Material Safety Data Sheet
Section 1: Product and Company Identification
RPM Wood Finishes Group, Inc. Company Phone number: (800) 522-8266
P.O. Box 22000 CHEMTREC: (800) 424-9300
Issue Date: 06/02/2007
Hickory, NC 28603
SHADING/GLAZING STAIN VAN DYKE BROWN
Product Name:
Product Code: SHADING/GLAZING STAIN VAN DYKE BROWN, B514-8786, B514-8786, B514-8786, B514-8786
Section 2: Hazards Identification
EMERGENCY OVERVIEW
Appearance: Colored Liquid Odor: Strong Solvent
Principal Hazards: DANGER! Flammable.
POISON! Harmful or fatal if swallowed. Causes eye and skin irritation. Vapor harmful.
Potential Health Effects: See Section 11 for more information.
Primary Routes of Exposure: Eye contact, ingestion, skin contact, inhalation, and absorption.
Eye Contact:
Product may cause eye irritation; signs and symptoms may include a burning sensation, redness, tearing, inflammation, blurred
vision, and/or possible transient corneal injury.
Ingestion:
Product if ingested may cause damage (including burns, scarring, and ulcerization) to mouth, throat, stomach, and digestive and
central nervous systems. Signs and symptoms may include headache, drowsiness, dizziness, swelling, abdominal discomfort,
burning sensation, shock or collapse, convulsions and/or bleeding. Contains methanol. May be fatal or cause blindness if
swallowed. Poison! Post-ingestion vomitous in the lungs may cause chemical pneumonia.
Skin Contact:
May be harmful if absorbed through the skin. Product may cause skin irritation; signs and symptoms may include drying,
cracking, sensitization, reddening, discoloration, blistering and/or swelling.
Inhalation:
Product if inhaled may cause severe irritation or damage (including but not limited to burns, scarring, and ulcerization) to
respiratory tract and central nervous system. Signs and symptoms may include weakness, headache, drowsiness, dizziness,
swelling, abdominal discomfort, burning sensation, shock or collapse, convulsions, breathing difficulties, nasal perforation,
ulceration, heart damage, blindness, bleeding and/or death. NOTICE: Reports have associated repeated and prolonged
occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents may be harmful or fatal.
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Material Safety Data Sheet
Product Name: SHADING/GLAZING STAIN VAN DYKE BROWN
Not Determined
Target Organs:
This product contains carcinogens or potential carcinogens as listed by IARC or NTP.
Carcinogenicity:
Components of this product are considered hazardous per the OSHA Hazard Communication Standard (29 CFR
Hazardous Listing:
1910.1200).
Section 3: Composition/Information on Ingredients
Chemical CAS Percent Composition
50 - 70
aliphatic petroleum distillates 64742-47-8
10 - 20
alkyd resin solids proprietary
1 - 10
magnesium silicate hydrate 14807-96-6
1 - 10
methanol 67-56-1
1 - 10
n-butyl stearate 123-95-5
1 - 10
1,2,4-trimethylbenzene 95-63-6
1 - 10
butanol 71-36-3
1 - 10
aliphatic hydrocarbons 8052-41-3
<1
propylene glycol 57-55-6
<1
m-xylene 108-38-3
<1
iron oxide 1309-37-1
<1
manganese oxide 1313-13-9
<1
aluminum oxide 1344-28-1
<1
o-xylene 95-47-6
<1
crystalline silica 14808-60-7
<1
ethylbenzene 100-41-4
<1
p-xylene 106-42-3
<1
methyl ethyl ketoxime 96-29-7
< 0.1
aromatic hydrocarbons 64742-95-6
< 0.1
water 7732-18-5
< 0.1
dipropylene glycol monomethyl ether 34590-94-8
< 0.1
toluene 108-88-3
< 0.1
ethanol 64-17-5
< 0.1
benzene 71-43-2
Section 4: First Aid Measures
Eye Contact:
If exposure occurs, flush the affected eye for at least 20 minutes. Tilt the head to prevent chemical from transferring to the
uncontaminated eye. Seek medical attention immediately after flushing.
