DOW CHEMICAL CANADA INC.
MATERIAL SAFETY DATA SHEET
Product Name: TRITON(TM) X-100 SURFACTANT Effective Date: 2001.09.18
MSDS#: 2207 Page 1 of 15
Dow (hereinafter, and for purposes of this MSDS only, refers to The Dow Chemical Company and to Dow
Chemical Canada Inc.) encourages and expects you to read and understand the entire MSDS, as there is
important information throughout the document. Dow expects you to follow the precautions identified in
this document unless your use conditions would necessitate other appropriate methods or actions.
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
1.1 IDENTIFICATION
Product Name TRITON(TM) X-100 SURFACTANT
1.2 COMPANY IDENTIFICATION
Supplier:
Dow Chemical Canada Inc.
1425 S. Vidal Street, P.O. Box 3030
Sarnia, Ontario N7T 8C6
Prepared By: Prepared for use in Canada by EH&S, Product Regulatory
Management Department.
Print Date: 2002 02 27
1.3 EMERGENCY TELEPHONE NUMBER
24-HOUR EMERGENCY PHONE NUMBER: (519) 339-3711
Customer Information Number: 1-800-331-6451
* or 庐 Indicates a Trademark of The Dow Chemical Company.
MATERIAL SAFETY DATA SHEET
Product Name: TRITON(TM) X-100 SURFACTANT Effective Date: 2001.09.18
MSDS#: 2207 Page 2 of 15
2. COMPOSITION INFORMATION
Component CAS # %W/W Hazard
Glycols, polyethylene, 9036-19-5 >= 97 <= 100% toxic
mono[(1,1,3,3-
tetramethylbutyl)phenyl] ether
Polyethylene glycol 25322-68-3 < 3% WHMIS: not hazardous
3. HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Appearance Transparent pale yellow
Liquid
Physical
State
Odor Mild
DANGER! CAUSES EYE BURNS.
Hazards of
HARMFUL IF SWALLOWED.
product
CAUSES SKIN IRRITATION.
PLASTIC CONTAINER, IF PRESENT, MAY CAUSE
STATIC IGNITION HAZARD.
ASPIRATION MAY CAUSE LUNG DAMAGE.
3.2 POTENTIAL HEALTH EFFECTS
Potential Effects of a Single Acute Exposure
Inhalation Mist may cause irritation of the respiratory tract, experienced as nasal discomfort and
discharge, with chest pain and coughing.
MATERIAL SAFETY DATA SHEET
Product Name: TRITON(TM) X-100 SURFACTANT Effective Date: 2001.09.18
MSDS#: 2207 Page 3 of 15
Eye Contact Causes severe irritation, experienced as discomfort or pain, excess blinking and tear
production, marked excess redness and swelling of the conjunctiva, and chemical burns of the cornea.
Iritis may occur.
Skin Contact Brief contact is not irritating. Prolonged or repeated contact may cause discomfort and
local redness.
Skin Absorption No evidence of harmful effects from available information.
Swallowing Moderately toxic. May cause abdominal discomfort, nausea, vomiting, and diarrhea.
Aspiration into the lungs may occur during ingestion or vomiting, resulting in lung injury.
Chronic, Prolonged or Repeated Exposure
Potential Effects of Repeated Exposure No adverse effects anticipated from available
information.
Other Potential Effects of Exposure None currently known.
Medical Conditions Aggravated by Exposure
A knowledge of the available toxicology information and of the physical and chemical properties
of the material suggests that exposure is unlikely to aggravate existing medical conditions.
3.3 POTENTIAL ENVIRONMENTAL EFFECTS
Toxic to aquatic organisms.
4. FIRST AID PROCEDURES
4.1 INHALATION
If any symptoms develop, remove to fresh air.
4.2 EYE CONTACT
Immediately flush eyes with water and continue washing for at least 15 minutes. DO NOT
remove contact lenses, if worn. Obtain medical attention without delay, preferably from an
ophthalmologist.
