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                            0893 105 - WURTH ALUMINIUM SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
NA477ECP Version No:3
CD 2007/2 Page 1 of 20



Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


PRODUCT NAME
0893 105 - WURTH ALUMINIUM SPRAY

STATEMENT OF HAZARDOUS NATURE
Considered a Hazardous Substance according to the criteria of the New
Zealand Hazardous Substances New Organisms legislation.

OTHER NAMES

PROPER SHIPPING NAME
AEROSOLS

PRODUCT USE
The use of a quantity of material in an unventilated or confined space may result in
increased exposure and an irritating atmosphere developing.
Before starting consider control of exposure by mechanical ventilation.
Spray paint for the protection of metal surfaces.
Application is by spray atomisation from a hand held aerosol pack.

SUPPLIER
Company: Wurth New Zealand Limited
Address:
42 Hobill Avenue
Manukau City
Auckland
NZL
Telephone: 0800 683 040
Fax: 0800 100 104




Section 2 - HAZARDS IDENTIFICATION


GHS Classification
Acute Toxicity (Oral) Category 5
Chronic Aquatic Hazard Category 2
Eye Irritation Category 2B
Flammable Aerosol Category 1
Organ Damage Category 2
Reproductive Toxicity Category 2
Respiratory Irritation Category 3
Skin Corrosion/Irritation Category 2

EMERGENCY OVERVIEW

HAZARD
DANGER
Determined by Chemwatch using GHS/HSNO criteria:
2.1.2A 6.1E 6.3A 6.4A 6.8B 6.8B 6.9B 9.1B
May cause respiratory irritation
Extremely flammable aerosol

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0893 105 - WURTH ALUMINIUM SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
NA477ECP Version No:3
CD 2007/2 Page 2 of 20
Section 2 - HAZARDS IDENTIFICATION

May be harmful if swallowed
Causes skin irritation
Causes eye irritation
Suspected of damaging fertility
Suspected of damaging the unborn child
May cause damage to organs through prolonged or repeated exposure by inhalation.
Toxic to aquatic life with long lasting effects

PRECAUTIONARY STATEMENTS

Prevention
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Wash hands thoroughly after handling.
Do not breathe dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Obtain special instructions before use.
Keep away from heat/sparks/open flame - No smoking.
Do not handle until all safety precautions have been read and understood.
Use personal protective equipment as required.

Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
If skin irritation occurs, seek medical advice/attention.
If eye irritation persists, get medical advice/attention.
If exposed or concerned: Get medical attention advice.
Wear eye/face protection.
Get medical advice/attention if you feel unwell.
Leaking gas fire: Do not extinguish, unless leak can be stopped safely
Eliminate all ignition sources if safe to do so.
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
IF ON SKIN: Gently wash with plenty of soap and water.
Wash/Decontaminate removed clothing before reuse.
Remove/Take off immediately all contaminated clothing

Storage
Store locked up.
Protect from sunlight and do not expose to temperatures exceeding 50??C/122??F.

Disposal
Dispose of contents and container in accordance with relevant legislation.


Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %
naphtha petroleum, light, hydrotreated 64742-49-0. 10-35
toluene 108-88-3 10-19
aluminium 7429-90-5 1-10^
naphtha, petroleum, hydrodesulfurised heavy 64742-82-1. 1-2.5
naphtha petroleum, light aromatic solvent 64742-95-6. 1-2.5
methylal 109-87-5 NotSpec
dimethyl ether 115-10-6 >50




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0893 105 - WURTH ALUMINIUM SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
NA477ECP Version No:3
CD 2007/2 Page 3 of 20


Section 4 - FIRST AID MEASURES

NEW ZEALAND POISONS INFORMATION CENTRE 0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111

SWALLOWED
Not considered a normal route of entry.
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
路 Observe the patient carefully.
路 Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
路 Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
路 Seek medical advice.
Avoid giving milk or oils.
Avoid giving alcohol.

EYE
If aerosols come in contact with the eyes:
路 Immediately hold the eyelids apart and flush the eye continuously for at least 15
minutes with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
路 Transport to hospital or doctor without delay.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.

SKIN
If solids or aerosol mists are deposited upon the skin:
路 Flush skin and hair with running water (and soap if available).
路 Remove any adhering solids with industrial skin cleansing cream.
路 DO NOT use solvents.
路 Seek medical attention in the event of irritation.