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Material Safety Data Sheet
SHADING/GLAZING STAIN VAN DYKE BROWN
Product Name:
Ingestion:
Do not induce vomiting. Dilute with water or milk. Never give fluids if the victim is unconscious or having convulsions. Seek
medical attention immediately. Contact Poison Control Center immediately.
Skin Contact:
If exposure occurs, flush the affected area thoroughly with water for at least 15 minutes. Destroy contaminated clothing and shoes.
Seek medical attention immediately.
Inhalation:
Remove to fresh air. If not breathing, administer CPR until help arrives or the victim starts to breathe on his own. If breathing is
difficult, give oxygen. Seek medical attention immediately.
Section 5: Fire Fighting Measures
Extinguishing Media:
Use alcohol foam, dry chemical, carbon dioxide or any Class B fire extinguishing agent. Water may be unsuitable for extinguishing
fires. Water may be used to cool and prevent the rupture of containers that are exposed to the heat from a fire.
Products of Combustion:
Combustion may produce carbon monoxide, carbon dioxide, and irritating or toxic vapors and gases.
Protection of Firefighters / Explosion Hazards:
Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as
possible. Fire fighters should be protected from potential explosion hazards while extinguishing the fire. Wear self-contained
breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use.
Containers of this material may build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. Use
water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish a fire resulting from the flow of flammable
liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air
mixture after the initial fire is extinguished.
Section 6: Accidental Release Measures
Follow personal protective equipment recommendations found in Section 8. Personal protection needs must be evaluated based on
information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of
the spill, the area in which the spill occurred, and the training and the expertise of employees in the area responding to the spill.
Never exceed any occupational exposure limits. Shut off ignition sources; including electrical equipment and flames. Do not allow
smoking in the area. Do not allow the spilled product to enter public drainage systems or open waterways.
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Material Safety Data Sheet
Product Name: SHADING/GLAZING STAIN VAN DYKE BROWN
Section 7: Handling and Storage
Handling:
Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to
heat, flame, sparks, static electricity, or other sources of ignition.
Storage:
Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials.
Section 8: Exposure / Personal Protection
OSHA 29 CFR 1910.1000 Air Contaminants 鈥? Tables:
Status
Z-1 PEL Z-2 PEL Specifically ACGIH TLV
Z-3
Chemical CAS
(units as noted) (PPM) Regulated see: (units as noted)
64742-47-8
aliphatic petroleum distillates
proprietary
alkyd resin solids
14807-96-6
magnesium silicate hydrate * 2 MGM3
67-56-1
methanol 260 MGM3 (200 PPM) 200 PPM
123-95-5
n-butyl stearate
95-63-6
1,2,4-trimethylbenzene 25 PPM
71-36-3
butanol 300 MGM3 (100 PPM) 20 PPM
8052-41-3
aliphatic hydrocarbons 2900 MGM3 (500 PPM) 100 PPM
57-55-6
propylene glycol
108-38-3
m-xylene 435 MGM3 (100 PPM) 100 PPM
1309-37-1
iron oxide 15 MGM3 5 MGM3
1313-13-9
manganese oxide 0.2 MGM3
1344-28-1
aluminum oxide 5 MGM3 10 MGM3
95-47-6
o-xylene 435 MGM3 (100 PPM) 100 PPM
14808-60-7
crystalline silica * 0.025 MGM3
100-41-4
ethylbenzene 435 MGM3 (100 PPM) 100 PPM
106-42-3
p-xylene 435 MGM3 (100 PPM) 100 PPM
96-29-7
methyl ethyl ketoxime
aromatic hydrocarbons 64742-95-6
7732-18-5
water
34590-94-8
dipropylene glycol monomethyl ether 600 MGM3 (100 PPM) 100 PPM
108-88-3
toluene 200 PPM 50 PPM
64-17-5
ethanol 1900 MGM3 (1000 PPM) 1000 PPM
71-43-2
benzene 10 PPM 29 CFR 1910.1028 0.5 PPM
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Material Safety Data Sheet
SHADING/GLAZING STAIN VAN DYKE BROWN
Product Name:
Engineering Controls:
Use adequate ventilation to maintain airborne concentrations at levels below permissible or recommended occupational exposure
limits.
