Date Issued: June 2003
Supersedes: June 2000
MATERIAL SAFETY DATA SHEET
STARBAR铮? GOLDEN MALRIN铮? FLY BAIT
Wellmark International
Manufacturer:
1100 East Woodfield Road, Suite 500 Schaumburg, IL 60173
Address:
1-800-347-8272
Emergency Phone:
CHEMTREC: 1-800-424-9300
Transportation Emergency Phone:
1. CHEMICAL PRODUCT INFORMATION
Product Name: Starbar铮? Golden Malrin铮? Fly Bait
Methomyl; S-methyl N-[(methylcarbamoyl)oxy]thioacetimidate
Chemical Name/Synonym:
Carbamate
Chemical Family:
C5 H10 N2 O2 S
Formula:
2724-274
EPA Registration No.:
128E
RF Number:
2. COMPOSITION / INFORMATION ON INGREDIENTS
Component (chemical, common name) CAS Weight Tolerance
Number
Methomyl: (S-Methyl N-[(methylcarbamoyl)oxy] thioacetimidate 16752-77-5 1.1% 2.5 mg/m3
(OSHA &
ACGIH)
(Z)-9 Tricosene 27519-02-4 0.049% Not established
Inert ingredients (non-hazardous and/or trade secret) 98.851 Not established
3. HAZARD INFORMATION
PRECAUTIONARY STATEMENT
KEEP OUT OF THE REACH OF CHILDREN
CAUTION: HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH THE SKIN. AVOID BREATHING
DUST. AVOID CONTACT WITH SKIN, EYES OR CLOTHING. DO NOT ALLOW CHILDREN INTO TREATED
AREAS.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Active ingredient is a cholinesterase inhibitor: may cause excessive sweating, salivation, nausea, vomiting, headaches,
diarrhea, slurred speech, muscle twitching, pin-point pupils, ataxia, tightness in chest, vomiting, cyanosis, pulmonary
edema.
No Oral: Yes Inhalation: Yes
PRIMARY ROUTE OF ENTRY Dermal/Eye:
LD50 (rat): 3,106 mg/kg
ACUTE TOXICITY Oral:
LD50 (rabbit): >2,100 mg/kg (highest dose level tested)
Dermal:
Unknown
Inhalation:
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OTHER TOXICOLOGICAL INFORMATION
Non-irritating (rabbit)
Skin Irritation:
Very minimal (rabbit)
Eye Irritation:
Not considered a sensitizer
Sensitizer:
4. FIRST AID MEASURES
Hold eye open and rinse slowly and gently with water for 15-20 minutes.
Eye:
Remove contact lenses, if present, after the first 5 minutes, then continue
rinsing eye. Call a poison control center or doctor for treatment advice.
Take off contaminated clothing. Rinse skin immediately with plenty of water for
Skin:
15 鈥? 20 minutes
Immediately call poison control center or doctor for advice. Have person sip a
Ingestion:
glass of water if able to swallow. Do not induce vomiting unless told to do so
by poison control center or doctor. Do not give any liquid to the person. Do
not give anything by mouth to an unconscious person.
Remove to clear air area.
Inhalation:
Methomyl is a cholinesterase inhibitor. Atropine is antidotal. Where symptoms
Note to Physician:
are visible, atropine I.V. to effect is suggested.
5. FIRE FIGHTING MEASURES
NFPA Rating: Health: 1 Fire: 0 Reactivity: 0
Combustible solid
Flammability Class:
Does not flash
Flash Point:
N/A
Explosive Limits (% of Volume):
Water, foam, dry chemical, CO2
Extinguishing Media:
Fire fighters should wear full protective clothing including self-contained
Special Protective Equipment:
breathing apparatus.
Normal procedures. Do not allow fire fighting water to escape into waterways
Fire Fighting Procedures:
or sewers.
Carbon monoxide
Combustion Products:
Will ignite if exposed to intense heat or open flame. Fire or intense heat may
Unusual Fire/Explosion Hazards:
rupture container
6. ACCIDENTAL RELEASE MEASURES
Small amounts may be swept up and spread in planned use areas as directed
Steps to be taken:
on label or placed in container for disposal.
If in liquid form, use clay granules, sawdust, dirt or equivalent.
Absorbents:
Reactive metals, strong oxidizers
Incompatibles:
7. HANDLING AND STORAGE
Avoid breathing dust, avoid contact with skin, eyes or clothing. Wear the
Handling:
following personal protective clothing during loading, application, repairing, and
cleaning of application equipment., and disposal of the pesticide: Long-legged
pants; shoes and socks; gloves. Always wash hands, face and arms with soap
and water before using tobacco products, eating, drinking, or toileting
Do not store near water, food, or feed. Store in a dry cool place not reachable
Storage:
by children.
