3M MATERIAL SAFETY DATA SHEET 3M Fire Barrier Water Tight Sealant 1000 NS and 1003 SL 03/22/2006
Material Safety Data Sheet
Copyright, 2006, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
3M Fire Barrier Water Tight Sealant 1000 NS and 1003 SL
PRODUCT NAME:
3M
MANUFACTURER:
Building Safety Solutions Dept
DIVISION:
3M Center
ADDRESS:
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 03/22/2006
Supercedes Date: 03/13/2006
Document Group: 08-8510-3
Product Use:
Specific Use: Sealant Used For Fire Protection
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
Calcium Carbonate 1317-65-3 15 - 40
Siloxanes and Silcones, Di-Me, Hydroxy-Terminated 70131-67-8 25 - 35
Poly(Dimethylsiloxane) 63148-62-9 20 - 25
Ketoxime Silane 22984-54-9 3- 7
Amorphous Silica 7631-86-9 0.5 - 4.5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Paste
Odor, Color, Grade: Low odor, thixotropic caulk
General Physical Form: Solid
Immediate health, physical, and environmental hazards: May cause allergic skin reaction.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.
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3M MATERIAL SAFETY DATA SHEET 3M Fire Barrier Water Tight Sealant 1000 NS and 1003 SL 03/22/2006
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Target Organ Effects:
Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give
anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
Not Applicable
OSHA Flammability Classification:
5.2 EXTINGUISHING MEDIA
Non-combustible. Choose material suitable for surrounding fire.
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Not applicable.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
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3M MATERIAL SAFETY DATA SHEET 3M Fire Barrier Water Tight Sealant 1000 NS and 1003 SL 03/22/2006
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Ventilate the area with fresh air. Collect as much of the spilled material as possible.
Clean up residue with detergent and water. Place in a closed container approved for transportation by appropriate authorities. Dispose
of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid contact with
oxidizing agents. For industrial or professional use only.
7.2 STORAGE
Store away from acids. Store away from oxidizing agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact.
The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin Protection
Avoid prolonged or repeated skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Polyvinyl Chloride.
8.2.3 Respiratory Protection
Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
Calcium Carbonate ACGIH TWA 10 mg/m3
Calcium Carbonate OSHA TWA, respirable 5 mg/m3 Table Z-1
Calcium Carbonate OSHA TWA, as total dust 15 mg/m3 Table Z-1
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3M MATERIAL SAFETY DATA SHEET 3M Fire Barrier Water Tight Sealant 1000 NS and 1003 SL 03/22/2006
Amorphous Silica CMRG TWA, as respirable 3 mg/m3
dust
TIN, ORGANIC COMPOUNDS ACGIH TWA, as Sn 0.1 mg/m3 Skin Notation*; Table A4
TIN, ORGANIC COMPOUNDS ACGIH STEL, as Sn 0.2 mg/m3 Skin Notation*
TIN, ORGANIC COMPOUNDS OSHA TWA, as Sn 0.1 mg/m3 Skin Notation*; Table Z-1A
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,
either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Paste
Specific Physical Form:
Low odor, thixotropic caulk
Odor, Color, Grade:
Solid
General Physical Form:
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
1.32 [Ref Std: WATER=1]
Specific Gravity
No Data Available
Melting point
Nil
Solubility in Water
16 g/l
Volatile Organic Compounds
1.2 %
Percent volatile
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong acids; Strong bases; Strong oxidizing agents
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon dioxide During Combustion
Oxides of Nitrogen During Combustion
Hazardous Decomposition: silicon dioxide, calcium oxide and possible traces of incompletely burned carbon products.
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
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3M MATERIAL SAFETY DATA SHEET 3M Fire Barrier Water Tight Sealant 1000 NS and 1003 SL 03/22/2006
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Dispose of waste product in a sanitary landfill. As a disposal alternative, dispose of waste product in a
facility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
98-0400-5276-7, 98-0400-5278-3, 98-0400-5279-1, 98-0400-5281-7
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
FIFRA
Status Registration Number
Registered 5383-50
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
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3M MATERIAL SAFETY DATA SHEET 3M Fire Barrier Water Tight Sealant 1000 NS and 1003 SL 03/22/2006
or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 1 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
HMIS Hazard Classification
Health: 2 Flammability: 1 Reactivity: 0 Protection: B
Hazardous Material Identification System (HMIS庐) hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS庐 ratings are to be used with a fully implemented HMIS庐 program. HMIS庐 is a registered mark of the National Paint and Coatings
Association (NPCA).
Revision Changes:
Section 3: Potential effects from inhalation information was modified.
Section 3: Potential effects from ingestion information was modified.
Section 2: Ingredient table was modified.
Section 15: 311/312 Delayed Hazard score was modified.
Section 8: Exposure guidelines ingredient information was modified.
Section 8: Exposure guideline note was added.
Section 3: Immediate other hazard(s) was deleted.
Section 3: Other health effects information (reproductive hazards) was deleted.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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