MATERIAL SAFETY DATA SHEET
GLB Shoxidizer
1. Product And Company Identification
Supplier Manufacturer
GLB Advantis Technologies, Inc.
1400 Bluegrass Lakes Parkway 1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States Alpharetta, GA 30004 United States
Telephone Number: (770)521-5999 Telephone Number: (770) 521-5999
FAX Number: (770)521-5959 FAX Number: (770) 521-5959
Web Site: www.poolspacare.com Web Site: www.poolspacare.com
Supplier Emergency Contacts & Phone Number Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300 CHEMTREC - DAY OR NIGHT: (800) 424-9300
Issue Date: 06/12/2006
Product Name: GLB Shoxidizer
CAS Number: Not Established
MSDS Number: 352
2. Composition/Information On Ingredients
Ingredient CAS Percent Of
Name Number Total Weight
POTASSIUM HYDROGENPEROXYMONOSULFATE SULFATE 70693-62-8
SODIUM CARBONATE 497-19-8
SODIUMDICHLORO-S-TRIAZINETRIONE 2893-78-9
Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in
29CFR 1910.1200(i)(1).
EMERGENCY OVERVIEW
Individuals with preexisting diseases of the skin or gastrointestinal tract may have increased susceptibility to the
toxicity of excessive exposures.
3. Hazards Identification
Eye Hazards
Eye contact may cause eye corrsion, ulceration, irritation with tearing, pain or blurred vision. Severe eye damage
may result if not immediately treated.
Skin Hazards
Skin contact with dry product upon contact with moisture or perspiration may cause skin burns or ulceration,
irritation with itching, burning, redness, swelling or rash; temporary body hair loss may occur in contacted areas.
Skin contact with the product may cause allergic skin reactions in sensitive individuals. May be harmful if absorbed
through the skin.
Ingestion Hazards
May be harmful if ingested. Ingestion may cause gastritis possibly progressing to necrosis or hemorrhage. Irritation
of the digestive tract may appear with stomach pain, heartburn, nausea, vomiting or diarrhea; however, there may be
no symptoms at all.
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3. Hazards Identification - Continued
Inhalation Hazards
Inhalation may cause irritation of the nose, throat, and lungs with cough, nose bleeds, difficultly breathing or
shortness of breath. Avoid breathing dusts, mists or vapors. May be fatal if inhaled.
Chronic/Carcinogenicity Effects
None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC,
NTP, OSHA or ACGIH as a carcinogen.
First Aid (Pictograms)
4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Call a
physician.
Skin
In case of contact, immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated
clothing and shoes. Call a physician or poison control center immediately. Wash clothing before reuse.
Ingestion
DO NOT INDUCE VOMITING. Drink 2 glasses of water. Contact a physician or poison control. Never give anything
by mouth to an unconscious victim.
Inhalation
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a
physician or a poison control center immediately.
Fire Fighting (Pictograms)
5. Fire Fighting Measures
Flash Point: N/A 掳F
Flammability Class: N/A
Fire And Explosion Hazards
Will not burn. Improper storage of large masses of this material can trap heat and lead to ignition of combustibles.
Grinding or intensive mixing may cause decomposition with liberation of heat, oxygen and chlorine gas; ignition of
oxidizable material if present may occur.
Extinguishing Media
Water. Flood with high volume, low pressure water. Small quantities of water may react with this product to form
chlorine gas. Do not use carbon dioxide or other gas-filled fire extinguishers; they will have no effect on
decomposing persulfates.
Fire Fighting Instructions
Will release oxygen when heated, intensifying a fire. Will release chlorine gas. Acidic mist may be present; self
contained breathing apparatus should be used.
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6. Accidental Release Measures
Sweep up. Flush area with low pressure water.
Do not discharge to sewer. Toxic to fish and aquatic organisms.
Handling & Storage (Pictograms)
7. Handling And Storage
Handling Precautions
Do not inhale. Do not get in eyes, on skin or clothing. Wash thoroughly after handling. Wash clothing after use.
Storage Precautions
Store in a cool, dry, well-ventilated area away from heat sources such as light fixtures or space heaters. Leave open
space on all sides of each pallet to provide ventilation. See local fire codes for allowable limits. Bulk Bags should
be stored on pallets; if stacked use pyramid style, no more than 2 pallets high. Closely stacked bags should not
exceed 4 ft. cube. Keep packages dry. Do not store with combustible materials or with incompatibles.
Protective Clothing (Pictograms)
8. Exposure Controls/Personal Protection
Engineering Controls
Use sufficient ventilation to keep employee exposure below recommended limits.
Eye/Face Protection
Wear safety glasses or coverall chemical splash goggles.
Skin Protection
Where there is potential for skin contact have available and wear appropriate impervious gloves, apron, pants and
jacket.
Respiratory Protection
A NIOSH approved air-purifying respirator with an appropriate particulate cartridge or canister may be permissible
under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection
provided by air-purifying respirators is limited. Use a positive pressure air-supplied respirator if there is any potential
for an uncontrolled release, exposure levels are not known, or any other circumstances where air-purifying respirators
may not provide adequate protection.
9. Physical And Chemical Properties
Appearance
White granular to powder
Odor
None (mild), chlorine
Chemical Type: Mixture
Physical State: Solid
Specific Gravity: 1.1-1.4
Percent Volitales: <1%
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9. Physical And Chemical Properties - Continued
Odor - Continued
pH Factor: 7-7.5 At a Concentration Of 1% solution
Solubility: in water is 25 g 100 cc H2O at 20C
10. Stability And Reactivity
Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid (Stability)
The mixture reacts when moistened with small quantities of water to produce heat, carbon dioxide and chlorine gas.