INHALED
If aerosols, fumes or combustion products are inhaled:
路 Remove to fresh air.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
路 If breathing is shallow or has stopped, ensure clear airway and apply resuscitation,
preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as
trained. Perform CPR if necessary.
路 Transport to hospital, or doctor.

NOTES TO PHYSICIAN
Treat symptomatically.
For acute or short term repeated exposures to petroleum distillates or related
hydrocarbons:
路 Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is
respiratory failure.
路 Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis,
tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with
inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated.
路 Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and
electrocardiographic evidence of myocardial injury has been reported; intravenous lines
and cardiac monitors should be established in obviously symptomatic patients. The lungs
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0893 105 - WURTH ALUMINIUM SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
NA477ECP Version No:3
CD 2007/2 Page 4 of 20
Section 4 - FIRST AID MEASURES

excrete inhaled solvents, so that hyperventilation improves clearance.
路 A chest x-ray should be taken immediately after stabilisation of breathing and
circulation to document aspiration and detect the presence of pneumothorax.
路 Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of
potential myocardial sensitisation to catecholamines. Inhaled cardioselective
bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a
second choice.
路 Lavage is indicated in patients who require decontamination; ensure use of cuffed
endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical Toxicology].


Section 5 - FIRE FIGHTING MEASURES


EXTINGUISHING MEDIA
SMALL FIRE:
路 Water spray, dry chemical or CO2
LARGE FIRE:
路 Water spray or fog.

FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water course.
路 If safe, switch off electrical equipment until vapour fire hazard removed.
路 Use water delivered as a fine spray to control fire and cool adjacent area.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
路 Equipment should be thoroughly decontaminated after use.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 100 metres in all directions.

FIRE/EXPLOSION HAZARD
路 Liquid and vapour are flammable.
路 Moderate fire hazard when exposed to heat or flame.
路 Vapour forms an explosive mixture with air.
路 Moderate explosion hazard when exposed to heat or flame.
路 Vapour may travel a considerable distance to source of ignition.
路 Heating may cause expansion or decomposition leading to violent rupture of containers.
路 Aerosol cans may explode on exposure to naked flame.
路 Rupturing containers may rocket and scatter burning materials.
路 Hazards may not be restricted to pressure effects.
路 May emit acrid, poisonous or corrosive fumes.
路 On combustion, may emit toxic fumes of carbon monoxide (CO)., carbon dioxide (CO2),
other pyrolysis products typical of burning organic material.
路 Liquid and vapour are highly flammable.
路 Severe fire hazard when exposed to heat or flame.
路 Vapour forms an explosive mixture with air.
路 Severe explosion hazard, in the form of vapour, when exposed to flame or spark.
路 Vapour may travel a considerable distance to source of ignition.
路 Heating may cause expansion or decomposition with violent container rupture.
路 Aerosol cans may explode on exposure to naked flames.
路 Rupturing containers may rocket and scatter burning materials.
路 Hazards may not be restricted to pressure effects.
路 May emit acrid, poisonous or corrosive fumes.
路 On combustion, may emit toxic fumes of carbon monoxide (CO).

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0893 105 - WURTH ALUMINIUM SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
NA477ECP Version No:3
CD 2007/2 Page 5 of 20
Section 5 - FIRE FIGHTING MEASURES

Combustion products include:

FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine
bleaches, pool chlorine etc. as ignition may result.

Personal Protective Equipment
Breathing apparatus.
Gas tight chemical resistant suit.
Limit exposure duration to 1 BA set 30 mins.


Section 6 - ACCIDENTAL RELEASE MEASURES


EMERGENCY PROCEDURES

MINOR SPILLS
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Wear protective clothing, impervious gloves and safety glasses.
路 Shut off all possible sources of ignition and increase ventilation.
路 Wipe up.
路 If safe, damaged cans should be placed in a container outdoors, away from all ignition
sources, until pressure has dissipated.
路 Undamaged cans should be gathered and stowed safely.

