MATERIAL SAFETY DATA SHEET
GCD 110 Developer (Class 10)
1. PRODUCT AND COMPANY IDENTIFICATION
GCD 110 Developer (Class 10)
PRODUCT NAME:
None known
OTHER/GENERIC NAMES:
Solvent for negative photoresists.
PRODUCT USE:
MANUFACTURER:
General Chemical Corp
90 East Halsey Rd.
Parsippany, NJ 07054
FOR MORE INFORMATION CALL:
(Monday-Friday, 9:00am-4:30pm) 973-515-1840
IN CASE OF EMERGENCY CALL:
(24 Hours/Day, 7 Days/Week) 800-631-8050
2. COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT NAME/ WEIGHT % OSHA PEL
CAS NUMBER
NAPHTHA (PETROLEUM), None
100
HYDROTREATED HEAVY
64742-48-9
Trace impurities and additional material names not listed above may also appear in Section 15 towards the end of the
MSDS. These materials may be listed for local "Right-to-Know" compliance and for other reasons.
This product is considered hazardous under the OSHA Hazard
OSHA Hazard Communication Standard:
Communication Standard.
3. HAZARDS IDENTIFICATION
Clear liquid. Petroleum odor. May irritate eyes and skin. Harmful
EMERGENCY OVERVIEW:
if swallowed. Do not get in eyes, on skin, or on clothing. Avoid breathing vapors. Flammable Liquid.
POTENTIAL HEALTH HAZARDS:
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May cause moderate skin irritation. May cause skin defatting with prolonged
SKIN:
exposure.
May cause mild eye irritation.
EYES:
May irritate nose, throat and lungs. Excessive inhalation causes headache,
INHALATION:
dizziness, nausea and incoordination. Aspiration into the lungs may cause
potentially fatal chemical pneumonitis.
May cause irritation of the mouth, throat and stomach. Aspiration can be a hazard
INGESTION:
if this material is swallowed.
Long-term exposure to naphthas and aromatic solvents has been associated with
DELAYED EFFECTS:
brain damage, characterized by memory loss and personality changes.
Ingredients found on one of the three OSHA designated carcinogen lists are listed below.
INGREDIENT NAME/ WEIGHT % NTP STATUS IARC STATUS OSHA LIST:
CAS NUMBER
NAPHTHA (PETROLEUM), 100 Not listed Not listed Not listed
HYDROTREATED HEAVY
64742-48-9
4. FIRST AID MEASURES
Immediately flush skin with plenty of water for at least 15 minutes. Remove
SKIN:
contaminated clothing and launder before reuse. Get medical attention.
In case of contact, immediately flush eyes with plenty of water for at least 15
EYES:
minutes and get medical attention if irritation persists.
If inhaled, remove from area to fresh air. Get medical attention if respiratory
INHALATION:
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MATERIAL SAFETY DATA SHEET
GCD 110 Developer (Class 10)
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irritation develops or if breathing becomes difficult.
Get immediate medical attention. Do not induce vomiting. Never give anything by
INGESTION:
mouth to an unconscious person.
Treat symptomatically.
ADVICE TO PHYSICIAN:
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
102-128F (39-53C)
FLASH POINT:
Tag Closed Cup
FLASH POINT METHOD:
-495F (-293C)
AUTOIGNITION TEMPERATURE:
7%
UPPER FLAME LIMIT (volume % in air):
0.7%
LOWER FLAME LIMIT (volume % in air):
Not determined.
FLAME PROPAGATION RATE (solids):
Flammable.
OSHA FLAMMABILITY CLASS:
EXTINGUISHING MEDIA:
Water fog, carbon dioxide, foam, dry chemical
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Vapors may be ignited by sparks, flames or other sources of ignition. Vapors may travel to a source of ignition and
flash back.
SPECIAL FIRE-FIGHTING PRECAUTIONS/INSTRUCTIONS:
Wear approved positive-pressure self-contained breathing apparatus and protective clothing.
6. ACCIDENTAL RELEASE MEASURES
IN CASE OF SPILL OR OTHER RELEASE: (See Section 8 for recommended personal protective equipment.)
Remove sources of ignition. Absorb spill with inert material and place in containers for later disposal.
Spills and releases may have to be reported to Federal and/or local authorities. See Section 15 regarding
reporting requirements.
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7. HANDLING AND STORAGE
NORMAL HANDLING: (See section 8 for recommended personal protective equipment.)
Avoid contact with skin, eyes and clothing. Avoid breathing mist or vapor. Bond and ground containers during
transfer operations. Use only non-sparking tools and equipment.
STORAGE RECOMMENDATIONS:
Store in a cool, dry, well-ventilated area away from sources of ignition. Keep containers tightly closed. Outside
storage preferred. If stored inside, store in a standard flammable liquids storage room or cabinet.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Local exhaust ventilation designed for explosive atmospheres.
ENGINEERING CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT
Wear rubber gloves and protective clothing.
SKIN PROTECTION:
Wear chemical safety goggles.
EYE PROTECTION:
RESPIRATORY PROTECTION:Use approved NIOSH respiratory protection if TLV exceeded..... Or over exposure
is likely.
Provide eyewash stations and quick-drench shower facilities in or near areas of
ADDITIONAL
use or handling.
