MATERIAL SAFETY DATA SHEET
MSDS Y-110 REVISION 1
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
COMBAT INSECT CONTROL SYSTEMS
C/O The Dial Corporation Medical Emergencies: 1-888-689-9082
Center For Innovation Chemtrec: 1-800-424-9300 (24 Hours Daily)
15101 N. Scottsdale Rd Other Information: 1-888-468-6673
Scottsdale, Arizona 85254-9934
PRODUCT: COMBAT DATE OF ISSUE: May 11, 2007
TRADE NAMES/SYNONYMS: Combat Quick Kill Formula 2
Combat Quick Kill Large Roach Bait
Combat Quick Kill Large Roach Bait 8ct
Combat Large Roach Bait F.03
CHEMICAL FAMILY: INSECTICIDE
EPA REG. NUMBER: 64240-34
SECTION 2: HAZARD IDENTIFICATION
EMERGENCY OVERVIEW
CAUTION: Wash thoroughly with soap and water after handling bait stations. KEEP OUT OF REACH OF CHILDREN.
DO NOT ALLOW CHILDREN OR PETS TO PLAY WITH THE BAIT STATIONS. PRECAUTIONARY STATEMENTS:
Hazards to humans and domestic animals.
This product is labeled in accordance with guidelines set forth in the Federal Insecticide, Fungicide and Rodenticide Act.
The use pattern and exposure in the workplace are generally not consistent with those experienced by consumers. The
requirements of the Occupational Safety and Health Administration applicable to this Material Safety Data Sheet may differ
from the requirements of the FD & C Act and as a result, this MSDS may contain additional health hazard information not
pertinent to consumer use and not found on the product label.
REGULATORY STATUS
This material is considered to be hazardous under OSHA鈥檚 Hazard Communication Standard (29 CFR 1900.1200).
This MSDS should be retained and available for employees and other users of this product.
POTENTIAL HEALTH EFFECTS
EYE CONTACT: Can cause mild-to-moderate eye irritation.
SKIN CONTACT: Can cause mild skin irritation with prolonged contact.
INHALATION: Not a likely route of exposure. Irritating, in high concentration, to the respiratory tract (nose, throat,
and lungs).
INGESTION: Not a likely route of exposure. Ingestion of large amounts may cause some gastrointestinal
discomfort including nausea, vomiting, abdominal pain, diarrhea, and lethargy.
CHRONIC HEALTH EFFECTS: Due to the nature and composition of this product no chronic health effects are
anticipated.
MEDICAL CONDITIONS GENERALLY RECOGNIZED AS BEING AGGRAVATED BY EXPOSURE: No known health
conditions are aggravated by exposure to this product.
POTENTIAL ENVIRONMENTAL EFFECTS
See Section 12: Ecological Information.
COMBAT INSECT CONTROL SYSTEMS 鈥? C/O The Dial Corporation 鈥? 15101 N. Scottsdale Rd 鈥? Scottsdale, AZ 85254
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COMBAT QUICK KILL FORMULA 2 MSDS Y-110 (Rev. 1) May 11, 2007
SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS
Based on our hazard evaluation, the following chemical substance(s) in this product have been identified as hazardous.
INGREDIENT CAS NUMBER PERCENT (w/w)
FIPRONIL 120068-37-3 0.03 %
SECTION 4: FIRST AID MEASURES
Have the product container or label with you when calling a poison control center or doctor or going for treatment.
EYES: Immediately rinse eyes with plenty of water, occasionally lifting upper and lower lids, until no
evidence of product remains. Get medical attention if pain or irritation persists.
SKIN: Rinse affected area with plenty of water until no evidence of product remains. Get medical attention if
irritation persists.
INGESTION: Treat symptomatically and supportively. Maintain airway and respiration. If vomiting occurs, keep head
below hips to prevent aspiration. Dilution by rinsing the mouth and giving water or milk to drink is generally
recommended. If unconscious, the victim should not be given anything to drink. Contact physician or local poison
control center.
INHALATION: Remove from exposure area to fresh air immediately. Keep affected person warm and at rest. Treat
symptomatically and supportively. Contact physician or local poison control center. If breathing has stopped, give
artificial respiration, and get medical attention immediately.
NOTE TO PHYSICIAN: The physician's judgment should be used to control symptoms and clinical condition based on the
individual reactions of the patient.