MAJOR SPILLS
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water courses
路 No smoking, naked lights or ignition sources.
路 Increase ventilation.
路 Stop leak if safe to do so.
路 Water spray or fog may be used to disperse / absorb vapour.
路 Absorb or cover spill with sand, earth, inert materials or vermiculite.
路 If safe, damaged cans should be placed in a container outdoors, away from ignition
sources, until pressure has dissipated.
路 Undamaged cans should be gathered and stowed safely.
路 Collect residues and seal in labelled drums for disposal.

PROTECTIVE ACTIONS FOR SPILL
PROTECTIVE ACTION ZONE

half
evacuation
downwind
direction
distance
down wind distance
wind isolation
distance
direction
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE


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0893 105 - WURTH ALUMINIUM SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
NA477ECP Version No:3
CD 2007/2 Page 6 of 20
Section 6 - ACCIDENTAL RELEASE MEASURES

From IERG (Canada/Australia)
Isolation Distance -
Downwind Protection Distance 8 metres
IERG Number 49

FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone
assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on
either side of the predominant wind direction, resulting in a crosswind protective action distance equal
to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill
and working away from the site in the downwind direction. Within the protective action zone a level of
vapour concentration may exist resulting in nearly all unprotected persons becoming incapacitated and
unable to take protective action and/or incurring serious or irreversible health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high
probability of localised wind reversal may expose nearly all persons without appropriate protection to
life-threatening concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or
box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from
a small cylinder are also considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as
a cargo tank, portable tank or a "one-tonne" compressed gas cylinder.
5 Guide 126 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.

EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed
for up to one hour WITHOUT experiencing or developing

life-threatening health effects is:
toluene 1000 ppm
aluminium 250 mg/m鲁
naphtha petroleum, light aromatic solvent 750 ppm
dimethyl ether 60000 ppm

irreversible or other serious effects or symptoms which could impair an individual's ability to take
protective action is:
toluene 300 ppm
aluminium 50 mg/m鲁
naphtha petroleum, light aromatic solvent 750 ppm
dimethyl ether 50000 ppm

other than mild, transient adverse effects without perceiving a clearly defined odour is:
toluene 50 ppm
aluminium 30 mg/m鲁
naphtha petroleum, light aromatic solvent 750 ppm
dimethyl ether 3000 ppm

The threshold concentration below which most people will experience no appreciable risk of health effects:
toluene 50 ppm
aluminium 15 mg/m鲁
naphtha petroleum, light aromatic solvent 500 ppm
dimethyl ether 1000 ppm

American Industrial Hygiene Association (AIHA)

Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%

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0893 105 - WURTH ALUMINIUM SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
NA477ECP Version No:3
CD 2007/2 Page 7 of 20
Section 6 - ACCIDENTAL RELEASE MEASURES

R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture

Personal Protective Equipment advice is contained in Section 8 of the MSDS.


Section 7 - HANDLING AND STORAGE


PROCEDURE FOR HANDLING
DO NOT allow clothing wet with material to stay in contact with skin.
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Prevent concentration in hollows and sumps.
路 DO NOT enter confined spaces until atmosphere has been checked.
路 Avoid smoking, naked lights or ignition sources.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 DO NOT incinerate or puncture aerosol cans.
路 DO NOT spray directly on humans, exposed food or food utensils.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions are maintained.

SUITABLE CONTAINER
路 Aerosol dispenser.
路 Check that containers are clearly labelled.

STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents.

STORAGE REQUIREMENTS
Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and
internal pressure may eject contents of can.
路 Store in original containers in approved flammable liquid storage area.
路 DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
路 No smoking, naked lights, heat or ignition sources.
路 Keep containers securely sealed. Contents under pressure.
路 Store away from incompatible materials.
路 Store in a cool, dry, well ventilated area.
路 Avoid storage at temperatures higher than 40 deg C.
路 Store in an upright position.
路 Protect containers against physical damage.
路 Check regularly for spills and leaks.
路 Observe manufacturer's storing and handling recommendations.