RECOMMENDATIONS:
EXPOSURE GUIDELINES
INGREDIENT NAME/ WEIGHT % ACGIH TLV OSHA PEL OTHER LIMIT
CAS NUMBER
NAPHTHA (PETROLEUM), 100 400 ppm 8-hr TWA (for None None
HYDROTREATED HEAVY petroleum naphtha)
64742-48-9
鹿 = Limit established by General Chemical Corporation.
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虏 = Workplace Environmental Exposure Level (AIHA).
鲁 = Biological Exposure Index (ACGIH).
OTHER EXPOSURE LIMITS FOR POTENTIAL DECOMPOSITION PRODUCTS:
None.
9. PHYSICAL AND CHEMICAL PROPERTIES
Clear liquid
APPEARANCE:
Liquid
PHYSICAL STATE:
149.00
MOLECULAR WEIGHT:
Mixture
CHEMICAL FORMULA:
Mild hydrocarbon odor.
ODOR:
0.74-0.76
SPECIFIC GRAVITY (water=1.0):
Insoluble
SOLUBILITY IN WATER (weight %):
Not applicable.
pH:
313-380F (156-193C)
BOILING POINT:
Not applicable
MELTING POINT:
<10 mm Hg
VAPOR PRESSURE:
5.00
VAPOR DENSITY (air=1.0):
0.3 n-butyl acetate
EVAPORATION RATE: COMPARED TO:
100
% VOLATILES:
102-128F (39-53C)
FLASH POINT:
(Flash point method and additional flammability data are found in Section 5.)
10. STABILITY AND REACTIVITY
NORMALLY STABLE? (CONDITIONS TO AVOID):
Normally stable. Static discharges may cause ignition at temperatures at or above the flash point.
INCOMPATIBILITIES:
Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon dioxide. Carbon monoxide.
HAZARDOUS POLYMERIZATION:
Will not occur.
11. TOXICOLOGICAL INFORMATION
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GCD 110 Developer (Class 10)
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IMMEDIATE (ACUTE) EFFECTS:
For petroleum, naphtha:
LD50 (oral-rat): >5 gm/kg
LD50 (dermal-rabbit): >3 gm/kg
DELAYED (SUBCHRONIC AND CHRONIC) EFFECTS:
Data not available.
OTHER DATA:
Data not available.
12. ECOLOGICAL INFORMATION
Data not available.
13. DISPOSAL CONSIDERATIONS
RCRA
Yes
Is the unused product a RCRA hazardous waste if discarded?
D001 (ignitable)
If yes, the RCRA ID number is:
OTHER DISPOSAL CONSIDERATIONS:
Disposal should be made in accordance with federal, state and local regulations.
The information offered in section 13 is for the product as shipped. Use and/or alterations to the products such as mixing
with other materials may significantly change the characteristics of the material and alter the RCRA classification and the
proper disposal method.
14. TRANSPORT INFORMATION
3
US DOT HAZARD CLASS:
Hydrocarbons, liquid, n.o.s. (isoparaffinic hydrocarbons), UN 3295, PG III
PROPER SHIPPING NAME:
For additional information on shipping regulations affecting this material, contact the information number found in Section
1.
15. REGULATORY INFORMATION
TOXIC SUBSTANCES CONTROL ACT (TSCA)
Listed on Inventory: YES
TSCA INVENTORY STATUS:
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GCD 110 Developer (Class 10)
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All components of this product are listed on the TSCA Inventory.
OTHER TSCA ISSSUES:
SARA TITLE III/CERCLA:
"Reportable Quantities (RQs) and/or "Threshold Planning Quantities (TPQs) exist for the following ingredients.
INGREDIENT NAME/ WEIGHT % SARA/CERCLA RQ (lb): SARA EHS TPQ (lb)
CAS NUMBER
NAPHTHA (PETROLEUM), 100 None None
HYDROTREATED HEAVY
64742-48-9
Spills or releases resulting in the loss of any ingredient at or above its RQ requires immediate notification to the
National Response Center [(800) 424-8802] and to your Local Emergency Planning Committee.
Immediate. Fire.
SECTION 311 HAZARD CLASS:
SARA 313 TOXIC CHEMICALS:
The following ingredients are SARA 313 "Toxic Chemicals" and may be subject to annual reporting requirements. CAS
numbers and weight percents are found in Section 2.
INGREDIENT NAME/ WEIGHT % COMMENT
CAS NUMBER
NAPHTHA (PETROLEUM), Not listed.
100
HYDROTREATED HEAVY
64742-48-9
STATE RIGHT-TO-KNOW:
The following are listed for state right-to-know purposes.
INGREDIENT NAME/ WEIGHT % NJ RIGHT-TO-KNOW: MA RIGHT-TO-KNOW: PA RIGHT-TO-KNOW:
CAS NUMBER
NAPHTHA (PETROLEUM), 100 Not listed Not listed Not listed
HYDROTREATED HEAVY
64742-48-9
ADDITIONAL REGULATORY INFORMATION:
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MATERIAL SAFETY DATA SHEET
GCD 110 Developer (Class 10)
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None.
16. OTHER INFORMATION
01/01/2001
CURRENT ISSUE DATE:
CHANGES TO MSDS FROM PREVIOUS ISSUE DATE ARE DUE TO THE FOLLOWING :
Not applicable - new MSDS.
OTHER INFORMATION:
None.
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