Eye / Face Protection:
Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is possible due to splashing or spraying
of material.
Skin Protection:
Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate.
Respiratory Protection:
A NIOSH-approved air-purifying respirator with the appropriate cartridge may be appropriate under certain circumstances where
airborne concentrations are expected to exceed permissible exposure limits. Protection provided by air-purifying respirators is
limited. Use a positive-pressure, air supplied respirator if there is potential for an uncontrolled release, exposure levels are not
known or any other circumstances where air-purifying respirators may not provide adequate protection.
General Hygiene Considerations:
It is good practice to avoid contact with the product and/or its vapor, mists or dust by using appropriate protective measures.
Wash thoroughly after handling and before eating or drinking.
Section 9: Physical and Chemical Properties
Colored Liquid
Physical State:
Strong Solvent
Odor:
Odor Threshold: Not determined.
pH: Not determined.
Freezing Point: Not determined.
Boiling Point: Not determined.
81 (CALC_)
o
Flash Point ( F):
Evaporation Rate: Not determined.
Flammability (solid, gas): Not determined.
Upper Flammability Limit: Not determined.
Lower Flammability Limit: Not determined.
Vapor Pressure: Not determined.
Vapor Density: Not determined.
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Material Safety Data Sheet
Product Name: SHADING/GLAZING STAIN VAN DYKE BROWN
0.91
Specific Gravity:
7.54
Weight per Gallon (lbs):
Solubility (water): Not determined.
Partition Coefficient (n-octanol/water): Not determined.
Auto-ignition Temperature: Not determined.
0.736
MIR Value:
600.06
Coating VOC g/l:
5
Coating VOC lbs/gal:
599.88
Material VOC g/l:
5
Material VOC lbs/gal:
22.93
Solids VOL%:
33.56
Solids WT %:
Contains Non-Photochemically Reactive Solvent.
VOC data per US EPA guidelines. Some states and localities have guidelines more stringent than federal regulations.
Section 10: Stability and Reactivity
Stability:
Stable under normal conditions.
Conditions to Avoid/Incompatible Materials:
Keep away from heat, sparks and flames.
Hazardous Decomposition Products:
Not determined.
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Material Safety Data Sheet
SHADING/GLAZING STAIN VAN DYKE BROWN
Product Name:
Section 11: Toxicology Information
IARC NTP
CAS
Chemical
64742-47-8
aliphatic petroleum distillates
alkyd resin solids proprietary
magnesium silicate hydrate 14807-96-6
methanol 67-56-1
n-butyl stearate 123-95-5
1,2,4-trimethylbenzene 95-63-6
butanol 71-36-3
aliphatic hydrocarbons 8052-41-3
propylene glycol 57-55-6
m-xylene 108-38-3
iron oxide 1309-37-1
manganese oxide 1313-13-9
aluminum oxide 1344-28-1
o-xylene 95-47-6
crystalline silica 14808-60-7 *
ethylbenzene 100-41-4
p-xylene 106-42-3
methyl ethyl ketoxime 96-29-7
aromatic hydrocarbons 64742-95-6
water 7732-18-5
dipropylene glycol monomethyl ether 34590-94-8
toluene 108-88-3
ethanol 64-17-5 *
benzene 71-43-2 *
Toxicological evaluation of this product as a whole has not been performed. Individual components that are potential or known
carcinogens are listed above.