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0893 105 - WURTH ALUMINIUM SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
NA477ECP Version No:3
CD 2007/2 Page 8 of 20


Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION


EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
New toluene 50 188
Zealand (Toluene)
Workplace
Exposure
Standards
(WES)
New methylal 1, 000 3, 110
Zealand (Methylal)
Workplace
Exposure
Standards
(WES)
New dimethyl 400 766 500 958
Zealand ether
Workplace (Dimethyle
Exposure ther)
Standards
(WES)

The following materials had no OELs on our records
鈥? naphtha petroleum, light, hydrotreated: CAS:64742- 49- 0
鈥? naphtha, petroleum, hydrodesulfurised heavy: CAS:64742- 82- 1
鈥? naphtha petroleum, light aromatic solvent: CAS:64742- 95- 6


EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)
toluene 500
methylal 2, 200 [LEL]

NOTES
Values marked LEL indicate that the IDLH was based on 10% of the lower explosive limit
for safety considerations even though the relevant toxicological data indicated that
irreversible health effects or impairment of escape existed only at higher
concentrations.


ODOUR SAFETY FACTOR (OSF)
OSF=17 (TOLUENE)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:

Class OSF Description
A 550 Over 90% of exposed individuals
are aware by smell that the
Exposure Standard (TLV- TWA for
example) is being reached, even
when distracted by working
activities
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0893 105 - WURTH ALUMINIUM SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
NA477ECP Version No:3
CD 2007/2 Page 9 of 20
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

B 26- 550 As " A" for 50- 90% of persons
being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by smell
that the Exposure Standard is
being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested

.

MATERIAL DATA
Not available. Refer to individual constituents.

INGREDIENT DATA
NAPHTHA PETROLEUM, LIGHT AROMATIC SOLVENT:
NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
NAPHTHA, PETROLEUM, HYDRODESULFURISED HEAVY:
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no
-observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five
-category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
路 cause inflammation
路 cause increased susceptibility to other irritants and infectious agents
路 lead to permanent injury or dysfunction
路 permit greater absorption of hazardous substances and
路 acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.

NAPHTHA PETROLEUM, LIGHT AROMATIC SOLVENT:
TOLUENE:
Established occupational exposure limits frequently do not take into consideration
reproductive end points that are clearly below the thresholds for other toxic effects.
Occupational reproductive guidelines (ORGs) have been suggested as an additional
standard. These have been established after a literature search for reproductive no
-observed-adverse effect-level (NOAEL) and the lowest-observed-adverse-effect-level
(LOAEL). In addition the US EPA's procedures for risk assessment for hazard
identification and dose-response assessment as applied by NIOSH were used in the creation
of such limits. Uncertainty factors (UFs) have also been incorporated.

NAPHTHA PETROLEUM, LIGHT AROMATIC SOLVENT:
TOLUENE:
These exposure guidelines have been derived from a screening level of risk assessment
and should not be construed as unequivocally safe limits. ORGS represent an 8-hour time
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0893 105 - WURTH ALUMINIUM SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
NA477ECP Version No:3
CD 2007/2 Page 10 of 20
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).

NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
for petroleum distillates:
CEL TWA: 500 ppm, 2000 mg/m3 (compare OSHA TWA).

TOLUENE:
Exposure limits with "skin" notation indicate that vapour and liquid may be absorbed
through intact skin. Absorption by skin may readily exceed vapour inhalation exposure.
Symptoms for skin absorption are the same as for inhalation. Contact with eyes and mucous
membranes may also contribute to overall exposure and may also invalidate the exposure
standard.
Odour Threshold Value: 0.16-6.7 (detection), 1.9-69 (recognition)
NOTE: Detector tubes measuring in excess of 5 ppm, are available.
High concentrations of toluene in the air produce depression of the
central nervous system (CNS) in humans. Intentional toluene exposure
(glue-sniffing) at maternally-intoxicating concentration has also produced
birth defects. Foetotoxicity appears at levels associated with CNS
narcosis and probably occurs only in those with chronic toluene-induced
kidney failure. Exposure at or below the recommended TLV-TWA is thought
to prevent transient headache and irritation, to provide a measure of
safety for possible disturbances to human reproduction, the prevention of
reductions in cognitive responses reported amongst humans inhaling
greater than 40 ppm, and the significant risks of hepatotoxic, behavioural
and nervous system effects (including impaired reaction time and
incoordination). Although toluene/ethanol interactions are well
recognised, the degree of protection afforded by the TLV-TWA among
drinkers is not known.

