Date Issued: November, 2004
Supersedes: January, 2004
MATERIAL SAFETY DATA SHEET
ZOECON ALTOSID庐 XR EXTENDED RESIDUAL BRIQUETS
Wellmark International
Manufacturer:
1501 E. Woodfield Rd., Suite 200 West, Schaumburg, IL 60173
Address:
1-800-248-7763
Emergency Phone:
CHEMTREC: 1-800-424-9300
Transportation Emergency Phone:
1. CHEMICAL PRODUCT INFORMATION
Product Name: Zoecon Altosid庐 XR Extended Residual Briquets
(S)-Methoprene; isopropyl (2E,4E,7S)-11-methoxy-3,7,11-trimethyl-2,4-
Chemical Name/Synonym:
dodecadienoate
Terpenoid
Chemical Family:
C19 H34 O3
Formula:
2724-421
EPA Registration No.:
292A
RF Number:
2. COMPOSITION / INFORMATION ON INGREDIENTS
Component (chemical, common name) CAS Weight Tolerance
Number
(S)- Methoprene: Isopropyl (2E,4E,7S)-11-methoxy-3,7,11-trimethyl- 65733-16-6 2.1% Not established
2,4-dodecadienoate
Inert ingredients (non-hazardous and/or trade secret) 97.9%
3. HAZARD INFORMATION
PRECAUTIONARY STATEMENT
Caution: Keep out of the reach of children.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
No adverse reactions have resulted from normal human exposure during research and testing. Adverse animal reactions
to this product have not been shown.
Yes Oral: Yes Inhalation No
PRIMARY ROUTE OF ENTRY Dermal/Eye:
LD50 (rat): >34,000 mg/kg (highest dose level tested)(Based on (S)-
ACUTE TOXICITY Oral:
Methoprene)
LD50 (rabbit): >2,000 mg/kg (Hot) (highest dose level tested) (Based on (S)-
Dermal:
Methoprene)
LC50 (rat): Not applicable to this product form
Inhalation:
OTHER TOXICOLOGICAL INFORMATION
Non-irritating (rabbit) (Based on (S) Methoprene)
Skin Irritation:
Mild/moderate irritation, corneal opacity at 1 hour - all animals clear by 72
Eye Irritation:
hours (rabbit) (Based on (S) Methoprene)
Not a sensitizer (guinea pig) (Based on (S) Methoprene)
Sensitizer:
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4. FIRST AID MEASURES
Hold eye open and flush slowly and gently with water for 15-20 minutes.
Eye:
Remove contact lenses, if present, after the first five minutes, then continue
rinsing eye.
Wash material off with soap and water. Remove contaminated clothing and
Skin:
footwear. See a physician if symptoms persist.
Drink 1-2 glasses of water and try to induce vomiting. Seek medical attention.
Ingestion:
Never give anything by mouth to an unconscious person.
Although this is not a primary route of entry, remove victim to fresh air. See a
Inhalation:
physician if cough or other respiratory symptoms develop
Treat symptomatically
Note to Physician:
5. FIRE FIGHTING MEASURES
NFPA Rating: Health: 0 Fire: 0 Reactivity: 0
N/A
Flammability Class:
Does not flash
Flash Point:
N/A
Explosive Limits (% of Volume):
Water, foam, dry chemical
Extinguishing Media:
Firefighters should wear protective clothing, eye protection, and self contained
Special Protective Equipment:
breathing apparatus.
Normal procedures. Do not allow run-off to enter waterways inhabited by
Fire Fighting Procedures:
aquatic organisms
None known
Combustion Products:
None
Unusual Fire/Explosion Hazards:
6. ACCIDENTAL RELEASE MEASURES
Sweep up material and place in a container for disposal. Do not allow spill to
Steps to be taken:
enter waterways inhabited by aquatic organisms
Not necessary due to product form and packaging
Absorbents:
None
Incompatibles:
7. HANDLING AND STORAGE
Avoid contact with eyes or clothing. Do not remove briquets from container
Handling:
except for immediate use. Avoid breathing dust. Wash thoroughly with soap
and water after handling.
Store in a cool, dry place. Do not contaminate food or feed by storage or
Storage:
disposal. Keep away from children.
8. EXPOSURE CONTROL / PERSONAL MEASURES
Not Applicable
Exposure Limits:
Use with adequate ventilation.
Ventilation:
Under ordinary use conditions, no special protection is required. If prolonged
Personal Protective Equipment:
exposure is expected, it is recommended to wear a MSHA/NIOSH approved
organic vapor/pesticide respirator, impervious gloves, chemical goggles or
safety glasses with side shields.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Grey to black solid with slight hydrocarbon odor.
Appearance and Odor:
N/A
Boiling Point:
N/A
Melting Point:
N/A
Vapor Pressure (mm Hg):
N/A
Vapor Density (Air = 1):
1.8492 g/cc
Specific Gravity:
N/A
Bulk Density:
1 ppm
Solubility:
N/A
Evaporation Rate:
N/A
pH:
10. STABILITY AND REACTIVITY
Stable
Stability:
Non-reactive
Reactivity:
None
Incompatibility w/ Other
Materials:
None
Decomposition Products:
Will not occur
Hazardous Polymerization:
11. TOXICOLOGICAL INFORMATION
CHRONIC TOXICITY [Specific to Active Ingredient(s)]
Methoprene is not considered as an oncogenic compound. The NOEL for non-carcinogen effects in an 18-month mouse
study was 250ppm.
DEVELOPMENTAL/REPRODUCTIVE TOXICITY [Specific to Active Ingredient(s)]
Methoprene is not a teratogenic compound. The NOEL for maternal and embryo toxicity in rabbits was 200/mg/kg/day.
The NOEL for reproductive effects in rats was 500 ppm.
MUTAGENICITY [Specific to Active Ingredient(s)]
Methoprene is not a mutagenic compound.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL FATE [Based on (RS)-Methoprene]
Hydrolysis: T1/2 > 4 weeks
T1/2 < 10 hours
Photolysis:
~ 10 days
Soil half life:
< 2 ppm
Water solubility:
ECOTOXICITY [Based on (S)-Methoprene]
Acute Toxicity: fish:LC50 (trout): 760 ppb, (bluegill): > 370 ppb ((S)-Methoprene); aquatic
invertebrates:LC50 (Daphnia): 360 ppb ((S)-Methoprene This product is toxic
to aquatic dipteran. )
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13. DISPOSAL CONSIDERATIONS
Dispose of empty bag in sanitary landfill or by incineration, or, if allowed by state and local authorities, by burning. If
burned, stay out of smoke.
14. TRANSPORT INFORMATION
Not regulated as hazardous by D.O.T.
DOT49CFR Description:
Insecticides, NOI other than poison in boxes or drums. NMFC 102120
Freight Classification:
15. REGULATORY INFORMATION
Not regulated
CERCLA (Superfund):
Not regulated as hazardous
RCRA:
SARA 311/312 HAZARD CATEGORIES
Immediate Health: Yes (irritation)
No
Delayed Health:
No
Fire:
No
Sudden Pressure:
No
Reactivity:
The information presented herein, while not guaranteed, was prepared by technically knowledgeable personnel and to the
best of our knowledge is true and accurate. It is not intended to be all inclusive and the manner and conditions of use and
handling may involve other or additional considerations.
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