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8. EXPOSURE CONTROL / PERSONAL MEASURES
Methomyl = 2.5 mg/m3 (OSHA PEL & ACGIH TLV)
Exposure Limits:
Ventilate to keep airborne exposures below recommended limits
Ventilation:
If excessive exposure is anticipated, it is recommended for handlers to wear a
Personal Protective Equipment:
MSHA/NIOSH approved organic respirator with a dust prefilter, impervious
gloves, goggles with side shields, and other appropriate clothing to prevent
skin contact.
9. PHYSICAL AND CHEMICAL PROPERTIES
Solid blue granules with characteristic sulfurous odor.
Appearance and Odor:
N/A
Boiling Point:
N/A
Melting Point:
N/A
Vapor Pressure (mm Hg):
N/A
Vapor Density (Air = 1):
>1
Specific Gravity:
0.84 g/ml (0.80 - 0.90
Bulk Density:
Soluble in water
Solubility:
N/A
Evaporation Rate:
N/A
pH:
10. STABILITY AND REACTIVITY
Stable
Stability:
Nonreactive
Reactivity:
Reactive metals, strong oxidizers
Incompatibility w/ Other
Materials:
Oxides of nitrogen, carbon monoxide, carbon dioxide
Decomposition Products:
Will not occur
Hazardous Polymerization:
11. TOXICOLOGICAL INFORMATION
CHRONIC TOXICITY [Specific to Active Ingredient(s)]
In a 2 year feeding study in rats at feeding levels, 0, 50, 100, 200 and 400 ppm; the no effect level (NOEL) was 100 ppm
based on slight hemolytic anemia and/or body weight effects observed at the higher dietary concentrations. No
compound related neoplastic lesions were observed. In a 2 year feeding study in mice at feeding levels, 0, 50, 75, and
200 ppm; no compound related neoplastic or non-neoplastic histologic effects were found at any level. The NOEL was
considered to be 50 ppm based on transient hemolytic anemia and increased mortality at the higher dietary
concentrations. In a 2 year feeding study in dogs at feeding levels 0, 50, 100, 400, and 1,000 ppm the NOEL of 100 ppm
was based on hemolytic anemia and non-neoplastic changes within the kidney and spleen at the higher dietary
concentrations. There were no neoplastic effects at any dose
DEVELOPMENTAL/REPRODUCTIVE TOXICITY [Specific to Active Ingredient(s)]
A 3-generation rat reproduction study at rates of 50 and 100 ppm showed no adverse effect upon fertility, and no
compound related histologic effect. A 2-generation rat study conducted at 75, 600, and 1,200 ppm in the diet showed
similar results. In rats, no embryotoxic or teratogenic effects were observed at levels up to 400 ppm (highest level fed). In
rabbits, the highest dietary dose level (100 mg/kg) did not cause any observed compound related abnormalities.
MUTAGENICITY [Specific to Active Ingredient(s)]
Methomyl was negative in numerous assays to evaluate mutagenicity and genotoxicity, including Ames test, Reverse
Mutation Assay, Recessive Lethal Assay, three DNA damage studies, an unscheduled DNA Synthesis Assay, and in vitro
and in vivo cytogenic assays. Methomyl is not listed as a carcinogen by the IARC, NTP, OSHA and ACGIH.
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12. ECOLOGICAL INFORMATION
ENVIRONMENTAL FATE [Active Ingredients Only]
Hydrolysis: N/A
N/A
Photolysis:
N/A
Soil half life:
Soluble in water
Water solubility:
Do not apply directly to water, or to areas where surface water is present. This chemical is known to leach through soil
into ground water, especially where soils are permeable or water table is near the surface.
ECOTOXICITY [Active Ingredients Only]
Acute Toxicity: fish:LC50 (rainbow trout): 3.4 ppm (96 hour study), (bluegill sunfish): 0.72 mg/L
(96 hour study); aquatic invertebrates:LC50 (daphnia magna): 31.7 ppb (48
hour study) . Toxic to birds.
13. DISPOSAL CONSIDERATIONS
Do not contaminate water, food or feed by disposal. Waste resulting from the use of this product may be disposed of on
site or an approved waste disposal facility. Plastic Container Disposal: Triple rinse (or equivlent). Then offer for
recycling or reconditioning or puncture and dispose of in a sanitary landfill or by other approved state and local
procedures.
14. TRANSPORT INFORMATION
Not applicable
DOT49CFR Description:
Insecticides, Animal, NOI, O/T Poison NMFC I-102120 Class 60
Freight Classification:
15. REGULATORY INFORMATION
Reportable Quantity (RQ) = Methomyl 100 lbs. If a spill exceeds the RQ
CERCLA (Superfund):
contact the National Response Center at (800)424-8802
Methomyl (PO66)
RCRA:
SARA 311/312 HAZARD CATEGORIES
Immediate Health: Yes (irritant)
Yes
Delayed Health:
No
Fire:
No
Sudden Pressure:
No
Reactivity:
The information presented herein, while not guaranteed, was prepared by technically knowledgeable personnel and to
the best of our knowledge is true and accurate. It is not intended to be all inclusive and the manner and conditions of use
and handling may involve other or additional considerations.
23-11-037
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