NAPHTHA, PETROLEUM, HYDRODESULFURISED HEAVY:

CEL TWA: 100 ppm hydrocarbons [EXXON]

NAPHTHA PETROLEUM, LIGHT AROMATIC SOLVENT:

REL TWA: 25-100 ppm*, 125 mg/m3* [Various Manufacturers]
CEL TWA: 50 ppm, 125 mg/m3

METHYLAL:
The TLV-TWA is protective against eyes and mucous membrane irritation and
against central nervous system depression.

DIMETHYL ETHER:
The no-effect-level for dimethyl ether is somewhere between 2000 ppm
(rabbits) and 50,000 ppm (humans) with possible cardiac sensitisation
occurring around 200,000 ppm (dogs). The AIHA has adopted a safety factor
of 100 in respect to the 50,000 ppm level in its recommendation for a
workplace environmental exposure level (WEEL) which is thought to protect
against both narcotic and sensitising effects. This level is consistent
with the TLV-TWA of 400 ppm for diethyl ether and should be easily
achievable using current technologies. The use of the traditionally
allowable excursion of 1.25 to the level of 6.25 ppm is felt to be more
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0893 105 - WURTH ALUMINIUM SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
NA477ECP Version No:3
CD 2007/2 Page 11 of 20
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

than adequate as an upper safe limit of exposure.
Human data:
50,000 ppm (12 mins): Feelings of mild intoxication.
75,000 ppm (12 mins): As above plus slight lack of attenuation.
82,000 ppm (12 mins): Some incoordination, slight blurring of vision
(30 mins): As above plus analgesia of the face and rushing of
blood to the face.
100,000 ppm (10-20 mins): Narcotic symptoms
(64 mins) : Sickness (assumed to be nausea)
144,000 ppm (36 mins): Unconsciousness

PERSONAL PROTECTION

EYE
No special equipment for minor exposure i.e. when handling small quantities.
OTHERWISE: For potentially moderate or heavy exposures:
路 Safety glasses with side shields.
路 NOTE: Contact lenses pose a special hazard; soft lenses may absorb irritants and ALL
lenses concentrate them.

HANDS/FEET
No special equipment needed when handling small quantities.
OTHERWISE:
For potentially moderate exposures:
Wear general protective gloves, eg. light weight rubber gloves.
For potentially heavy exposures:
Wear chemical protective gloves, eg. PVC. and safety footwear.

OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
路 Overalls.
路 Skin cleansing cream.
路 Eyewash unit.
路 Do not spray on hot surfaces.

RESPIRATOR
Respiratory protection may be required when ANY "Worst Case" vapour-phase concentration
is exceeded (see Computer Prediction in "Exposure Standards").


Protection Factor (Min) Half- Face Respirator Full- face Respirator
10 x ES AX- AUS -
AX- PAPR- AUS -
20 x ES - AX- AUS
- AX- PAPR- AUS
100 x ES - AX- 2
- AX- PAPR- 2

^ - Full-face.

The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.




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0893 105 - WURTH ALUMINIUM SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
NA477ECP Version No:3
CD 2007/2 Page 12 of 20
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

ENGINEERING CONTROLS
General exhaust is adequate under normal conditions. If risk of overexposure exists, wear
SAA approved respirator. Correct fit is essential to obtain adequate protection.
Provide adequate ventilation in warehouse or closed storage areas.



Section 9 - PHYSICAL AND CHEMICAL PROPERTIES


APPEARANCE
Highly flammable liquid with a characteristic odour; does not mix with water.
Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable ether
propellant.

PHYSICAL PROPERTIES
Liquid.
Gas.
Does not mix with water.

Molecular Weight: Not Applicable Boiling Range (掳 - 24
C):
Melting Range (掳 Not Available
C): Specific Gravity (water= 1): Not Available
Solubility in water (g/L): Immiscible pH (as supplied): Not Applicable
pH (1% solution): Not Applicable Vapour Pressure (kPa): 520
Volatile Component (%vol): >60 Evaporation Rate: Not Available
Relative Vapour Density (air=1): Not Available Flash Point (掳 - 42
C):
Lower Explosive Limit (%): 1.2 Upper Explosive Limit (%): 18.6
Autoignition Temp (掳 235
C): Decomposition Temp (掳 Not Av ailable
C):
State: Liquid Viscosity: Not Available

log Kow (Sangster 1997): 2.73
log Kow: 2.1-3
log Kow (Sangster 1997): 0.18
log Kow: 0
log Kow (Sangster 1997): 0.1
log Kow: 0.1-0.12


Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION


CONDITIONS CONTRIBUTING TO INSTABILITY
路 Elevated temperatures.
路 Presence of open flame.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.