4.3 SKIN CONTACT
Remove contaminated clothing. Wash skin with soap and water. Obtain medical attention if
irritation persists. Wash clothing before reuse.
4.4 SWALLOWING
MATERIAL SAFETY DATA SHEET
Product Name: TRITON(TM) X-100 SURFACTANT Effective Date: 2001.09.18
MSDS#: 2207 Page 4 of 15
If patient is fully conscious, give two glasses of water. DO NOT INDUCE VOMITING. Obtain
medical attention.
4.5 NOTES TO PHYSICIAN
There is no specific antidote. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.
Any material aspirated during vomiting may cause lung injury. Therefore, emesis should not be
induced mechanically or pharmacologically. If it is considered necessary to evacuate the
stomach contents, this should be done by means least likely to cause aspiration (e.g., gastric
lavage after endotracheal intubation).
5. FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Flash Point - Closed Cup: Pensky-Martens Closed Cup ASTM D 93 251 掳C 485 掳F
Flash Point - Open Cup: Cleveland Open Cup ASTM D 92 290 掳C 555 掳F
Autoignition Temperature: Not currently available.
Flammable Limits In Air:
Lower Not determined.
Upper Not determined.
5.2 EXTINGUISHING MEDIA
Extinguish fires with water spray or apply alcohol-type or all-purpose-type foam by
manufacturer's recommended techniques for large fires. Use carbon dioxide or dry chemical
media for small fires.
5.3 EXTINGUISHING MEDIA TO AVOID
No information currently available.
5.4 SPECIAL FIRE FIGHTING PROCEDURES
Do not direct a solid stream of water or foam into hot, burning pools; this may cause frothing and
increase fire intensity.
5.5 SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Use self-contained breathing apparatus and protective clothing.
5.6 UNUSUAL FIRE AND EXPLOSION HAZARDS
See Section 8.3 - Engineering Controls
MATERIAL SAFETY DATA SHEET
Product Name: TRITON(TM) X-100 SURFACTANT Effective Date: 2001.09.18
MSDS#: 2207 Page 5 of 15
This material may produce a floating fire hazard.
5.7 HAZARDOUS COMBUSTION PRODUCTS
Burning can produce the following products: Carbon monoxide and/or carbon dioxide. Carbon
monoxide is highly toxic if inhaled; carbon dioxide in sufficient concentrations can act as an
asphyxiant.
6. ACCIDENTAL RELEASE MEASURES
Steps to be Taken if Material is Released or Spilled:
Contain spills immediately with inert materials (e.g., sand, earth). Transfer liquids and solid
diking material to suitable containers for recovery or disposal. To avoid gelling and foaming
problems, do not use water to flush away spills.
Personal Precautions: Wear eye and skin protection. Floor may be slippery; use care to avoid
falling. See Section 8.2 - Personal Protection.
Environmental Precautions: Avoid discharge to natural waters.
7. HANDLING AND STORAGE
7.1 HANDLING
General Handling
Do not get in eyes.
Do not swallow.
Avoid contact with skin and clothing.
Do not handle or empty in presence of flammable vapor.
Keep container closed.
Use with adequate ventilation.
Wash thoroughly after handling.
FOR INDUSTRY USE ONLY.
Ventilation
General (mechanical) room ventilation is expected to be satisfactory.
Other Precautions
This product may contain trace amounts of ethylene oxide (CAS No. 75-21-8), a condition which
creates the potential for accumulation of ethylene oxide in the head space of shipping and
storage containers and in enclosed areas where the product is being handled or used. Ethylene
oxide is listed by OSHA as probably carcinogenic to humans, IARC as carcinogenic to humans,
MATERIAL SAFETY DATA SHEET
Product Name: TRITON(TM) X-100 SURFACTANT Effective Date: 2001.09.18
MSDS#: 2207 Page 6 of 15
and NTP as known to be a human carcinogen. OSHA considers that, at excessive levels,
ethylene oxide may present reproductive, mutagenic, genotoxic, neurologic and sensitization
hazards. If this product is handled with adequate ventilation, the presence of these trace
amounts is not expected to result in any short or long term hazard. Personnel should be
monitored to determine levels of exposure to ethylene oxide. If necessary, protective measures
should be taken. The ACGIH TLV is 1 ppm TWA8.
