCA
off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved
Inventory.
Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 16 鈥? Other Information
Section 8 鈥? Exposure Controls/Personal Protection These products have been classified in accordance with the hazard criteria of the CPR and the MSDS contains all
of the information required by the CPR.
PRECAUTIONS TO BE TAKEN IN USE - Use only with adequate ventilation. Avoid contact with skin and eyes.
Avoid breathing vapor and spray mist. Wash hands after using.
VENTILATION - Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is
maintained below applicable exposure limits. Refer to OSHA Standards 1910.94,1910.107, 1910.108.
RESPIRATORY PROTECTION - If personal exposure cannot be controlled below applicable limits by ventilation,
wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials
in Section 2.
PROTECTIVE GLOVES - Wear gloves which are recommended by glove supplier for protection against materials in
The above information pertains to these products as currently formulated, and is based on the information available
Section 2.
at this time. Addition of reducers or other additives to these products may substantially alter the composition and
EYE PROTECTION - Wear safety spectacles with unperforated sideshields.
hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied,
OTHER PRECAUTIONS - Intentional misuse by deliberately concentrating and inhaling the contents can be harmful
and assume no liability in connection with any use of this information.
or fatal.
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