SECTION 5: FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
OSHA FLAMMABILITY CLASSIFICATION: Not applicable FLASH POINT: > 200掳 (TCC)
F
UPPER FLAMMABILITY LIMIT: Not applicable LOWER FLAMMABILITY LIMIT: Not applicable
AUTO-IGNITION TEMPERATURE: Not applicable
FIRE AND EXPLOSION HAZARD: Negligible fire hazard when exposed to heat or flame.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon and oxides of nitrogen.
EXTINGUISHING MEDIA
Dry chemical, carbon dioxide (CO2) foam or water spray.
PROTECTION OF FIREFIGHTERS
In case of fire, wear a full-face positive-pressure self-contained breathing apparatus and protective suit. Move container
from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well
after fire is out. Use flooding amounts of water as a fog, solid streams may be ineffective. Avoid breathing vapors; keep
upwind.
SECTION 6: ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Ventilate spill area if possible. Do not touch spilled material. Stop or reduce any leaks if it is safe to do so. Use personal
protective equipment recommended in Section 8. Notify appropriate government, occupational health and safety and
environmental authorities. Keep unnecessary people away; isolate hazard area and restrict entry. Ensure clean-up is
conducted by trained personnel only.
ENVIRONMENTAL PRECAUTIONS
COMBAT INSECT CONTROL SYSTEMS 鈥? C/O The Dial Corporation 鈥? 15101 N. Scottsdale Rd 鈥? Scottsdale, AZ 85254
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COMBAT QUICK KILL FORMULA 2 MSDS Y-110 (Rev. 1) May 11, 2007
This product is toxic to fish and aquatic invertebrates. This product should not be directly discharged into lakes,streams,
ponds, estuaries, oceans, public water supplies, or other waters. Do not contaminate surface or ground water by cleaning
equipment or disposal of wastes, including equipment washwater.
METHODS FOR CONTAINMENT AND CLEAN UP
SMALL SPILLS: Contain and absorb with sand or other absorbent material and place into containers for later disposal.
Wash site of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement. Recover
by pumping or by using a suitable absorbent material and place into containers for later disposal. No smoking, flames or
flares in hazard area.
SECTION 7: HANDLING AND STORAGE
HANDLING:
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Avoid generating aerosols
and mists. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily
available.
STORAGE:
Store in a cool, dry, ventilated area out of reach of children and away from sources of heat, moisture, and incompatible
substances. Store in suitable labeled containers. Store the containers tightly closed.
SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION
The use of this product by consumers is safe under normal and reasonable foreseen use. The information provided below
refers to the occupational settings.
WORKER EXPOSURE LIMITS:
The following exposure limits exist for the ingredients listed below. The TLV-TWA is the Threshold Limit Value 鈥? Time
Weighted Average from Rhone 鈥? Poulenc for 12-month daily exposure.
INGREDIENT CAS NUMBER EXPOSURE LIMIT
3 3
Fipronil 120068-37-3 TLV-TWA 0.1 mg/m ; 0.032 mg/m
ENGINEERING CONTROLS: Provide local exhaust or general dilution ventilation to keep potential exposure to airborne
contaminants as low as possible.
RESPIRATOR: None required under normal use conditions. Use general ventilization to minimize exposure. Air
contamination monitoring should be carried out where generation of vapors is likely to occur, to assure that the employees
are not exposed to harmful concentrations of any of the above mentioned components. If respiratory protection is required,
it must be based on the contamination levels found in the workplace, must not exceed the working limits of the respirator
and be jointly approved by the National Institute for Occupational Safety and Health and the Mine Safety and Health
Administration (NIOSH-MSHA).
FOR FIRE FIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS: Any self-
contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other
positive-pressure mode. Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or
other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure
demand or other positive-pressure mode.
CLOTHING: Protective clothing (impervious to liquids) is required where splashing of product may occur.
GLOVES: Chemical-resistant gloves are required where repeated or prolonged skin contact may occur.
EYE/FACE PROTECTION: Splash-proof safety glasses are required to prevent eye contact where splashing of product
may occur.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Fipronil based food bait in a child resistant plastic station.
ODOR/ODOR THRESHOLD: Not available PHYSICAL STATE: Solid
pH (@ 25掳C): Not available VAPOR DENSITY: Not available
BOILING POINT: Not available VAPOR PRESSURE: Not available
COMBAT INSECT CONTROL SYSTEMS 鈥? C/O The Dial Corporation 鈥? 15101 N. Scottsdale Rd 鈥? Scottsdale, AZ 85254
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COMBAT QUICK KILL FORMULA 2 MSDS Y-110 (Rev. 1) May 11, 2007
MELTING/FREEZING POINT: 60掳 C FLASH POINT: See Section 5.