Section 11 - TOXICOLOGICAL INFORMATION


POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED
Although ingestion is not thought to produce harmful effects (as classified under EC
Directives), the material may still be damaging to the health of the individual,
following ingestion, especially where pre-existing organ (e.g liver, kidney) damage is
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Section 11 - TOXICOLOGICAL INFORMATION

evident. Present definitions of harmful or toxic substances are generally based on doses
producing mortality rather than those producing morbidity (disease, ill-health).
Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational
setting however, ingestion of insignificant quantities is not thought to be cause for
concern.
Considered an unlikely route of entry in commercial/industrial environments.
Not normally a hazard due to physical form of product.
Overexposure is unlikely in this form.
Ingestion may result in nausea, pain, vomiting. Vomit entering the lungs by aspiration
may cause potentially lethal chemical pneumonitis.

EYE
Although the material is not thought to be an irritant (as classified by EC Directives),
direct contact with the eye may produce transient discomfort characterised by tearing or
conjunctival redness (as with windburn).
The material may be irritating to the eye, with prolonged contact causing inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.

SKIN
Evidence exists, or practical experience predicts, that the material either produces
inflammation of the skin in a substantial number of individuals following direct contact,
and/or produces significant inflammation when applied to the healthy intact skin of
animals, for up to four hours, such inflammation being present twenty-four hours or more
after the end of the exposure period. Skin irritation may also be present after prolonged
or repeated exposure; this may result in a form of contact dermatitis (nonallergic). The
dermatitis is often characterised by skin redness (erythema) and swelling (oedema) which
may progress to blistering (vesiculation), scaling and thickening of the epidermis. At
the microscopic level there may be intercellular oedema of the spongy layer of the skin
(spongiosis) and intracellular oedema of the epidermis.
Skin contact is not thought to have harmful health effects (as classified under EC
Directives); the material may still produce health damage following entry through wounds,
lesions or abrasions.
The material may cause skin irritation after prolonged or repeated exposure and may
produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling the epidermis. Histologically there
may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of
the epidermis.

INHALED
The material is not thought to produce adverse health effects or irritation of the
respiratory tract (as classified by EC Directives using animal models). Nevertheless,
good hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.
Inhalation of aerosols (mists, fumes), generated by the material during the course of
normal handling, may be harmful.
Acute effects from inhalation of high concentrations of vapour are pulmonary irritation,
including coughing, with nausea; central nervous system depression - characterised by
headache and dizziness, increased reaction time, fatigue and loss of co-ordination.
WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.

CHRONIC HEALTH EFFECTS
Exposure to the material may cause concerns for human fertility, generally on the basis
that results in animal studies provide sufficient evidence to cause a strong suspicion of
impaired fertility in the absence of toxic effects, or evidence of impaired fertility
occurring at around the same dose levels as other toxic effects, but which are not a
secondary non-specific consequence of other toxic effects.
Prolonged or continuous skin contact with the liquid may cause defatting with drying,
cracking, irritation and dermatitis following.
Chronic solvent inhalation exposures may result in nervous system impairment
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Section 11 - TOXICOLOGICAL INFORMATION

and liver and blood changes. [PATTYS].
As with any chemical product, contact with unprotected bare skin; inhalation of vapour,
mist or dust in work place atmosphere; or ingestion in any form, should be avoided by
observing good occupational work practice.
Principal route of occupational exposure to the gas is by inhalation.

TOXICITY AND IRRITATION
Not available. Refer to individual constituents.

NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
No significant acute toxicological data identified in literature search.

TOLUENE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (human) LDLo: 50 mg/kg Skin (rabbit):20 mg/24h- Moderate
Oral (rat) LD50: 636 mg/kg Skin (rabbit):500 mg - Moderate
Inhalation (human) TCLo: 100 ppm Eye (rabbit):0.87 mg - Mild
Inhalation (man) TCLo: 200 ppm Eye (rabbit): 2mg/24h - SEVERE
Inhalation (rat) LC50: >26700 ppm/1h Eye (rabbit):100 mg/30sec - Mild
Dermal (rabbit) LD50: 12124 mg/kg
The material may cause skin irritation after prolonged or repeated exposure and may
produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling the epidermis. Histologically there
may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of
the epidermis.