7.2 STORAGE
Store in accordance with good industrial practices. Storage information may be obtained from
product-specific Storage and Handling Guides, or by calling Dow's Customer Information Group
at 1-800-258-2436 (U.S.) or 1-800-331-6451 (Canada).
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
8.1 EXPOSURE LIMITS
Polyethylene glycol 10 mg/m3 TWA8 AIHA WEEL Aerosol
There are no ACGIH or Dow exposure limits for this product; however, consult local authorities
for recommended exposure limits.
8.2 PERSONAL PROTECTION
Respiratory None expected to be needed. However, where misting may occur,
wear a MSHA/NIOSH approved (or equivalent) half-mask air purifying
Protection:
respirator.
Ventilation: General (mechanical) room ventilation is expected to be satisfactory.
Monogoggles
Eye Protection:
Polyvinyl chloride coated
Protective
Gloves:
Other Protective Eye bath, safety shower, chemical apron.
Equipment:
8.3 ENGINEERING CONTROLS
Surfactants can cause foaming problems in biological wastewater treatment plants and other
high shear operations.
MATERIAL SAFETY DATA SHEET
Product Name: TRITON(TM) X-100 SURFACTANT Effective Date: 2001.09.18
MSDS#: 2207 Page 7 of 15
PROCESS HAZARD: Sudden release of hot organic chemical vapor or mists from process
equipment operating at elevated temperature and pressure, or sudden ingress of air into hot
equipment under a vacuum, may result in ignitions without the presence of obvious ignition
sources. Published "autoignition" or "ignition" temperature values cannot be treated as safe
operating temperatures in chemical processes without analysis of the actual process conditions.
Any use of this product in elevated-temperature processes should be thoroughly evaluated to
establish and maintain safe operating conditions. Further information is available in a technical
bulletin entitled "Ignition Hazards of Organic Chemical Vapor."
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Appearance: Transparent pale yellow
pH: 9.7
Solubility in Water (by weight): Completely soluble but some compositions may
form gels
Odor: Mild
Flash Point - Closed Cup: Pensky-Martens Closed Cup ASTM D 93 251 掳C 485 掳F
Flash Point - Open Cup: Cleveland Open Cup ASTM D 92 290 掳C 555 掳F
Percent Volatiles: 0.0065 Wt%
Molecular Weight: 624 g/mol (Average)
Boiling Point (760 mmHg): > 200 掳C > 392 掳F
Freezing Point: 6 掳C 43 掳F
Specific Gravity (H2O = 1): 1.067 20 掳C / 20 掳C
Vapor Pressure: 20 掳C < 0.01 mmHg
Vapor Density (air = 1): >1
Evaporation Rate (Butyl Acetate = 1): < 0.01
Melting Point: Not applicable.
MATERIAL SAFETY DATA SHEET
Product Name: TRITON(TM) X-100 SURFACTANT Effective Date: 2001.09.18
MSDS#: 2207 Page 8 of 15
10. STABILITY AND REACTIVITY
10.1 STABILITY/INSTABILITY Stable
Conditions to Avoid: Prolonged excessive heat may cause product decomposition.
Incompatible Materials: Normally unreactive; however, avoid strong bases at high
temperatures, strong acids, strong oxidizing agents and materials reactive with hydroxyl
compounds.
10.2 HAZARDOUS POLYMERIZATION Will not occur.
10.3 INHIBITORS/STABILIZERS Not applicable.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Peroral
Rat; female; LD50 = 707 (402 - 1240) mg/kg
Major Signs: sluggishness, unsteady gait, labored breathing, lacrimation, prostration,
piloerection, encrustation on perinasal fur
Gross Pathology: lungs and liver discolored; stomach and intestines liquid-filled
Peroral
Rat; male = 500 mg/kg
Mortality: 0/3
MATERIAL SAFETY DATA SHEET
Product Name: TRITON(TM) X-100 SURFACTANT Effective Date: 2001.09.18
MSDS#: 2207 Page 9 of 15
Major Signs: sluggishness, unsteady gait, labored breathing, lacrimation, prostration,
piloerection, encrustation on perinasal fur
Gross Pathology: lungs and liver discolored; stomach and intestines liquid-filled
Percutaneous
Rabbit; female; LD50 = 12.3 (9.13 - 16.7) g/kg; 24 h occluded.