FLAMMABLE PROPERTIES: See Section 5. SOLUBILITY IN WATER: Partial
DENSITY/SPECIFIC GRAVITY: 1.27 g/ml EVAPORATION RATE: Not available
OCTANOL/WATER PARTITION COEFFICIENT (Kow): Not available
VISCOSITY (Dynamic): Not applicable
SECTION 10: STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable under normal ambient temperature (70掳 21掳 and pressure (1 atm).
F, C)
CONDITIONS TO AVOID: Avoid storing in direct sunlight and avoid extremes of temperature.
INCOMPATIBLE MATERIALS: Strong oxidizers and reducing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition products may include oxides of carbon.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.
SECTION 11: TOXICOLOGICAL INFORMATION
PRODUCT INFORMATION SUMMARY: The use of this product by consumers is safe under normal and reasonable
foreseen use. Direct contact with eyes can cause mild-to-moderate irritation. Can cause mild skin irritation with prolonged
contact.
COMPONENT ANALYSIS: The following toxicity information is available for the product and/or for the hazardous
ingredients when used as technical grade.
PRODUCT / INGREDIENT LD50 / DRAIZE SCORE TOXICITY / IRRITATION RATING
ACUTE ORAL TOXICITY
Combat Quick Kill Formula 2 > 5,000 mg/kg (rat) Non-hazardous
Fipronil (active ingredient) 97 mg/kg (rat) Very Toxic
ACUTE DERMAL TOXICITY
Combat Quick Kill Formula 2 > 2,000 mg/kg (rabbit) Practically Non-Toxic
Fipronil (active ingredient) 354 mg/kg (rabbit) ExtremelyToxic
ACUTE INHALATION TOXICITY
Combat Quick Kill Formula 2 > 5.0 mg/l Slightly Toxic
Fipronil (active ingredient) 0.39 mg/l (rat) Moderately Toxic
EYE IRRITATION
Combat Quick Kill Formula 2 Slightly Irritating
Fipronil (active ingredient) Moderately Irritating
SKIN IRRITATION
Combat Quick Kill Formula 2 Practically Non-Irritating
Fipronil (active ingredient) Slightly Irritating
SENSITIZATION: This product is not considered a skin or respiratory sensitizer.
CARCINOGENICITY: None of the ingredients in this product are listed as carcinogens by the International Agency for
Research on Cancer (IARC), the National Toxicology Program (NTP) or the Occupational Safety and Health
Administration (OSHA).
MUTAGENICITY: None of the ingredients in this product are known to cause mutagenicity.
REPRODUCTIVE/FETAL/DEVELOPMENTAL TOXICITY: None of the ingredients in this product are known as
reproductive, fetal, or developmental hazards.
TARGET ORGAN TOXICITY: None of the ingredients in this product are known to have target organ toxicity.
EPIDEMIOLOGICAL INFORMATION: None of the ingredients in this product are known to have health-related information
in working populations.
COMBAT INSECT CONTROL SYSTEMS 鈥? C/O The Dial Corporation 鈥? 15101 N. Scottsdale Rd 鈥? Scottsdale, AZ 85254
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COMBAT QUICK KILL FORMULA 2 MSDS Y-110 (Rev. 1) May 11, 2007
SECTION 12: ECOLOGICAL INFORMATION
The environmental toxicity of this product has not been evaluated. The active ingredient Fipronil is toxic birds, fish, and
aquatic invertebrates. The following toxicity information is available for the hazardous ingredient when used as technical
grade.
INGREDIENT LC50 / ED50 / SPECIES TOXICITY RATING
AQUATIC VERTEBRATES (FISH)
Fipronil (active ingredient) 96h LC50: 0.248 mg/l (Rainbow trout) Very Toxic
(flow-through test)
AQUATIC INVERTEBRATES
Fipronil (active ingredient) 48h EC50: 0.248 mg/l (Daphnia Very Toxic
magna) flow-through test)
ENVIRONMENTAL FATE: No environmental fate data exists for the product.
PERSISTENCE AND DEGRADABILITY: The persistence and degradability of this product has not been determined.
Fipronil is degraded to Fipronil amide by hydrolysis with a half-life of 28 days (pH 9 and 25掳C).
Water: In water, Fipronil undergoes photolysis with a half-life of 0.151 days (0.9 mg/l at pH 5 and 25掳 Fipronil is also
C).
metabolized in water under anaerobic conditions with half-lives of 116-130 days.