NAPHTHA, PETROLEUM, HYDRODESULFURISED HEAVY:
No data of toxicological significance identified in literature search.

NAPHTHA PETROLEUM, LIGHT AROMATIC SOLVENT:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: >5000 mg/kg * Nil Reported
Inhalation (rat) LC50: >3670 ppm/8 h *
Inhalation (rat) TCLo: 1320 ppm/6h/90D- I
* [Devoe]

METHYLAL:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Inhalation (rat) LC50: 15000 ppm Nil Reported
Inhalation (rat) LC50: 3000 ppm/4h

DIMETHYL ETHER:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Inhalation (rat) LC50: 308000 mg/m鲁 Nil Reported


Section 12 - ECOLOGICAL INFORMATION

Marine Pollutant:Not Determined
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
DO NOT discharge into sewer or waterways.
Water hazard class 2 (Self-assessment): hazardous to water.
Refer to data for ingredients, which follows:

continued...
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Section 12 - ECOLOGICAL INFORMATION

NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.

Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.

Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.

Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
DO NOT discharge into sewer or waterways.

TOLUENE:
Hazardous Air Pollutant: Yes
Fish LC50 (96hr.) (mg/l): 7.3- 22.8
BCF<100: 13.2 (EELS
log Kow (Sangster 1997): 2.73
log Pow (Verschueren 1983): 2.69
BOD5: 5%
COD: 21%
ThOD: 3.13
Half- life Soil - High (hours): 528
Half- life Soil - Low (hours): 96
Half- life Air - High (hours): 104
Half- life Air - Low (hours): 10
Half- life Surface water - High (hours): 528
Half- life Surface water - Low (hours): 96
Half- life Ground water - High (hours): 672
Half- life Ground water - Low (hours): 168
Aqueous biodegradation - Aerobic - High (hours): 528
Aqueous biodegradation - Aerobic - Low (hours): 96
Aqueous biodegradation - Anaerobic - High (hours): 5040
Aqueous biodegradation - Anaerobic - Low (hours): 1344
Aqueous biodegradation - Removal secondary treatment - High (hours): 75%
Photolysis maximum light absorption - High (nano- m): 268
Photolysis maximum light absorption - Low (nano- m): 253.5
Photooxidation half- life water - High (hours): 1284
Photooxidation half- life water - Low (hours): 321
Photooxidation half- life air - High (hours): 104
Photooxidation half- life air - Low (hours): 10

The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.
continued...
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Section 12 - ECOLOGICAL INFORMATION


Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.

Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.

Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
DO NOT discharge into sewer or waterways.
log Kow: 2.1-3
log Koc: 1.12-2.85
Koc: 37-250
log Kom: 1.39-2.89
Half-life (hr) air: 2.4-104
Half-life (hr) H2O surface water: 5.55-528
Half-life (hr) H2O ground: 168-2628
Half-life (hr) soil: <48-240
Henry's Pa m鲁 /mol: 518-694
Henry's atm m鲁 /mol: 5.94E-03
BOD 5 if unstated: 0.86-2.12,5%
COD: 0.7-2.52,21-27%
ThOD: 3.13
BCF: 1.67-380
Log BCF: 0.22-3.28

NAPHTHA, PETROLEUM, HYDRODESULFURISED HEAVY:
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.

Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.

Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.

Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
DO NOT discharge into sewer or waterways.

NAPHTHA PETROLEUM, LIGHT AROMATIC SOLVENT:
continued...
0893 105 - WURTH ALUMINIUM SPRAY
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Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
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Section 12 - ECOLOGICAL INFORMATION

The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.

Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.

Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.

Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
DO NOT discharge into sewer or waterways.