Major Signs: sluggishness, labored breathing, gasping, wetness or staining on perioral and
perinasal fur, emaciation
Gross Pathology: lungs, liver, kidneys and spleen discolored
Percutaneous
Rabbit; male = 8.0 g/kg; 24 h occluded.
Mortality: 2/3
Major Signs: sluggishness, labored breathing, gasping, wetness or staining on perioral and
perinasal fur, emaciation
Gross Pathology: lungs, liver, kidneys and spleen discolored
IRRITATION
Skin: Rabbit; 4 h occluded
Results: minor to moderate erythema, minor edema
Eye: Rabbit; 0.1 ml
Results: minor to severe corneal injury with vascularization, iritis, moderate to severe
conjunctival irritation with purulent discharge
Eye: Rabbit; 0.01 ml
Results: severe corneal injury, severe iritis and conjunctival irritation
SIGNIFICANT DATA WITH POSSIBLE RELEVANCE TO HUMANS
Rats fed dietary concentrations of the 40-mole ethoxylate of octylphenol(OPE40) up to 14000
ppm (700 mg/kg/day) for two years showed no adverse effects on growth or survival, feed
consumption, hematologic values, urine measurements, organ weights or histopathologic
lesions. In two-year feeding studies for related alkylphenol ethoxylates, the 4-mole ethoxylate of
nonylphenol (NPE4) at doses of 200 mg/kg/day or 40 mg/kg/day in rats and dogs, respectively,
MATERIAL SAFETY DATA SHEET
Product Name: TRITON(TM) X-100 SURFACTANT Effective Date: 2001.09.18
MSDS#: 2207 Page 10 of 15
produced no significant effects. The 9-mole ethoxylate (NPE9) at doses of 140 or 30 mg/kg/day
in the diet of rats or dogs, respectively, produced no adverse effects. Parameters evaluated
included body and organ weights and histopathology of 28 tissues. A dose of 1000 mg/kg/day of
NPE9 resulted in reduced body weights and enlarged livers in rats and reduced weight, emesis,
and minimal blood changes in dogs. A dose of 88 mg/kg/day NPE9 produced increased liver to
body weight ratios in dogs which was attributed to decreased feed consumption.
Alkylphenol Ethoxylate Toxicity: In studies with rabbits, sustained occluded skin contact of
undiluted similar material caused inflammatory changes in the lung. Developmental effects
including extra ribs and other skeletal variations were observed in the fetuses of rats treated with
maternally toxic levels of a 9-mole ethoxylate of octylphenol, or a 4-mole or 9-mole ethoxylate of
nonylphenol. The significance of these findings to humans is unclear as several human studies
did not show any association of congenital effects in children with maternal exposure to
spermicides containing octyl or nonylphenol ethoxylates. Alkylphenol Toxicity: In a 2-generation
reproduction study with octylphenol at dietary concentrations of 0.2 to 2000 ppm, treatment-
related effects in adult F0, F1, and F2 animals were limited to reduced body weights and food
consumption at 2000 ppm. No effects on any reproductive parameters were observed in either
generation. No effects on sperm measurements, estrous cyclicity, or reproductive organs were
observed in adult animals. Pup body weights during lactation were reduced at 2000 ppm. The
NOAEL for systemic and postnatal toxicity was 200 ppm (approximately 15 mg/kg/day) and for
reproductive toxicity was >2000 ppm (approximately 150 mg/kg/day). Although octylphenol has
weak estrogen mimetic activity in some screening assays, no estrogenic or reproductive effects
occurred from dietary exposure to rats for two generations over a 10,000 fold dose range.