Soil: In loam soil (46% sand, 23% clay, 31% silt) containing 1.73% organic matter, Fipronil undergoes photolysis with a
half-life of 34 days (224 mg/kg at pH 6.7 and 25掳 Fipronil is also metabolized in soil under aerobic conditions with half-
C).
lives of 122-128 and 308-342 days in sandy loam (1.7% organic matter and pH 7.8 at 25掳 and sand (3.3% organic
C)
matter and pH 6.1 at 25掳 respectively. The metabolite under these conditions is 5-amino-3-cyano-1-(2,6-dichloro-4-tri-
C),
fluoromethylphenyl)-4-trifluoromethanesulfonylpyrazole.
BIOACCUMULATION POTENTIAL: The bioaccumulation potential of this product has not been determined.
MOBILITY: The mobility of this product (in soil and water) has not been determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Pesticide wastes may be acutely hazardous. Improper disposal of excess pesticide, spary mixture, or rinsate is a violation
of Federal Law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide
or Environmental Control Agency, or the hazardous waste representative at the nearest EPA Regional Office for guidance.
WASTE NUMBER AND DESCRIPTION: Not applicable, not regulated.
DISPOSAL CONSIDERATIONS: This product is not a RCRA hazardous waste and can be disposed of in accordance with
federal, state and local regulations.
SECTION 14: TRANSPORT INFORMATION
GROUND TRANSPORT
DOT Hazard Class: Not regulated Packing Group: Not applicable
DOT Proper Shipping Name: Insecticide, Non-toxic, Solid Shipping Label Information: Not applicable
UN/NA Number: Not applicable
AIR TRANSPORT (ICAO/IATA) MARINE TRANSPORT (IMDG/IMO)
ICAO/IATA Hazard Class: Not regulated IMDG/IMO Hazard Class: Not regulated
ICAO/IATA Proper Shipping Name: Not applicable IMDG/IMO Proper Shipping Name: Not applicable
SECTION 15: REGULATORY INFORMATION
UNITED STATES:
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200 :
COMBAT INSECT CONTROL SYSTEMS 鈥? C/O The Dial Corporation 鈥? 15101 N. Scottsdale Rd 鈥? Scottsdale, AZ 85254
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COMBAT QUICK KILL FORMULA 2 MSDS Y-110 (Rev. 1) May 11, 2007
The Occupational Safety and Health Administration requires Material Safety Data Sheets to provide any hazards that may
be associated with the product, and make this information available in the workplace. Since the use pattern and exposure
in the workplace are generally not consistent with those experienced by consumers, this MSDS may contain additional
health hazard information not pertinent to consumer use.
EPA - SARA TITLE III SECTION 313: This product contains no materials reportable under this section.
EPA CERCLA/SARA TITLE III SUERFUND AMENDMENT AND REAUTHORIZATION ACT:
This product contains no CERCLA/SARA Title III materials.
TSCA: This product is a registered pesticide and is exempted from listing on the U.S. Toxic Substances Control Act
(TSCA) chemical substance inventory.
FIFRA: EPA Registration Number 64240-34
EPA Establishment Number 071106-GA-001
STATE REGULATIONS
CALIFORNIA PROPOSITION 65: This product does not contain substances listed under California Proposition 65.
CANADA:
This product is not registered for sale or distribution in Canada.
SECTION 16: OTHER INFORMATION
DISCLAIMER: The information contained herein is provided in good faith and is believed to be correct as of the date
hereof. However, The Dial Corporation makes no representation as to the comprehensiveness or accuracy of the
information. It is expected that individuals receiving the information will exercise their independent judgment in
determining its appropriateness for a particular purpose. Accordingly, The Dial Corporation will not be responsible for
damages of any kind resulting from the use of or reliance upon such information. No representations, or warranties, either
expressed or implied of merchantability, fitness for a particular purpose or of any other nature is made hereunder with
respect to the information set forth herein or to the product to which the information refers.
NFPA RATINGS (Scale 0-4, where 4=high degree of hazard): HEALTH=1 FLAMMABILITY=1 REACTIVITY=0
HMIS RATINGS (Scale 0-4, where 4=severe hazard): HEALTH=1 FLAMMABILITY=1 REACTIVITY=0
MSDS CREATION DATE: 11/14/04
SUPERSEDES: Ver. 0, 11/14/04
REVISION DATE: 05/11/07
REVISION: 16-Section MSDS
COMBAT INSECT CONTROL SYSTEMS 鈥? C/O The Dial Corporation 鈥? 15101 N. Scottsdale Rd 鈥? Scottsdale, AZ 85254
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