Incompatible Materials
Contains oxidizing agents. Do not mix with chemicals or any other substance.
This mixture, if mixed with compounds containing halides or active halogens, can cause release of the respective
halogen if moisture is present. For example, mixing with calcium hypochlorite or with sodium bromide can cause
release of chlorine or bromine gas, respectively. Mixing with heavy metal salts such as those of cobalt, nickel,
copper, or manganese can cause decomposition with release of oxygen and heat.
Hazardous Decomposition Products
Decomposes when heated or dampened, releasing oxygen, chlorine gas and heat of decomposition. Decomposition
temperature: >110 degrees C.
11. Toxicological Information
Potassium Hydrogen Peroxymonosulfate Sulfate:
Inhalation 4 hour LC50: >5 mg/L in rats
Skin absorption LD50: >11000 mg/kg in rabbits
Oral LD50: 200-2000 mg/kg in rats
Severe skin and eye irritant, but is not a skin sensitizer in animals.
Single exposure by inhalation produced nonspecific effects such as weight loss and slight respiratory irritation. Repeated
inhalation exposures produced eye irritation and reversible corneal damage.
Administration of large single ingestion doses produced nonspecific effects such as weight loss and irritation, as well as
gastric ulceration, necrosis and hemorrhage. Repeated administration at a combined dosage of 1000/600 mg/kg for 13
weeks caused pathological changes of the stomach, body weight loss, gasping, noisy respiration, and hunched posture.
There were no toxic effects noted at 20 or 200 mg/kg and the no-observed-adverse-effect-level (NOAEL) is considered to be
200 mg/kg.
Tests for carcinogenic activity or reproductive toxicity have not been performed. A range-finding developmental toxicity
study showed developmental effects only at exposure levels producing other toxic effects in the adult animal.
Did not produce genetic damage in bacterial cell cultures. Did produce genetic damage in mammalian cell cultrures. It did
produce genetic damage in tests on animals, but showed some evidence of bone marrow cell toxicity in female mice.
Sodium Dichloroisocyanurate:
Oral LD50: 1420 mg/kg in rats
Oral LD50: 1230 mg/kg in mice
Dermal LD50: >2000 mg/kg in rabbits
Inhalation 4-hour LC50: >0.036 & <0.799 mg/L in rats
Animal testing indicates Sodium Dichloroisocyanurate is an eye irritant; and, it has been reported to be non-corrosive to
skin.
The following is known for a substance that is analogous in structure to Sodium Dichloroisocyanurate: Animal testing
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11. Toxicological Information - Continued
indicates the analogous substance is a skin irritant, but is not a skin sensitizer.
Rats and dogs fed Sodium Dichloroisocyanurate in their diet for 6 months showed no signs of toxicity or organ damage.
Sodium Dichloroisocyanurate has not caused developmental effects in animals.
Sodium Dichloroisocyanurate has not caused genetic damage in bacterial cell cultures.
Sodium Dichloroisocyanurate is degraded in the body to Sodium Cyanurate. The following data exists for Sodium
Cyanurate: Rats and mice, given Sodium Cyanurate (up to it's limit of solubility) in their drinking water for 90 days,
displayed no major compound-related adverse effects.
Sodium Cyanurate has not caused genetic damage in mammalian cell cultures or in animals.
Sodium Cyanurate has not caused carcinogenic, developmental or reproductive toxicity effects in long-term, repeated-dose
studies in animals.
Sodium Carbonate:
Oral LD50: 4200 mg/kg in rats
Sodium Carbonate is a skin irritant, is a severe eye irritant, but is untested for animal sensitization.
Single exposure by inhalation caused respiratory irritation. Repeated exposures caused reduced weight gain and
respiratory irritation.
No animal data are available to define the carcinogenity or reproductive hazards of this material. In animal testing sodium
carbonate has not caused developmental toxicity. It does not produce genetic damage in bacterial or mammalian cell
cultures or animals, but has not been tested for heritable genetic damage.
12. Ecological Information
Ecotoxicological Information
Potassium Hydrogen Peroxymonosulfate Sulfate:
96 hour LC50 - Rainbow trout: 53 mg/L
48 hour EC50 - Daphnia magna: 3.5 mg/L
Sodium Dichloroisocyanurate:
96 hour LC50 - Bluegill sunfish: 0.43 mg/L
96 hour LC50 - Rainbow trout: 0.25-0.65 mg/L
96 hour LC50 - Fathead minnow: 0.70 mg/L
48 hour EC50 - Daphnia magna: 0.11-0.28 mg/L
24 hour EC50 - Asiatic clam: 0.6 mg/L
Sodium Carbonate:
96 hour LC50 - Bluegill sunfish: 300 mg/L
96 hour LC50 - Mosquito fish: 1200 mg/L
13. Disposal Considerations
Comply with Federal, State, and local regulations. Large quantities should be tested for residual chlorine and dechlorinated
if necessary.
14. Transport Information
Proper Shipping Name
Not regulated
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MATERIAL SAFETY DATA SHEET
GLB Shoxidizer
14. Transport Information - Continued
Hazard Class
Not regulated
DOT Identification Number
NONE
15. Regulatory Information
SARA Hazard Classes
Acute Health Hazard
Canadian Regulatory Information
Class C Oxidizing Material
Class D Division 2 Subdivision B - Toxic Material. Skin or Eye Irritant
Class E Corrosive Material
WHMIS - Canada (Pictograms)
NFPA HMIS
HEALTH 3
0
FLAMMABILITY 0
3 2
REACTIVITY 2
C
PERSONAL PROTECTION
16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended purposes
or for the consequences of its use. Each individual should make a determination as to the suitability of
the information for their particular purposes(s).
GLB
Printed Using MSDS Generator鈩? 2000
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