PENNSTOP (R) 85%
Material Safety Data Sheet
Arkema Inc.
1 PRODUCT AND COMPANY IDENTIFICATION
EMERGENCY PHONE NUMBERS:
Thio and Fine Chemicals
Chemtrec: (800) 424-9300 (24hrs) or (703) 527-3887
Arkema Inc.
Medical: Rocky Mountain Poison Control Center
2000 Market Street
(866) 767-5089 (24Hrs)
Philadelphia, PA 19103
Information Telephone Numbers Phone Number Available Hrs
Customer Service 1-800-628-4453 8:30 to 5:30 EST
Product Name PENNSTOP (R) 85%
Product Synonym(s) N,N-Diethylhydroxylamine
Chemical Family Alkyl Hydroxylamine
Chemical Formula (C2H5)2NOH
Chemical Name Ethanamine, n-ethyl-n-hydroxy
EPA Reg Num
Product Use Oxygen scavenger
2 COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient Name CAS RegistryNumber Typical % OSHA
Water 7732-18-5 15 N
Alkyl hydroxylamine 3710-84-7 85 Y
The substance(s) marked with a "Y" in the OSHA column, are identified as hazardous chemicals according to the
criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200)
This material is classified as hazardous under Federal OSHA regulation.
The components of this product are all on the TSCA Inventory list.
3 HAZARDS IDENTIFICATION
Emergency Overview
Colorless to light straw color liquid; fishy (amine) odor.
WARNING!
FLAMMABLE LIQUID AND VAPOR.
MAY BE HARMFUL IF ABSORBED THROUGH SKIN
MAY CAUSE EYE AND SKIN IRRITATION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
Potential Health Effects
Inhalation and skin contact are expected to be the primary routes of occupational exposure to this material. Based on
single exposure animal tests, it is considered to be slightly toxic if swallowed or absorbed through skin, practically non-
toxic if inhaled, slightly to moderately irritating to skin and slightly irritating to eyes. High vapor concentrations may be
irritating to the respiratory tract.
Product Code: PENS85 Page 1
Revision: 8 Issued: 15 DEC 2005 of 6
PENNSTOP (R) 85%
Material Safety Data Sheet
Arkema Inc.
4 FIRST AID MEASURES
IF IN EYES, immediately flush with plenty of water for at least 15 minutes. Get medical attention.
IF ON SKIN, immediately flush with plenty of water. Remove contaminated clothing and shoes. Get medical
attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
IF SWALLOWED, do NOT induce vomiting. Give water to drink. Get medical attention immediately. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF INHALED, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.
5 FIRE FIGHTING MEASURES
Fire and Explosive Properties
Auto-Ignition Temperature NE
Flash Point 46.7 C (116 F) Flash Point Method Seta CC
Flammable Limits- Upper NE
NE
Lower
Extinguishing Media
Use water spray, carbon dioxide, foam or dry chemical.
Fire Fighting Instructions
Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out
gear (full Bunker Gear) and self-contained breathing apparatus (pressure demand NIOSH approved or
equivalent). Fire fighting equipment should be thoroughly decontaminated after use.
Fire and Explosion Hazards
When burned, the following hazardous products of combustion can occur: Oxides of carbon and nitrogen
6 ACCIDENTAL RELEASE MEASURES
In Case of Spill or Leak
Extinguish or turn off all ignition sources. Ventilate the space involved. Wear appropriate personal protection
equipment as indicated in Section 8 of this MSDS. Contain spill with inert materials. Construct a dike to
prevent spreading. Collect with non-sparking tools to a suitable container. Prevent waterway contamination.
Absorb liquid onto inert absorbent and place in DOT approved drums for disposal. Consult a regulatory
specialist to determine appropriate state or local reporting requirements, for assistance in waste
characterization and/or hazardous waste disposal and other requirements listed in pertinent environmental
permits.
7 HANDLING AND STORAGE
Handling
Keep away from heat, sparks and flame.
Keep container closed.
Use only with adequate ventilation.
Avoid contact with eyes, skin and clothing.
Avoid breathing vapor.