12. ECOLOGICAL INFORMATION
12.1 ENVIRONMENTAL FATE
BOD (% Oxygen consumption)
Day 5 Day 10 Day 15 Day 20 Day 30
30 % 40 % 49 % 51 %
STURM (% Carbon dioxide evolved)
Day 5 Day 10 Day 15 Day 28
70 %
Closed Bottle BOD (% Oxygen consumption)
Day 5 Day 10 Day 15 Day 28
11 % 34 % 36 %
MATERIAL SAFETY DATA SHEET
Product Name: TRITON(TM) X-100 SURFACTANT Effective Date: 2001.09.18
MSDS#: 2207 Page 11 of 15
DOC (% dissolved organic carbon disappearance)
Day 7 Day 14 Day 21 Day 28
58 % 62 % 80 % 90 %
12.2 ECOTOXICITY
Toxicity to Micro-organisms
Bacterial Inhibition; IC50
Result value: 5000 mg/l
Toxicity to Aquatic Invertebrates
Daphnia; 48 h; LC50
Result value: 26 mg/l
Toxicity to Aquatic Invertebrates
Daphnia; 48 h; NOEC
Result value: 18 mg/l
Toxicity to Aquatic Invertebrates
Daphnia; 48 h; NOEC
Result value: 18 mg/l
Toxicity to Fish
Fathead Minnow; 96 h; NOEC
Result value: 3.2 mg/l
Toxicity to Fish
Fathead Minnow; 96 h; LC50
Result value: 8.9 mg/l
12.3 FURTHER INFORMATION
Based on available data for related alkylphenol ethoxylate (APE), appropriate treatment of
effluents will reduce levels of octylphenol ethoxylate (OPE) residues to concentrations that
should pose no harm to the environment, including protection for weak estrogen-mimetic activity
observed in laboratory studies for some degradation intermediates.
Chemical Oxygen Demand (COD) - measured: 2.18 mg/mg
Chemical Oxygen Demand (COD) - measured: 2.19 mg/mg
MATERIAL SAFETY DATA SHEET
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13. DISPOSAL CONSIDERATIONS
13.1 DISPOSAL
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER.
All disposal practices must be in compliance with all Federal, State/Provincial and local laws and
regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. DOW HAS
NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING
PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION
PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED
CONDITION AS DESCRIBED IN MSDS SECTION 2 (Composition/ Information On Ingredients).
FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a
licensed, permitted: incinerator or other thermal destruction device. waste water treatment
system. As a service to its customers, Dow can provide names of information resources to help
identify waste management companies and other facilities which recycle, reprocess or manage
chemicals or plastics, and that manage used drums. Telephone Dow's Customer Information
Group at 1-800-258-2436 or 1-989-832-1556 (U.S.), or 1-800-331-6451 (Canada) for further
details .
Disposal methods identified are for the product as sold. For proper disposal of used material, an
assessment must be completed to determine the proper and permissible waste management
options permissible under applicable rules, regulations and/or laws governing your location.
14. TRANSPORT INFORMATION
14.1 TDG - CANADA
SMALL CONTAINER
Proper Shipping Name : NOT REGULATED
LARGE CONTAINER
Proper Shipping Name : NOT REGULATED
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Additional transportation system information
can be obtained through an authorized sales or customer service representative. It is the
responsibility of the transporting organization to follow all applicable laws, regulations and rules
relating to the transportation of the material.
MATERIAL SAFETY DATA SHEET
Product Name: TRITON(TM) X-100 SURFACTANT Effective Date: 2001.09.18
MSDS#: 2207 Page 13 of 15
15. REGULATORY INFORMATION
15.1 FEDERAL/PROVINCIAL
HAZARDOUS P RODUCTS ACT INFORMATION: WHMIS CLASSIFICATION
The WHMIS classification for this product is as follows. Also, refer elsewhere in the MSDS for
specific warnings and safe handling information; and refer to your employer's workplace
education program.