METHYLAL:
log Pow (Verschueren 1983): 0
log Kow (Sangster 1997): 0.18

DO NOT discharge into sewer or waterways.
log Kow: 0
Degradation Biological: by soil microflora -8 days

DIMETHYL ETHER:
Water solubility (g/l): 35300
log Kow (Sangster 1997): 0.1

log Kow: 0.1-0.12
Koc: 14
Half-life (hr) air: 528
Half-life (hr) H2O surface water: 2.6-30
Henry's atm m鲁 /mol: 9.78E-04
BCF: 1.7
Bioaccumulation: not sig
processes Abiotic: RxnOH*


Section 13 - DISPOSAL CONSIDERATIONS

路 Consult State Land Waste Management Authority for disposal.
路 Discharge contents of damaged aerosol cans at an approved site.
路 Allow small quantities to evaporate.
路 DO NOT incinerate or puncture aerosol cans.
路 Bury residues and emptied aerosol cans at an approved site.




continued...
0893 105 - WURTH ALUMINIUM SPRAY
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Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
NA477ECP Version No:3
CD 2007/2 Page 18 of 20


Section 14 - TRANSPORTATION INFORMATION




Labels Required: FLAMMABLE GAS
HAZCHEM: 2Y

UNDG:
Dangerous Goods Class: 2.1 Subrisk: None
UN Number: 1950 Packing Group: None
Shipping Name:AEROSOLS

Air Transport IATA:
ICAO/IATA Class: 2.1 ICAO/IATA Subrisk: None
UN/ID Number: 1950 Packing Group: None
ERG Code: 10L
Shipping name:AEROSOLS

Maritime Transport IMDG:
IMDG Class: 2.1 IMDG Subrisk: SP63
UN Number: 1950 Packing Group: None
EMS Number: F- D, S- U Marine Pollutant: Not Determined
Shipping name:AEROSOLS



Section 15 - REGULATORY INFORMATION


REGULATIONS
0893 105 - Wurth Aluminium Spray (CAS No: None):
No regulations applicable

naphtha petroleum, light, hydrotreated (CAS: 64742-49-0) is found on the following regulatory lists;
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Transferred List of Single Component Substances
OECD Representative List of High Production Volume (HPV) Chemicals

toluene (CAS: 108-88-3) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Agency for Research on Cancer (IARC) Carcinogens
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Poisons Schedule
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances - Table II
United Nations List of Precursors and Chemicals Frequently used in the Illicit Manufacture of Narcotic Drugs and Psychotropic Substances Under International
Control - Table II
WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking-water

naphtha, petroleum, hydrodesulfurised heavy (CAS: 64742-82-1) is found on the following regulatory lists;
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Transferred List of Single Component Substances
OECD Representative List of High Production Volume (HPV) Chemicals

naphtha petroleum, light aromatic solvent (CAS: 64742-95-6) is found on the following regulatory lists;
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Transferred List of Single Component Substances
OECD Representative List of High Production Volume (HPV) Chemicals

methylal (CAS: 109-87-5) is found on the following regulatory lists;
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred


continued...
0893 105 - WURTH ALUMINIUM SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
NA477ECP Version No:3
CD 2007/2 Page 19 of 20
Section 15 - REGULATORY INFORMATION
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals

dimethyl ether (CAS: 115-10-6) is found on the following regulatory lists;
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals


Specific advice on controls required for materials used in
New Zealand can be found at
http://www.ermanz.govt.nz/search/registers.html


Section 16 - OTHER INFORMATION

NEW ZEALAND POISONS INFORMATION CENTRE
0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111


REPRODUCTIVE HEALTH GUIDELINES
Ingredient ORG UF Endpoi CR Adeq
nt TLV
toluene 9.6 mg/m3 10 D
NA -
naphtha petroleum, light 12 mg/m3 100 D
NA -
aromatic solvent
These exposure guidelines have been derived from a screening level of risk assessment and
should not be construed as unequivocally safe limits. ORGS represent an 8-hour time
-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).

EXPOSURE STANDARD FOR MIXTURES
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m3): 250 mg/m鲁
If the breathing zone concentration of ANY of the components listed below is exceeded,
"Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m3 Mixture Conc: (%).

Component Breathing zone Breathing Zone Mixture Conc
(ppm) (mg/m鲁) (%)
naphtha, petroleum, hydrodesulfurised heavy 125.0000
2.5 50.00 125.0000 2.5

Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.

This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.



continued...
0893 105 - WURTH ALUMINIUM SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 23-Aug-2004 CHEMWATCH 7502-91
NA477ECP Version No:3
CD 2007/2 Page 20 of 20
Section 16 - OTHER INFORMATION

Issue Date: 23-Aug-2004
Print Date: 20-Jul-2007

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