Product Code: PENS85 Page 2
Revision: 8 Issued: 15 DEC 2005 of 6
PENNSTOP (R) 85%
Material Safety Data Sheet
Arkema Inc.
7 HANDLING AND STORAGE
Wash thoroughly after handling.
CONTAINER HAZARDOUS WHEN EMPTY. Emptied container retains vapor and product residue. Follow
labeled warnings even after container is emptied. RESIDUAL VAPORS MAY EXPLODE ON IGNITION. DO
NOT CUT, DRILL GRIND OR WELD ON OR NEAR THIS CONTAINER. Improper disposal or reuse of this
container may be dangerous and/or illegal.
Storage
Store in well ventilated area away from heat and sources of ignition such as flame, sparks and static
electricity. Ensure that all storage and handling equipment is properly rated, grounded and installed to satisfy
electrical classification requirements. Static electricity may accumulate and create a fire hazard. All storage
containers, including containers such as drums, cylinders and IBC鈥檚, must be bonded and grounded during
filling and emptying operations. Store away from oxidizers and reactive materials. Keep container tightly
closed. Observe all federal, state and local regulations and National Fire Protection Association (NFPA)
Codes which pertain to the specific local conditions of storage and use, including OSHA 29 CFR 1910.106
and NFPA 30, 70, 77, and 497.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls
Investigate engineering techniques to reduce exposures. Provide ventilation if necessary to minimize
exposures. If practical, use local mechanical exhaust ventilation at sources of air contamination such as
open process equipment. Consult ACGIH ventilation manual or NFPA Standard 91 for design of exhaust
systems.
Eye / Face Protection
Where there is potential for eye contact, wear chemical goggles and have eye flushing equipment available.
Skin Protection
Wear appropriate chemical resistant protective clothing and chemical resistant gloves to prevent skin
contact. Consult glove manufacturer to determine appropriate type glove material for given application.
Wear face shield and chemical resistant clothing such as a rubber apron when splashing may occur. Rinse
contaminated skin promptly. Wash contaminated clothing and clean protective equipment before reuse.
Wash skin thoroughly after handling.
Respiratory Protection
Avoid breathing vapor or mist. Where airborne exposure is likely, use NIOSH approved respiratory
protection equipment appropriate to the material and/or its components. If exposures cannot be kept at a
minimum with engineering controls, consult respirator manufacturer to determine appropriate type equipment
for given application. Observe respirator use limitations specified by NIOSH or the manufacturer. For
emergency and other conditions where there may be a potential for significant exposure, use an approved full
face positive-pressure, self-contained breathing apparatus or positive-pressure airline with auxiliary self-
contained air supply. Respiratory protection programs must comply with 29 CFR 搂 1910.134.
Airborne Exposure Guidelines for Ingredients
The components of this product have no established Airborne Exposure Guidelines
-Only those components with exposure limits are printed in this section.
-Skin contact limits designated with a "Y" above have skin contact effect. Air sampling alone is insufficient to accurately quantitate
exposure. Measures to prevent significant cutaneous absorption may be required.
-ACGIH Sensitizer designator with a value of "Y" above means that exposure to this material may cause allergic reactions.
-WEEL-AIHA Sensitizer designator with a value of "Y" above means that exposure to this material may cause allergic skin reactions.
Product Code: PENS85 Page 3
Revision: 8 Issued: 15 DEC 2005 of 6
PENNSTOP (R) 85%
Material Safety Data Sheet
Arkema Inc.
9 PHYSICAL AND CHEMICAL PROPERTIES
Colorless to light straw color liquid; fishy (amine) odor.
Appearance/Odor
pH NE
Specific Gravity 0.90 @ 22 C
Vapor Pressure 32 mmHg @ 25 C
Vapor Density 3.1
Melting Point NA
Freezing Point -25 C (-13 F)
Boiling Point 125-130 C
Solubility In Water Soluble
Evaporation Rate NE
Percent Volatile 100
Molecular Weight 89.1
Other Physical Data Henry鈥檚 constant: 0.0059 Pa m3/mole
10 STABILITY AND REACTIVITY
Stability
This material is chemically stable under normal and anticipated storage and handling conditions.