Toxic Materials Causing
D2B Other Effects
HAZARDOUS P RODUCTS ACT INFORMATION: HAZARDOUS INGREDIENTS
This product contains the following ingredients which are Controlled Products and/or are on the
Ingredient Disclosure List (Canadian HPA Section 13 and 14)., Multiple ranges allow for
variations in product composition due to variations in the manufacture of the product.
Component CAS # Amount
Glycols, polyethylene, mono[(1,1,3,3- 9036-19-5 >= 97.0000 <=
tetramethylbutyl)phenyl] ether 100.0000%
HAZARDOUS P RODUCTS ACT INFORMATION: CPR COMPLIANCE
This product has been classified in accordance with the hazard criteria of the Canadian
Controlled Products Regulations (CPR) and the MSDS contains all the information
required by the CPR.
TOXIC SUBSTANCES CONTROL ACT (TSCA)
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory
requirements.
EUROPEAN I NVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES (EINECS)
MATERIAL SAFETY DATA SHEET
Product Name: TRITON(TM) X-100 SURFACTANT Effective Date: 2001.09.18
MSDS#: 2207 Page 14 of 15
The components of this product are on the EINECS inventory or are exempt from EINECS
inventory requirements.
CEPA - DOMESTIC SUBSTANCES LIST (DSL)
All substances contained in this product are listed on the Canadian Domestic Substances List
(DSL) or are not required to be listed.
VOC: Vapor pressure <0.01 mmHg @ 20掳 C
0 g/L
This section provides selected regulatory information on this product including its components.
This is not intended to include all regulations. It is the responsibility of the user to know and
comply with all applicable rules, regulations and laws relating to the product being used.
16. OTHER INFORMATION
16.1 ADDITIONAL INFORMATION
ADDITIONAL INFORMATION: Additional product safety information on this product may be
obtained by calling Dow's Customer Information Group at 1-800-258-2436 (U.S.) or 1-800-331-
6451 (Canada).
16.2 HAZARD RATING SYSTEM
NFPA ratings for this product are: H - 3 F- 1 R-0
These ratings are part of a specific hazard communication program and should be disregarded
where individuals are not trained in the use of this hazard rating system. You should be familiar
with the hazard communication programs applicable to your workplace.
16.3 RECOMMENDED USES AND RESTRICTIONS
MATERIAL SAFETY DATA SHEET
Product Name: TRITON(TM) X-100 SURFACTANT Effective Date: 2001.09.18
MSDS#: 2207 Page 15 of 15
NOTICE! NOT TO BE USED AS A BIOCIDE IN INTRAVAGINAL END-USE APPLICATIONS
(INCLUDING SPERMICIDES). FOR INDUSTRY USE ONLY.
Cleaning agent
FOR INDUSTRY USE ONLY
16.4 REVISION
Version: 6.
Revision: 2001.09.18
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
16.5 LEGEND
Bacterial/NA Non Acclimated Bacteria
F Fire
H Health
N/A Not available
NFPA National Fire Protection Association
O Oxidizer
R Reactivity
TS Trade secret.
VOL/VOL Volume/Volume
W Water Reactive
W/W Weight/Weight
NOTICE: Dow urges each customer or recipient of this MSDS to study it carefully and consult
appropriate expertise, as necessary or appropriate, to become aware of and understand the data
contained in this MSDS and any hazards associated with the product. The information herein is
provided in good faith and believed to be accurate as of the effective date shown above.
However, no warranty, express or implied, is given., Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure
that its activities comply with all federal, state, provincial or local laws. The information
presented here pertains only to the product as shipped. Since conditions for use of the product
are not under the control of Dow, it is the buyer's/user's duty to determine the conditions
necessary for the safe use of this product., Due to the proliferation of sources for information
such as manufacturer-specific MSDSs, Dow is not and cannot be responsible for MSDSs
obtained from any source other than Dow. If you have obtained a Dow MSDS from a non-Dow
source or if you are not sure that a Dow MSDS is current, please contact Dow for the most
current version.
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