Section 12: Ecological Information
Ecological evaluation of this material has not been performed; however, do not allow the product to be released to the
environment without governmental approval/permits.
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Material Safety Data Sheet
SHADING/GLAZING STAIN VAN DYKE BROWN
Product Name:
Section 13: Disposal Considerations
Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material, contaminated
absorbent, container and unused contents in accordance with local, state, and federal regulations.
Section 14: Transportation Information
UN1263, PAINT, 3, III
DOT Basic description:
See 49 CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations.
Section 15: Regulatory Information
Proposition 65
CERCLA RQ
EPCRA TPQ
EPCRA EHS
SARA 313
CERCLA
EINECS
WHMIS
TSCA
DSL
Chemical Name CAS
64742-47-8 * *
*
aliphatic petroleum distillates
proprietary
alkyd resin solids
14807-96-6 * * *
magnesium silicate hydrate
67-56-1 * 5000 LBS * * * * *
methanol
123-95-5 * * *
n-butyl stearate
95-63-6 * * * * *
1,2,4-trimethylbenzene
71-36-3 * 5000 LBS * * * * *
butanol
8052-41-3 * * * *
aliphatic hydrocarbons
57-55-6 * * * *
propylene glycol
108-38-3 * 100 LBS * * * * *
m-xylene
1309-37-1 * * * *
iron oxide
1313-13-9 * * * * * *
manganese oxide
1344-28-1 * * * * *
aluminum oxide
95-47-6 * 100 LBS * * * * *
o-xylene
14808-60-7 * * * * *
crystalline silica
100-41-4 * 1000 LBS * * * * * *
ethylbenzene
106-42-3 * 100 LBS * * * * *
p-xylene
96-29-7 * * *
methyl ethyl ketoxime
64742-95-6 * *
aromatic hydrocarbons *
7732-18-5 * * *
water
34590-94-8 * * * *
dipropylene glycol monomethyl ether
108-88-3 * 1000 LBS * * * * * *
toluene
64-17-5 * * * * *
ethanol
*
71-43-2 * 10 LBS * * * * *
benzene
WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects, or
other reproductive harm.
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Material Safety Data Sheet
Product Name: SHADING/GLAZING STAIN VAN DYKE BROWN
Section 16: Other Information
IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN
GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE
MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM
AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR
TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A
PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET
FORTH. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART
OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION
FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DATA
AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
0
Health 2 3
HMIS Codes Flammability Reactivity
Key to Abbreviations:
* Item appears on indicated list (or inventory)
ACGIH American Conference of Governmental Industrial Hygienists
CAS Chemical Abstract Service Registry Number
CERCLA Comprehensive Environmental Response, Compensation, and Liability Act
CERCLA RQ CERCLA Reportable Quantity
CFR Code of Federal Regulations
CPR Cardiopulmonary resuscitation
DSL Domestic Substances List of Canada
EINECS European Inventory of Existing Chemical Substances
EPCRA Emergency Planning and Community Right-to-know Act
EPCRA EHS EPCRA Extremely Hazardous Substance
EPCRA TPQ EPCRA Threshold Planning Quantity
o
F Fahrenheit degrees
g/l Grams per liter
gal Gallons
IARC International Agency for Research on Cancer
lbs or LBS Pounds
MGM3 Milligrams per cubic meter
MIR Maximum Incremental Reactivity
MSDS Material Safety Data Sheet
NIOSH National Institute of Occupational Safety and Health
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
PPM Parts per million
Proposition 65 California's Safe Drinking Water and Toxic Enforcement Act
SARA Superfund Amendments and Reauthorization Act
TLV Threshold Limit Value
TSCA Toxic Substances Control Act
USEPA United States Environmental Protection Agency
VOC Volatile Organic Compound
VOL Volume
WT Weight
WHMIS Canadian Workplace Hazardous Materials Information System
UN United Nations
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