Incompatibility
Avoid contact with strong oxidizers, activated carbon, and sulfonyl chlorides.
Hazardous Decomposition Products
Begins to decompose slowly at 120 - 130 C, which could liberate diethylamine.
11 TOXICOLOGICAL INFORMATION
Toxicological Information
Data on this material and/or its components are summarized below.
Single exposure (acute) studies indicate:
Oral - Slightly Toxic to Rats (LD50 2,190 mg/kg)
Dermal - Slightly Toxic to Rabbits (LD50 1,300 mg/kg)
Inhalation - Practically Non-toxic to Rats (4-hr LC50 3,140 ppm)
Eye Irritation - Slightly Irritating to Rabbits
Skin Irritation - Slightly to Moderately Irritating to Rabbits
An early study produced an allergic skin reaction in guinea pigs following repeated skin application; however,
no skin allergy was observed in guinea pigs in a more recent study. Repeated inhalation exposure produced
changes in liver and thymus weights and associated blood and clinical chemistry effects in rats. The only
histopathological changes were indicative of irritation in nasal passages. Long-term oral exposure produced no
adverse effects in rats or mice. No birth defects were observed in rats following oral exposure during
pregnancy, even at dosages that produced adverse effects on the mothers. No birth defects were noted in mice
after inhalation of this and two other concurrently administered materials during pregnancy. Both positive and
negative responses were observed in standard assays for genetic changes.
12 ECOLOGICAL INFORMATION
Product Code: PENS85 Page 4
Revision: 8 Issued: 15 DEC 2005 of 6
PENNSTOP (R) 85%
Material Safety Data Sheet
Arkema Inc.
12 ECOLOGICAL INFORMATION
Ecotoxicological Information
Data on this material and/or its components are summarized below.
This material is practically non-toxic to guppies (96-hr LC50 150 mg/l; neutralized material) and Daphnia magna
(48-hr EC50 111 mg/l). It is slightly toxic to bacteria (16-hr EC50 37 mg/l).
Chemical Fate Information
Data on this material and/or its components are summarized below.
This material is not readily biodegradable (20% after 28-days) and is not expected to bioaccumulate (log Pow -
1.5).
13 DISPOSAL CONSIDERATIONS
Waste Disposal
Incineration is the recommended method for disposal observing all local, state and federal regulations. Note:
Chemical additions to, processing of, or otherwise altering this material may make this waste management
information incomplete, inaccurate, or otherwise inappropriate. Furthermore, state and local waste disposal
requirements may be more restrictive or otherwise different from federal laws and regulations.
14 TRANSPORT INFORMATION
DOT Name Flammable liquid, n.o.s.
DOT Technical Name (Diethylhydroxylamine)
DOT Hazard Class 3
UN Number 1993
DOT Packing Group PG III
RQ None
15 REGULATORY INFORMATION
Hazard Categories Under Criteria of SARA Title III Rules (40 CFR Part 370)
Immediate (Acute) Health Y Fire Y
Reactive
Delayed (Chronic) Health N N
Sudden Release of Pressure N
The components of this product are all on the TSCA Inventory list.
Ingredient Related Regulatory Information:
CERCLA RQ SARA TPQ
SARA Reportable Quantities
Water NE
Alkyl hydroxylamine NE NE
16 OTHER INFORMATION
Product Code: PENS85 Page 5
Revision: 8 Issued: 15 DEC 2005 of 6
PENNSTOP (R) 85%
Material Safety Data Sheet
Arkema Inc.
Revision Information
Revision Number 8
15 DEC 2005
Revision Date
Supercedes Revision Dated 03-MAY-2005
Revision Summary
Revised section 5.
Key
NE= Not Established NA= Not Applicable (R) = Registered Trademark
Arkema Inc. believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR
IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided
herein relates only to the specific product designated and may not be valid where such product is used in
combination with any other materials or in any process. Further, since the conditions and methods of use are
beyond the control of Arkema Inc., Arkema Inc. expressly disclaims any and all liability as to any results
obtained or arising from any use of the product or reliance on such information.
Product Code: PENS85 Page 6
Revision: 8 Issued: 15 DEC 2005 of 6
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